A simple, fast and reliable method was developed for the analysis of jinggangmycin A （validamycin A） in commercial formulations. The running buffer used was acetate buffer （100 mmol/L, pH 4.7） with 15 kV as the ap...A simple, fast and reliable method was developed for the analysis of jinggangmycin A （validamycin A） in commercial formulations. The running buffer used was acetate buffer （100 mmol/L, pH 4.7） with 15 kV as the applied voltage. The detection was achieved by using direct UV mode at 200 nm and the detection limit was 0.2 μg/mL. Linearity in the concentration range of 5-500 μg/mL was excellent （RE 〉 0.999）. The run-to-run repeatability （n = 3）, as expressed by the relative standard deviation （RSD） for migration times and peak areas were less than 0.5% and 3.0% respectively. The mean recovery ranged from 97.2% to 101.4%.展开更多
以钛酸正四丁酯为钛源、甲酸锂为锂源、柠檬酸为碳源、脲作为氮源,采用溶胶-凝胶法制备出了氮修饰碳包覆钛酸锂(Li_4Ti_5O_(12)/NC)的复合电极材料。借助X射线衍射仪(XRD)、X射线光电子能谱分析仪(XPS)、傅里叶变换红外光谱仪(FTIR)、...以钛酸正四丁酯为钛源、甲酸锂为锂源、柠檬酸为碳源、脲作为氮源,采用溶胶-凝胶法制备出了氮修饰碳包覆钛酸锂(Li_4Ti_5O_(12)/NC)的复合电极材料。借助X射线衍射仪(XRD)、X射线光电子能谱分析仪(XPS)、傅里叶变换红外光谱仪(FTIR)、热重分析仪(TGA)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)对Li_4Ti_5O_(12)/NC的晶体结构、组成和形貌进行了表征分析,结果表明,所得产物是由尖晶石结构Li_4Ti_5O_(12)外围包覆NC组成。恒电流充放电实验结果显示,碳氮包覆量为9.48%的Li_4Ti_5O_(12)/NC材料在1C下首次放电比容量为212.9 m A·h/g,充放电循环100周后仍能保持160.1 m A·h/g的较高比容量。碳氮包覆不会改变材料的晶型,但能有效抑制复合材料粒径增大,同时增加复合材料锂脱嵌活性位点,提高其比容量和导电性。展开更多
By introducing the mechanical motion into the confined etchant layer technique(CELT), we have developed a promising ultraprecision machining method, termed as electrochemical mechanical micromachining(ECMM), for produ...By introducing the mechanical motion into the confined etchant layer technique(CELT), we have developed a promising ultraprecision machining method, termed as electrochemical mechanical micromachining(ECMM), for producing both regular and irregular three dimensional(3 D) microstructures. It was found that there was a dramatic coupling effect between the confined etching process and the slow-rate mechanical motion because of the concentration distribution of electrogenerated etchant caused by the latter. In this article, the coupling effect was investigated systemically by comparing the etchant diffusion, etching depths and profiles in the non-confined and confined machining modes. A two-dimensional(2 D) numerical simulation model was proposed to analyze the diffusion variations during the ECMM process, which is well verified by the machining experiments. The results showed that, in the confined machining mode, both the machining resolution and the perpendicularity tolerance of side faces were improved effectively. Furthermore, the theoretical modeling and numerical simulations were proved valuable to optimize the technical parameters of the ECMM process.展开更多
文摘A simple, fast and reliable method was developed for the analysis of jinggangmycin A （validamycin A） in commercial formulations. The running buffer used was acetate buffer （100 mmol/L, pH 4.7） with 15 kV as the applied voltage. The detection was achieved by using direct UV mode at 200 nm and the detection limit was 0.2 μg/mL. Linearity in the concentration range of 5-500 μg/mL was excellent （RE 〉 0.999）. The run-to-run repeatability （n = 3）, as expressed by the relative standard deviation （RSD） for migration times and peak areas were less than 0.5% and 3.0% respectively. The mean recovery ranged from 97.2% to 101.4%.
文摘以钛酸正四丁酯为钛源、甲酸锂为锂源、柠檬酸为碳源、脲作为氮源,采用溶胶-凝胶法制备出了氮修饰碳包覆钛酸锂(Li_4Ti_5O_(12)/NC)的复合电极材料。借助X射线衍射仪(XRD)、X射线光电子能谱分析仪(XPS)、傅里叶变换红外光谱仪(FTIR)、热重分析仪(TGA)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)对Li_4Ti_5O_(12)/NC的晶体结构、组成和形貌进行了表征分析,结果表明,所得产物是由尖晶石结构Li_4Ti_5O_(12)外围包覆NC组成。恒电流充放电实验结果显示,碳氮包覆量为9.48%的Li_4Ti_5O_(12)/NC材料在1C下首次放电比容量为212.9 m A·h/g,充放电循环100周后仍能保持160.1 m A·h/g的较高比容量。碳氮包覆不会改变材料的晶型,但能有效抑制复合材料粒径增大,同时增加复合材料锂脱嵌活性位点,提高其比容量和导电性。
基金supported by the National Natural Science Foundation of China (21573054, 21327002, 91323303, 21621091)the Joint Funds Key Project of the National Natural Science Foundation of China (U1537214)+2 种基金the State Key Program of National Natural Science of China (51535003)Self-Planned Task (SKLRS201606B) of State Key Laboratory of Robotics and System (HIT)the Open Project of the State Key Laboratory for Manufacturing Systems Engineering (Xi'an Jiaotong University)
文摘By introducing the mechanical motion into the confined etchant layer technique(CELT), we have developed a promising ultraprecision machining method, termed as electrochemical mechanical micromachining(ECMM), for producing both regular and irregular three dimensional(3 D) microstructures. It was found that there was a dramatic coupling effect between the confined etching process and the slow-rate mechanical motion because of the concentration distribution of electrogenerated etchant caused by the latter. In this article, the coupling effect was investigated systemically by comparing the etchant diffusion, etching depths and profiles in the non-confined and confined machining modes. A two-dimensional(2 D) numerical simulation model was proposed to analyze the diffusion variations during the ECMM process, which is well verified by the machining experiments. The results showed that, in the confined machining mode, both the machining resolution and the perpendicularity tolerance of side faces were improved effectively. Furthermore, the theoretical modeling and numerical simulations were proved valuable to optimize the technical parameters of the ECMM process.
