Traditional preparation of magnetic microcapsules involves cumbersome processes and often results in irregular-shaped products. Due to the stable laminar flow of reaction solution and the moderate reaction conditions,...Traditional preparation of magnetic microcapsules involves cumbersome processes and often results in irregular-shaped products. Due to the stable laminar flow of reaction solution and the moderate reaction conditions, the T-shaped microchannel (T-MC) reactor is supposed to yield microcapsules with regular shape. In this paper, magnetic particles of ferroferric oxide modified by oleic acid (OA-Fe3O4) and dispersed in tetrachloroethylene were used as core material. Polymethyl methacrylate (PMMA) was used as shell material. Magnetic microcapsules were prepared by using a T-MC reactor. Factors that influenced the encapsulated reaction were investigated in details, which included the velocity ratio of aqueous phase to oil phase, the length and the inner diameter of the microchannel. The morphology, composition, and magnetic responsiveness of the magnetic microcapsules were analyzed and characterized by SEM, FTIR, XRD, TGA, and vibrating sample magnetometer (VSM). The results confirmed that magnetic microcapsules prepared by T-MC reactor were regular in shape.展开更多
基金Fundamental Research Funds for the Central Universities,China(No.2011D10543,No.2013D110525)
文摘Traditional preparation of magnetic microcapsules involves cumbersome processes and often results in irregular-shaped products. Due to the stable laminar flow of reaction solution and the moderate reaction conditions, the T-shaped microchannel (T-MC) reactor is supposed to yield microcapsules with regular shape. In this paper, magnetic particles of ferroferric oxide modified by oleic acid (OA-Fe3O4) and dispersed in tetrachloroethylene were used as core material. Polymethyl methacrylate (PMMA) was used as shell material. Magnetic microcapsules were prepared by using a T-MC reactor. Factors that influenced the encapsulated reaction were investigated in details, which included the velocity ratio of aqueous phase to oil phase, the length and the inner diameter of the microchannel. The morphology, composition, and magnetic responsiveness of the magnetic microcapsules were analyzed and characterized by SEM, FTIR, XRD, TGA, and vibrating sample magnetometer (VSM). The results confirmed that magnetic microcapsules prepared by T-MC reactor were regular in shape.
