The microstructures of {111}<uvw> grain were characterized in detailed and systematically investigated with the aid of electron backscatter diffraction(EBSD) and transmission electron microscope(TEM). The stored...The microstructures of {111}<uvw> grain were characterized in detailed and systematically investigated with the aid of electron backscatter diffraction(EBSD) and transmission electron microscope(TEM). The stored energy in different regions in the grain was evaluated by the band contrast values collected from EBSD. The results show that the distribution of energy is inhomogeneous through the grain. Especially,the regions containing the least and the largest energy were extracted from the EBSD data, and then quantitatively analyzed based on the misorientation and Schmid factor. Many peaks with large misorientation appeared in the region containing larger energy, and these peaks represent the existences of micro-bands and micro-shear bands in {111} grain. The results of Schmid factor suggest that the region containing larger energy is prone to deforming ahead of the region with less stored energy, implying the more serious subdivision of the microstructure of region with larger stored energy.展开更多
针对具有较大多普勒扩展和时延扩展的车载通信环境,利用后训练序列信道响应携带的信道变化信息,提出一种结合后训练序列的判决反馈信道估计方法。该方法采用最小二乘算法估计后训练序列的信道响应;对前一个正交频分复用(orthogonal freq...针对具有较大多普勒扩展和时延扩展的车载通信环境,利用后训练序列信道响应携带的信道变化信息,提出一种结合后训练序列的判决反馈信道估计方法。该方法采用最小二乘算法估计后训练序列的信道响应;对前一个正交频分复用(orthogonal frequency division multiplexing,OFDM)符号和后训练序列的信道响应估计值进行系数加权求和来估计当前OFDM符号的信道响应,并利用其4个导频子载波的信道频率响应关系自动获取加权系数;最后,对获得的信道响应估计值进行判决反馈和低通滤波以降低噪声影响。仿真结果表明,与目前取得较好性能的STA(spectral temporal averaging)方法、CDP(constructing data pilot)方法和结合平滑滤波的判决反馈信道估计方法相比,所提方法具有更优的误包率性能。展开更多
在液滴外延生长过程中金属液滴承担着生长前驱体的角色,直接决定着后续量子环、量子点、纳米线等量子结构的密度、尺寸、位置等参数.本文开展了在MBE(molecular beam epitaxy)液滴外延过程中通过原位激光作用调控金属Ga-droplet的前沿研...在液滴外延生长过程中金属液滴承担着生长前驱体的角色,直接决定着后续量子环、量子点、纳米线等量子结构的密度、尺寸、位置等参数.本文开展了在MBE(molecular beam epitaxy)液滴外延过程中通过原位激光作用调控金属Ga-droplet的前沿研究.首先利用MBE在GaAs(001)衬底上(150℃)沉积6 ML Ga原子以获得Ga-droplet密度约为5.7×10^(10) cm^(-2)的表面,然后原位引入单脉冲单束激光辐照衬底表面.实验观察到:Ga-droplet在激光辐照(能量密度大于10 m J/cm^2)的条件下将开始克服表面各个方向的迁移势垒发生显著而丰富的迁移行为,且这种迁移的剧烈程度与激光能量具有强烈的正相关规律.伴随这种迁移,不同Ga-droplet之间将发生随机的融合,从而强烈影响其密度以及尺寸.统计表明:当激光能量从10 m J/cm^2提高至30 m J/cm^2时,Ga-droplet的密度将迅速减小到近原来的三分之一,同时尺寸则迅速地增大,且整体分布由传统的"窄带"向"宽带"特点过渡.故通过本文的研究,证实和发现了液滴存在着极为敏感的表面"光致迁移"特性.凭借这一特性,不仅可实现对液滴整体尺寸、密度的二次修饰,获得一些在传统液滴外延中难以实现的分布特点,而且在将来我们完全有望凭借多光束干涉图形化调控液滴,最终实现人为可控的液滴外延技术,从而极大地推动整个低维纳米半导体材料的生长.展开更多
作为一种具有广泛应用前景的高效电合成技术,耦合电溶解的铪醇盐合成(EHS)基于铪溶解/乙醇脱氢的同时非均相反应以及溶液中Hf^(4+)阳离子和烷氧阴离子的自发结合反应。为了阐明EHS过程的机制和动力学,通过电化学测试、扫描电镜、气相色...作为一种具有广泛应用前景的高效电合成技术,耦合电溶解的铪醇盐合成(EHS)基于铪溶解/乙醇脱氢的同时非均相反应以及溶液中Hf^(4+)阳离子和烷氧阴离子的自发结合反应。为了阐明EHS过程的机制和动力学,通过电化学测试、扫描电镜、气相色谱和微观动力学模拟等手段,探究阳极铪溶解和阴极乙醇脱氢的电化学行为。结果表明,优选的支持电解质四乙基氯化铵(Et_(4)NCl)展现了钝化膜击穿与铪溶解协同的剧烈点蚀机制以及两段脱氢机制。为量化钝化膜击穿和铪点蚀的动力学参数,提取与钝化速率、钝化膜击穿敏感性和点蚀速率相关的3个指标,并通过建立微观动力学模型评估基于Et_(4)NCl体系的EHS工艺,其电能消耗为1.53~1.83 k W·h/kg Hf(OC_(2)H_(5))_(4)。展开更多
基金supported by the National Natural Science Foundation of China(Grants 51421001,51504051 and 51701032)the Chongqing Science and Technology Commission in China(CSTC,2017jcyjAX0094 and cstc2015jcyjA90001
文摘The microstructures of {111}<uvw> grain were characterized in detailed and systematically investigated with the aid of electron backscatter diffraction(EBSD) and transmission electron microscope(TEM). The stored energy in different regions in the grain was evaluated by the band contrast values collected from EBSD. The results show that the distribution of energy is inhomogeneous through the grain. Especially,the regions containing the least and the largest energy were extracted from the EBSD data, and then quantitatively analyzed based on the misorientation and Schmid factor. Many peaks with large misorientation appeared in the region containing larger energy, and these peaks represent the existences of micro-bands and micro-shear bands in {111} grain. The results of Schmid factor suggest that the region containing larger energy is prone to deforming ahead of the region with less stored energy, implying the more serious subdivision of the microstructure of region with larger stored energy.
文摘针对具有较大多普勒扩展和时延扩展的车载通信环境,利用后训练序列信道响应携带的信道变化信息,提出一种结合后训练序列的判决反馈信道估计方法。该方法采用最小二乘算法估计后训练序列的信道响应;对前一个正交频分复用(orthogonal frequency division multiplexing,OFDM)符号和后训练序列的信道响应估计值进行系数加权求和来估计当前OFDM符号的信道响应,并利用其4个导频子载波的信道频率响应关系自动获取加权系数;最后,对获得的信道响应估计值进行判决反馈和低通滤波以降低噪声影响。仿真结果表明,与目前取得较好性能的STA(spectral temporal averaging)方法、CDP(constructing data pilot)方法和结合平滑滤波的判决反馈信道估计方法相比,所提方法具有更优的误包率性能。
文摘在液滴外延生长过程中金属液滴承担着生长前驱体的角色,直接决定着后续量子环、量子点、纳米线等量子结构的密度、尺寸、位置等参数.本文开展了在MBE(molecular beam epitaxy)液滴外延过程中通过原位激光作用调控金属Ga-droplet的前沿研究.首先利用MBE在GaAs(001)衬底上(150℃)沉积6 ML Ga原子以获得Ga-droplet密度约为5.7×10^(10) cm^(-2)的表面,然后原位引入单脉冲单束激光辐照衬底表面.实验观察到:Ga-droplet在激光辐照(能量密度大于10 m J/cm^2)的条件下将开始克服表面各个方向的迁移势垒发生显著而丰富的迁移行为,且这种迁移的剧烈程度与激光能量具有强烈的正相关规律.伴随这种迁移,不同Ga-droplet之间将发生随机的融合,从而强烈影响其密度以及尺寸.统计表明:当激光能量从10 m J/cm^2提高至30 m J/cm^2时,Ga-droplet的密度将迅速减小到近原来的三分之一,同时尺寸则迅速地增大,且整体分布由传统的"窄带"向"宽带"特点过渡.故通过本文的研究,证实和发现了液滴存在着极为敏感的表面"光致迁移"特性.凭借这一特性,不仅可实现对液滴整体尺寸、密度的二次修饰,获得一些在传统液滴外延中难以实现的分布特点,而且在将来我们完全有望凭借多光束干涉图形化调控液滴,最终实现人为可控的液滴外延技术,从而极大地推动整个低维纳米半导体材料的生长.
基金Science and Technology Innovation Program of Hunan Province,China(No.2021RC2002)Yangfan Plan,China(No.2017YT05C107)。
文摘作为一种具有广泛应用前景的高效电合成技术,耦合电溶解的铪醇盐合成(EHS)基于铪溶解/乙醇脱氢的同时非均相反应以及溶液中Hf^(4+)阳离子和烷氧阴离子的自发结合反应。为了阐明EHS过程的机制和动力学,通过电化学测试、扫描电镜、气相色谱和微观动力学模拟等手段,探究阳极铪溶解和阴极乙醇脱氢的电化学行为。结果表明,优选的支持电解质四乙基氯化铵(Et_(4)NCl)展现了钝化膜击穿与铪溶解协同的剧烈点蚀机制以及两段脱氢机制。为量化钝化膜击穿和铪点蚀的动力学参数,提取与钝化速率、钝化膜击穿敏感性和点蚀速率相关的3个指标,并通过建立微观动力学模型评估基于Et_(4)NCl体系的EHS工艺,其电能消耗为1.53~1.83 k W·h/kg Hf(OC_(2)H_(5))_(4)。
