This study was conducted to distinguish the compositions and provenance of sandstones and siltstones in the Ek1-Es3 members of Huimin （惠民） depression. The samples have been analyzed for petrographic, major element...This study was conducted to distinguish the compositions and provenance of sandstones and siltstones in the Ek1-Es3 members of Huimin （惠民） depression. The samples have been analyzed for petrographic, major element and selected trace element compositions （including REE）. The results show that the sandstones from the first member of Kongdian （孔店） Formation （Ek1） have higher quartz compositions than those from the fourth member （Es4） and the third member （Es3） of Shahejie （沙河街） Formation. The alkali feldspar/plagioclase ratio in the A-CN-K diagrams decreases in the order Ek1〉Es4〉Es3, which suggests that the Ek1 member had a more alkali feldspar-rich granitoid source and more intense weathering of the source than the Es4 and Es3 members. The mineral distributions in the A-CN-K diagrams also indicate that the sandstones and siltstones in the three members underwent K-metasomatism. Extrapolation of the sandstones and siltstones back to the plagioclase-alkali feldspar line in the A-CN-K diagram suggests a high average plagioclase to alkali feldspar ratio in the provenance （tonalite to granite）. In addition, the chemical index of weathering （CIW） and chemical index of alteration （CIA） parameters of the sandstones and siltstones suggest that the weathering of the first cycle material was intense, and the CIW decreases in the order Ek1〉Es4〉Es3 Trace element ratios suggest all the sedimentary rocks were mostly derived from granitoids. Elemental ratio plots （e.g., Th/Sc vs. Eu/Eu^＊） of sandstones and siltstones suggest a mix of a granodiorite-tonalite source as a source of the sandstones and siltstones. The sandstones and siltstones of Es3 and Es4 members also contain higher Eu/Eu＊ and lower Th/Sc ratios than the sandstones and siltstones of Ek1 member. As is consistent with the petrography, it suggests that the sandstones and siltstones of Es3 and Es4 members are derived from a source with less granite and more granodiorite-tonalite than the sandstones an展开更多
内蒙古白云鄂博矿床是世界最大的稀土矿之一,其矿床内部及周边出露有大量板岩并且板岩具多种颜色(黑色、黄绿色、深绿色等),板岩的研究程度相对较低。为了厘定板岩的矿物组成,本次研究应用玻片全扫描、TIMA(TESCAN Intergrated Mineral ...内蒙古白云鄂博矿床是世界最大的稀土矿之一,其矿床内部及周边出露有大量板岩并且板岩具多种颜色(黑色、黄绿色、深绿色等),板岩的研究程度相对较低。为了厘定板岩的矿物组成,本次研究应用玻片全扫描、TIMA(TESCAN Intergrated Mineral Analyzer)全扫描、电子探针、LA-ICP-MS(激光剥蚀电感耦合等离子体质谱仪)对其矿物组合特征和成分特征进行分析。玻片全扫描和TIMA全扫描比对表明板岩虽颜色各异,但主要由正长石组成,正长石体积比可达86.37%;在白云鄂博矿床范围内正长石有隐晶质、单晶集合体和单晶三种赋存形态。电子探针分析表明正长石中SiO_(2)为59.44%~64.76%、Al_(2)O_(3)为16.89%~19.73%、K_(2)O为13.96%~17.90%,K_(2)O/Na_(2)O为15.86~45.71;环带结构正长石K_(2)O的含量较其它正长石较低,K_(2)O/Na_(2)O为15.86~20.85。LA-ICP-MS分析表明正长石中Ba含量为700.08×10^(-6)~47 606.91×10^(-6),其它微量元素和稀土元素含量很少且差异不大。板岩整体颜色和正长石色带均具有随着Ba含量增多而颜色变深的现象,因此正长石的颜色深浅与Ba含量多少呈正相关关系。展开更多
基金the National High Technology Research and Development Program of China (No. 2006AA09Z336).
文摘This study was conducted to distinguish the compositions and provenance of sandstones and siltstones in the Ek1-Es3 members of Huimin （惠民） depression. The samples have been analyzed for petrographic, major element and selected trace element compositions （including REE）. The results show that the sandstones from the first member of Kongdian （孔店） Formation （Ek1） have higher quartz compositions than those from the fourth member （Es4） and the third member （Es3） of Shahejie （沙河街） Formation. The alkali feldspar/plagioclase ratio in the A-CN-K diagrams decreases in the order Ek1〉Es4〉Es3, which suggests that the Ek1 member had a more alkali feldspar-rich granitoid source and more intense weathering of the source than the Es4 and Es3 members. The mineral distributions in the A-CN-K diagrams also indicate that the sandstones and siltstones in the three members underwent K-metasomatism. Extrapolation of the sandstones and siltstones back to the plagioclase-alkali feldspar line in the A-CN-K diagram suggests a high average plagioclase to alkali feldspar ratio in the provenance （tonalite to granite）. In addition, the chemical index of weathering （CIW） and chemical index of alteration （CIA） parameters of the sandstones and siltstones suggest that the weathering of the first cycle material was intense, and the CIW decreases in the order Ek1〉Es4〉Es3 Trace element ratios suggest all the sedimentary rocks were mostly derived from granitoids. Elemental ratio plots （e.g., Th/Sc vs. Eu/Eu^＊） of sandstones and siltstones suggest a mix of a granodiorite-tonalite source as a source of the sandstones and siltstones. The sandstones and siltstones of Es3 and Es4 members also contain higher Eu/Eu＊ and lower Th/Sc ratios than the sandstones and siltstones of Ek1 member. As is consistent with the petrography, it suggests that the sandstones and siltstones of Es3 and Es4 members are derived from a source with less granite and more granodiorite-tonalite than the sandstones an
文摘内蒙古白云鄂博矿床是世界最大的稀土矿之一,其矿床内部及周边出露有大量板岩并且板岩具多种颜色(黑色、黄绿色、深绿色等),板岩的研究程度相对较低。为了厘定板岩的矿物组成,本次研究应用玻片全扫描、TIMA(TESCAN Intergrated Mineral Analyzer)全扫描、电子探针、LA-ICP-MS(激光剥蚀电感耦合等离子体质谱仪)对其矿物组合特征和成分特征进行分析。玻片全扫描和TIMA全扫描比对表明板岩虽颜色各异,但主要由正长石组成,正长石体积比可达86.37%;在白云鄂博矿床范围内正长石有隐晶质、单晶集合体和单晶三种赋存形态。电子探针分析表明正长石中SiO_(2)为59.44%~64.76%、Al_(2)O_(3)为16.89%~19.73%、K_(2)O为13.96%~17.90%,K_(2)O/Na_(2)O为15.86~45.71;环带结构正长石K_(2)O的含量较其它正长石较低,K_(2)O/Na_(2)O为15.86~20.85。LA-ICP-MS分析表明正长石中Ba含量为700.08×10^(-6)~47 606.91×10^(-6),其它微量元素和稀土元素含量很少且差异不大。板岩整体颜色和正长石色带均具有随着Ba含量增多而颜色变深的现象,因此正长石的颜色深浅与Ba含量多少呈正相关关系。
