The thermodynamic and kinetic mechanisms of Taixi anthracite during its graphitization process were explored.To understand the variation trends of carbon arrangement order,microcrystal size,and graphitization degree a...The thermodynamic and kinetic mechanisms of Taixi anthracite during its graphitization process were explored.To understand the variation trends of carbon arrangement order,microcrystal size,and graphitization degree against temperature during the graphitization process,a series of experiments were performed using Raman spectroscopy and X-ray diffraction(XRD).Subsequently,the influencing factors of the dominant reaction at different temperatures were analyzed using thermodynamics and kinetics.The results showed that the graphitization process of Taixi anthracite can be divided into three stages from the perspective of reaction thermodynamics and kinetics.Temperature played a crucial role in the formation and growth of a graphitic structure.Meanwhile,multivariate mechanisms coexisted in the graphitization process.At ultrahigh temperatures,the defects of synthetic graphite could not be completely eliminated and perfect graphite crystals could not be produced.At low temperatures,the reaction is mainly controlled by dynamics,while at high temperatures,thermodynamics dominates the direction of the reaction.展开更多
The three-dimensional(3 D) structures of pores directly affect the CH4 flow.Therefore,it is very important to analyze the3 D spatial structure of pores and to simulate the CH4 flow with the connected pores as the carr...The three-dimensional(3 D) structures of pores directly affect the CH4 flow.Therefore,it is very important to analyze the3 D spatial structure of pores and to simulate the CH4 flow with the connected pores as the carrier.The result shows that the equivalent radius of pores and throats are 1-16 μm and 1.03-8.9 μm,respectively,and the throat length is 3.28-231.25 μm.The coordination number of pores concentrates around three,and the intersection point between the connectivity function and the X-axis is 3-4 μm,which indicate the macro-pores have good connectivity.During the single-channel flow,the pressure decreases along the direction of CH4 flow,and the flow velocity of CH4 decreases from the pore center to the wall.Under the dual-channel and the multi-channel flows,the pressure also decreases along the CH4 flow direction,while the velocity increases.The mean flow pressure gradually decreases with the increase of the distance from the inlet slice.The change of mean flow pressure is relatively stable in the direction horizontal to the bedding plane,while it is relatively large in the direction perpendicular to the bedding plane.The mean flow velocity in the direction horizontal to the bedding plane(Y-axis) is the largest,followed by that in the direction horizontal to the bedding plane(X-axis),and the mean flow velocity in the direction perpendicular to the bedding plane is the smallest.展开更多
基金Projects(51704204,51974194,52104097)supported by the National Natural Science Foundation of ChinaProjects(20210302123147,20210302124352)supported by the Basic Research Program of Shanxi Province,China。
基金financially supported by the China Postdoctoral Science Foundation and China National “Twelfth Five-Year” Plan for Science & Technology (No. 2014BAB01B02)Shenhua Ningxia Coal Industry Group for financial support and providing Taixi anthracite samplesthe support of Advanced Analysis & Computation Center of China University of Mining and Technology
文摘The thermodynamic and kinetic mechanisms of Taixi anthracite during its graphitization process were explored.To understand the variation trends of carbon arrangement order,microcrystal size,and graphitization degree against temperature during the graphitization process,a series of experiments were performed using Raman spectroscopy and X-ray diffraction(XRD).Subsequently,the influencing factors of the dominant reaction at different temperatures were analyzed using thermodynamics and kinetics.The results showed that the graphitization process of Taixi anthracite can be divided into three stages from the perspective of reaction thermodynamics and kinetics.Temperature played a crucial role in the formation and growth of a graphitic structure.Meanwhile,multivariate mechanisms coexisted in the graphitization process.At ultrahigh temperatures,the defects of synthetic graphite could not be completely eliminated and perfect graphite crystals could not be produced.At low temperatures,the reaction is mainly controlled by dynamics,while at high temperatures,thermodynamics dominates the direction of the reaction.
基金financially supported by the National Key Research and Development Plan(No.2018YFB0605601)the National Natural Science Foundation of China(No.41972168)。
文摘The three-dimensional(3 D) structures of pores directly affect the CH4 flow.Therefore,it is very important to analyze the3 D spatial structure of pores and to simulate the CH4 flow with the connected pores as the carrier.The result shows that the equivalent radius of pores and throats are 1-16 μm and 1.03-8.9 μm,respectively,and the throat length is 3.28-231.25 μm.The coordination number of pores concentrates around three,and the intersection point between the connectivity function and the X-axis is 3-4 μm,which indicate the macro-pores have good connectivity.During the single-channel flow,the pressure decreases along the direction of CH4 flow,and the flow velocity of CH4 decreases from the pore center to the wall.Under the dual-channel and the multi-channel flows,the pressure also decreases along the CH4 flow direction,while the velocity increases.The mean flow pressure gradually decreases with the increase of the distance from the inlet slice.The change of mean flow pressure is relatively stable in the direction horizontal to the bedding plane,while it is relatively large in the direction perpendicular to the bedding plane.The mean flow velocity in the direction horizontal to the bedding plane(Y-axis) is the largest,followed by that in the direction horizontal to the bedding plane(X-axis),and the mean flow velocity in the direction perpendicular to the bedding plane is the smallest.
