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苯基取代苯并二噻吩二酮构建新型聚合物及其光伏性能研究
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作者 邓燧楠 刘海珍 +6 位作者 张连杰 罗文君 罗妹 张泽升 梁嘉豪 王新康 陈军武 《化学学报》 SCIE CAS CSCD 北大核心 2024年第3期257-264,共8页
随着材料和器件的不断发展,有机光伏(OPV)的器件效率不断提升,但制备仍存在较多额外加工工艺,不利于其大规模生产.如何合理调控活性层材料的溶解性、结晶性和两相形貌来简化器件制备工艺,实现高性能的as-cast器件将十分具有科学意义.本... 随着材料和器件的不断发展,有机光伏(OPV)的器件效率不断提升,但制备仍存在较多额外加工工艺,不利于其大规模生产.如何合理调控活性层材料的溶解性、结晶性和两相形貌来简化器件制备工艺,实现高性能的as-cast器件将十分具有科学意义.本工作通过设计合成苯基取代的苯并二噻吩二酮单元(二维BDD)作为共聚单元,制备了三种新型聚合物材料.当二维BDD单元摩尔分数为10%时, FBDT-m10能实现良好的聚集性能和加工性能,与Y6-BO共混制备的as-cast器件就可以得到良好的活性层形貌,最终实现了71.14%的填充因子及16.06%的器件效率. 展开更多
关键词 芳香取代 苯并二噻吩二酮 聚合物给体 有机太阳电池
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Determination of Work Function for p-and n-Type 4H-SiC Single Crystals via Scanning Kelvin Probe Force Microscopy
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作者 李辉 王国宾 +3 位作者 杨靖宇 张泽盛 邓俊 杜世萱 《Chinese Physics Letters》 SCIE EI CAS CSCD 2023年第12期160-166,共7页
Silicon carbide(SiC) is a promising platform for fabricating high-voltage, high-frequency and high-temperature electronic devices such as metal oxide semiconductor field effect transistors in which many junctions or i... Silicon carbide(SiC) is a promising platform for fabricating high-voltage, high-frequency and high-temperature electronic devices such as metal oxide semiconductor field effect transistors in which many junctions or interfaces are involved. The work function(WF) plays an essential role in these devices. However, studies of the effect of conductive type and polar surfaces on the WF of SiC are limited. Here, we report the measurement of WFs of Si-and C-terminated polar surfaces for both p-type and n-type conductive 4H-SiC single crystals by scanning Kelvin probe microscopy(SKPFM). The results show that p-type SiC exhibits a higher WF than n-type SiC.The WF of a C-terminated polar surface is higher than that of a Si-terminated polar surface, which is further confirmed by first-principles calculations. By revealing this long-standing knowledge gap, our work facilitates the fabrication and development of SiC-based electronic devices, which have tremendous potential applications in electric vehicles, photovoltaics, and so on. This work also shows that SKPFM is a good method for identifying polar surfaces of SiC and other polar materials nondestructively, quickly and conveniently. 展开更多
关键词 terminated PROBE CONDUCTIVE
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Theoretical Study of Coupling Mechanism between FBG and Shock Waves of Rock Burst
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作者 Shiming Wei zesheng zhang Yao Wang 《World Journal of Engineering and Technology》 2020年第4期784-791,共8页
To achieve the monitor of rock burst in coal mine with fiber Bragg grating (FBG) sensing, the coupling mechanism between FBG and shock waves w<span style="font-family:;" "="">as</span... To achieve the monitor of rock burst in coal mine with fiber Bragg grating (FBG) sensing, the coupling mechanism between FBG and shock waves w<span style="font-family:;" "="">as</span><span style="font-family:;" "=""> theoretically analyzed. Based on Housner’s random shock model, the coupling mechanism between shock waves and FBG was theoretically analyzed. The result shows that the wave will change the period </span><span><span style="white-space:nowrap;">&#581</span></span><span style="font-family:;" "=""> and effective refractive index </span><i><span style="font-family:;" "="">n</span></i><span style="font-family:;" "=""> of FBG, and further affect the initial wavelength value. The amplitude, phase and frequency of shock wave are directly related to the wavelength drifts of FBG. The transmitting velocity of shock wave in rock is affected by lithologic characteristics. The Elastic modulus, density and Poisson’s ratio of rock influence the initial wavelength value of FBG. This study provided a theoretical basis and practical application guidance for coal or rock burst monitoring with FBG sensing.</span> 展开更多
关键词 Rock Burst FBG Shock Waves Lithological Characteristics
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