Physical and chemical properties of the magnetic nanoparticles coated with oleate have been investigated by means of transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Mossbauer spectroscopy, su...Physical and chemical properties of the magnetic nanoparticles coated with oleate have been investigated by means of transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Mossbauer spectroscopy, superconducting quantum interference device (SQUID) magnetometry, infrared spectra (IR) and the contact angle device. The results show that doped Al ions in Fe3O4 nanoparticles are located on the octahedral sites of the spinel structure. Oleate is coated on the magnetic nanoparticles with two layers by chemical absorbing, the outer layer can be washed away. The wetting of the surface of magnetic nanoparticles coated with monolayer has been changed from hydrophilicity to hydrophobicity, and the nanoparticles can be dispersed very well in some organic solutions.展开更多
基金Hi-Tech Research and Develop-ment Program of China under the grant No.2002AA302202 the National Natural Scicnce Foundation of China through grant No.20490210.
文摘Physical and chemical properties of the magnetic nanoparticles coated with oleate have been investigated by means of transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Mossbauer spectroscopy, superconducting quantum interference device (SQUID) magnetometry, infrared spectra (IR) and the contact angle device. The results show that doped Al ions in Fe3O4 nanoparticles are located on the octahedral sites of the spinel structure. Oleate is coated on the magnetic nanoparticles with two layers by chemical absorbing, the outer layer can be washed away. The wetting of the surface of magnetic nanoparticles coated with monolayer has been changed from hydrophilicity to hydrophobicity, and the nanoparticles can be dispersed very well in some organic solutions.
