In order to provide a new way for waste cooking oil(WCO) resource utilization, several diester derivatives were obtained from WCO through a three-step chemical modifications, viz.: transesterification, epoxidation and...In order to provide a new way for waste cooking oil(WCO) resource utilization, several diester derivatives were obtained from WCO through a three-step chemical modifications, viz.: transesterification, epoxidation and oxirane ring opening with carboxylic acids. The effects of the chain length of side chain groups on the viscosity, acid value, low temperature fluidity, thermo-oxidative stability, tribological properties and surface tension of diester derivatives were investigated. The results showed that increasing the chain length of side chain groups had a positive influence on the viscosity, viscosity index, acid value, pour point, friction coefficient and wear scar diameter along with a negative influence on the oxidation onset temperature, volatile loss, insoluble deposit, maximum non-seizure load and surface tension. These diester derivatives exhibited improved physicochemical and tribological properties that make themselves promising environmentally friendly biolubricant basestocks.展开更多
Aqueous lubrication is commonly regarded as friendly to the environment.We review current knowledge of the behaviors and mechanisms of aqueous lubrication.Major methods for investigating aqueous lubrication are addres...Aqueous lubrication is commonly regarded as friendly to the environment.We review current knowledge of the behaviors and mechanisms of aqueous lubrication.Major methods for investigating aqueous lubrication are addressed.We describe studies on both friction and film formation performance of various water-based lubricants,Additionally,we discuss possible underlying mechanisms of aqueous lubrication.Attention is also drawn to continuing topics of investigation and some unsolved problems.展开更多
基金the financial support from the Natural Science Foundation of Chongqing(Project No.cstc2014jcyj A90013)
文摘In order to provide a new way for waste cooking oil(WCO) resource utilization, several diester derivatives were obtained from WCO through a three-step chemical modifications, viz.: transesterification, epoxidation and oxirane ring opening with carboxylic acids. The effects of the chain length of side chain groups on the viscosity, acid value, low temperature fluidity, thermo-oxidative stability, tribological properties and surface tension of diester derivatives were investigated. The results showed that increasing the chain length of side chain groups had a positive influence on the viscosity, viscosity index, acid value, pour point, friction coefficient and wear scar diameter along with a negative influence on the oxidation onset temperature, volatile loss, insoluble deposit, maximum non-seizure load and surface tension. These diester derivatives exhibited improved physicochemical and tribological properties that make themselves promising environmentally friendly biolubricant basestocks.
基金supported by the National Natural Science Foundation of China(51021064 and 51075227)
文摘Aqueous lubrication is commonly regarded as friendly to the environment.We review current knowledge of the behaviors and mechanisms of aqueous lubrication.Major methods for investigating aqueous lubrication are addressed.We describe studies on both friction and film formation performance of various water-based lubricants,Additionally,we discuss possible underlying mechanisms of aqueous lubrication.Attention is also drawn to continuing topics of investigation and some unsolved problems.
