A stability analysis approach of tunnel face considering a longitudinally inclined tunnel angle and anisotropic purely cohesive soils based on a continuous velocity field (CVF) is investigated in this study. Based on ...A stability analysis approach of tunnel face considering a longitudinally inclined tunnel angle and anisotropic purely cohesive soils based on a continuous velocity field (CVF) is investigated in this study. Based on the kinematic approach of limit analysis and the discretization technique, an improved three-dimensional CVF model for longitudinally inclined tunnels driven by pressurized shields is proposed. With the proposed model, the critical support pressure acted on tunnel face is determined by the work-balance equation. A serial of finite element numerical models are conducted to validate the proposed model. Finally, the effects of tunnel inclination angles, several dimensionless parameters as well as soil anisotropy on the critical support pressure are investigated. The numerical results show that the effects of the soil anisotropy and the tunnel inclination angle on tunnel faces should be considered in the actual design of tunneling engineering.展开更多
To address the seismic face stability challenges encountered in urban and subsea tunnel construction,an efficient probabilistic analysis framework for shield tunnel faces under seismic conditions is proposed.Based on ...To address the seismic face stability challenges encountered in urban and subsea tunnel construction,an efficient probabilistic analysis framework for shield tunnel faces under seismic conditions is proposed.Based on the upper-bound theory of limit analysis,an improved three-dimensional discrete deterministic mechanism,accounting for the heterogeneous nature of soil media,is formulated to evaluate seismic face stability.The metamodel of failure probabilistic assessments for seismic tunnel faces is constructed by integrating the sparse polynomial chaos expansion method(SPCE)with the modified pseudo-dynamic approach(MPD).The improved deterministic model is validated by comparing with published literature and numerical simulations results,and the SPCE-MPD metamodel is examined with the traditional MCS method.Based on the SPCE-MPD metamodels,the seismic effects on face failure probability and reliability index are presented and the global sensitivity analysis(GSA)is involved to reflect the influence order of seismic action parameters.Finally,the proposed approach is tested to be effective by a engineering case of the Chengdu outer ring tunnel.The results show that higher uncertainty of seismic response on face stability should be noticed in areas with intense earthquakes and variation of seismic wave velocity has the most profound influence on tunnel face stability.展开更多
One novel（named palcernuine, 1） and five known cernuane-type（2–6） alkaloids were isolated from the whole plant of Palhinhaea cernua f. sikkimensis. The structure of 1, possessing an unprecedented [5/6/6/6]-tetrac...One novel（named palcernuine, 1） and five known cernuane-type（2–6） alkaloids were isolated from the whole plant of Palhinhaea cernua f. sikkimensis. The structure of 1, possessing an unprecedented [5/6/6/6]-tetracyclic ring system containing two nitrogen atoms, was established on the basis of spectroscopic methods, and its absolute configuration was determined by comparison of the experimental and calculated electronic circular dichroism（ECD） spectra. A plausible biosynthetic pathway to 1 is proposed.展开更多
We study the spectrum of single-photon emission and scattering in a mixed optomechanical model which consists of both linear and quadratic optomechanical interactions.The spectra are calculated based on the exact long...We study the spectrum of single-photon emission and scattering in a mixed optomechanical model which consists of both linear and quadratic optomechanical interactions.The spectra are calculated based on the exact longtime solutions of the single-photon emission and scattering processes in this system.We find that there exist some phonon sideband peaks in the spectra and there are some sub peaks around the phonon sideband peaks under proper parameter conditions.The correspondence between the spectral features and the optomechanical interactions is confirmed, and the optomechanical coupling strengths can be inferred by analyzing the resonance peaks and dips in the spectra.展开更多
We have developed a microwave-assisted hydrothermal method,where both microwave and hydrothermal techniques are utilized to synthesize CdTe nanocrystals with high quality in less than 55 s.Among the known preparation ...We have developed a microwave-assisted hydrothermal method,where both microwave and hydrothermal techniques are utilized to synthesize CdTe nanocrystals with high quality in less than 55 s.Among the known preparation methods,the monodisperse CdTe nanocrystals showing narrow emission spectra,widest scope of emission peak（from 500 nm to 822 nm） and high quantum yield（up to 80%） were synthesized by this route.The quantum yield of CdTe with near-infrared emission（800 nm） is up to 10%,which is better than that of InAs（0.5%―2%） synthesized in organic phase.Moreover,we detected the latent fingerprints on aluminum,plastic,glass and papers by prepared CdTe nanocrystals,and photoluminescence fingerprints images were taken with a digital camera.Then the images would transmitt into fingerprint detection system of computer to identify the criminals in suit.展开更多
Chiral polymer was synthesized by the polymerization of （R）-6,6＇-bistributylstannyl-2,2＇-binaphtho-20-crown-6 （M-1） with 1,4-dibromo-2,3-bisbutoxy-naphthyl （M-2） by Pd（PPhs）4 catalyzed Stille coupling reacti...Chiral polymer was synthesized by the polymerization of （R）-6,6＇-bistributylstannyl-2,2＇-binaphtho-20-crown-6 （M-1） with 1,4-dibromo-2,3-bisbutoxy-naphthyl （M-2） by Pd（PPhs）4 catalyzed Stille coupling reaction. Both monomer and polymer were analyzed by NMR, MS, FT-IR, UV, polarimetry, DSC-TGA, CD, fluorescent spectroscopy and GPC. The major difference between monomer and polymer is that a long wavelength Cotton Effect was observed for the polymer due to its more extended conjugation in the repeating unit and a highly rigid backbone in the polymer chain. Polymer has strong blue fluorescence due to the efficient energy migration from the extended n-electronic structure of the repeating unit of the polymer to the chiral binaphthyl core and is expected to have potential application in the materials of fluorescent sensors and chiral chromatographic packing for resolution ofracemic amino acid.展开更多
Chiral polymers P-1 and P-2 were synthesized by the polymerization of （R）-3,3＇-diiodo-2,2＇-bisbutoxy-1,1＇- binaphthyl （M- 1 ） with 2,5-di（4-ethynylphenyl）- 1,3,4-oxadiazole （M-3） and （R）-3,3＇-diethylnyl-...Chiral polymers P-1 and P-2 were synthesized by the polymerization of （R）-3,3＇-diiodo-2,2＇-bisbutoxy-1,1＇- binaphthyl （M- 1 ） with 2,5-di（4-ethynylphenyl）- 1,3,4-oxadiazole （M-3） and （R）-3,3＇-diethylnyl-2,2＇-bisbutoxy- 1,1 ＇-binaphthyl （M-2） with 1,2-di（4-bromophenyl）acetylene （M-4） under Sonogashira reaction, respectively. Both monomers and polymers were analyzed by NMR, MS, FT-IR, UV-Vis spectroscopy, DSC-TGA, fluorescence spectroscopy, GPC and CD spectroscopy. CD spectra of P-1 and P-2 are similar due to the same chiral center units and main chain structure. The long wavelengths CD effect of P-1 and P-2 can be regarded as the more extended conjugated structure and a highly rigid backbone in the polymer chain. Polymers have strong blue fluorescence due to the efficient energy migration from the extended n-electronic structure of the polymers to the chiral binaphthyl core and are expected to provide understanding of the relationship between molecular structure and fluorescent property of the chiral polymers.展开更多
基金Project(2017YFB1201204)supported by the National Key Research and Development Program of China
文摘A stability analysis approach of tunnel face considering a longitudinally inclined tunnel angle and anisotropic purely cohesive soils based on a continuous velocity field (CVF) is investigated in this study. Based on the kinematic approach of limit analysis and the discretization technique, an improved three-dimensional CVF model for longitudinally inclined tunnels driven by pressurized shields is proposed. With the proposed model, the critical support pressure acted on tunnel face is determined by the work-balance equation. A serial of finite element numerical models are conducted to validate the proposed model. Finally, the effects of tunnel inclination angles, several dimensionless parameters as well as soil anisotropy on the critical support pressure are investigated. The numerical results show that the effects of the soil anisotropy and the tunnel inclination angle on tunnel faces should be considered in the actual design of tunneling engineering.
基金Project([2018]3010)supported by the Guizhou Provincial Science and Technology Major Project,China。
文摘To address the seismic face stability challenges encountered in urban and subsea tunnel construction,an efficient probabilistic analysis framework for shield tunnel faces under seismic conditions is proposed.Based on the upper-bound theory of limit analysis,an improved three-dimensional discrete deterministic mechanism,accounting for the heterogeneous nature of soil media,is formulated to evaluate seismic face stability.The metamodel of failure probabilistic assessments for seismic tunnel faces is constructed by integrating the sparse polynomial chaos expansion method(SPCE)with the modified pseudo-dynamic approach(MPD).The improved deterministic model is validated by comparing with published literature and numerical simulations results,and the SPCE-MPD metamodel is examined with the traditional MCS method.Based on the SPCE-MPD metamodels,the seismic effects on face failure probability and reliability index are presented and the global sensitivity analysis(GSA)is involved to reflect the influence order of seismic action parameters.Finally,the proposed approach is tested to be effective by a engineering case of the Chengdu outer ring tunnel.The results show that higher uncertainty of seismic response on face stability should be noticed in areas with intense earthquakes and variation of seismic wave velocity has the most profound influence on tunnel face stability.
基金supported by NSFC grants (Nos. 21472021, 81273401, 81202420)grants from the Ph.D. Programs Foundation of Ministry of Education (MOE) of China (Nos. 20120071110049, 20120071120049)the National Basic Research Program of China (973 Program, No. 2013CB530700)
文摘One novel（named palcernuine, 1） and five known cernuane-type（2–6） alkaloids were isolated from the whole plant of Palhinhaea cernua f. sikkimensis. The structure of 1, possessing an unprecedented [5/6/6/6]-tetracyclic ring system containing two nitrogen atoms, was established on the basis of spectroscopic methods, and its absolute configuration was determined by comparison of the experimental and calculated electronic circular dichroism（ECD） spectra. A plausible biosynthetic pathway to 1 is proposed.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11505055,11822501,11774087Natural Science Foundation of Hunan Province China under Grant No.2017JJ1021Scientific Research Fund of Hunan Provincial Education Department under Grant No.18A007
文摘We study the spectrum of single-photon emission and scattering in a mixed optomechanical model which consists of both linear and quadratic optomechanical interactions.The spectra are calculated based on the exact longtime solutions of the single-photon emission and scattering processes in this system.We find that there exist some phonon sideband peaks in the spectra and there are some sub peaks around the phonon sideband peaks under proper parameter conditions.The correspondence between the spectral features and the optomechanical interactions is confirmed, and the optomechanical coupling strengths can be inferred by analyzing the resonance peaks and dips in the spectra.
基金Supported by the National Natural Science Foundation of China(Nos.20775076 and 20875084)the National Technology Research & Development Program in the 11th Five-Year Plan of China(No.2006BAK10B09)
文摘We have developed a microwave-assisted hydrothermal method,where both microwave and hydrothermal techniques are utilized to synthesize CdTe nanocrystals with high quality in less than 55 s.Among the known preparation methods,the monodisperse CdTe nanocrystals showing narrow emission spectra,widest scope of emission peak（from 500 nm to 822 nm） and high quantum yield（up to 80%） were synthesized by this route.The quantum yield of CdTe with near-infrared emission（800 nm） is up to 10%,which is better than that of InAs（0.5%―2%） synthesized in organic phase.Moreover,we detected the latent fingerprints on aluminum,plastic,glass and papers by prepared CdTe nanocrystals,and photoluminescence fingerprints images were taken with a digital camera.Then the images would transmitt into fingerprint detection system of computer to identify the criminals in suit.
基金This work was supported by the National Natural Science Foundation of China (No. 20474028)Jiangsu Provincial Natural Science Foundation (No. BK2004086).
文摘Chiral polymer was synthesized by the polymerization of （R）-6,6＇-bistributylstannyl-2,2＇-binaphtho-20-crown-6 （M-1） with 1,4-dibromo-2,3-bisbutoxy-naphthyl （M-2） by Pd（PPhs）4 catalyzed Stille coupling reaction. Both monomer and polymer were analyzed by NMR, MS, FT-IR, UV, polarimetry, DSC-TGA, CD, fluorescent spectroscopy and GPC. The major difference between monomer and polymer is that a long wavelength Cotton Effect was observed for the polymer due to its more extended conjugation in the repeating unit and a highly rigid backbone in the polymer chain. Polymer has strong blue fluorescence due to the efficient energy migration from the extended n-electronic structure of the repeating unit of the polymer to the chiral binaphthyl core and is expected to have potential application in the materials of fluorescent sensors and chiral chromatographic packing for resolution ofracemic amino acid.
基金This work was supported by the National Natural Science Foundation of China (No. 20474028)Jiangsu Provincial Natural Science Foundation (No. BK2004086)
文摘Chiral polymers P-1 and P-2 were synthesized by the polymerization of （R）-3,3＇-diiodo-2,2＇-bisbutoxy-1,1＇- binaphthyl （M- 1 ） with 2,5-di（4-ethynylphenyl）- 1,3,4-oxadiazole （M-3） and （R）-3,3＇-diethylnyl-2,2＇-bisbutoxy- 1,1 ＇-binaphthyl （M-2） with 1,2-di（4-bromophenyl）acetylene （M-4） under Sonogashira reaction, respectively. Both monomers and polymers were analyzed by NMR, MS, FT-IR, UV-Vis spectroscopy, DSC-TGA, fluorescence spectroscopy, GPC and CD spectroscopy. CD spectra of P-1 and P-2 are similar due to the same chiral center units and main chain structure. The long wavelengths CD effect of P-1 and P-2 can be regarded as the more extended conjugated structure and a highly rigid backbone in the polymer chain. Polymers have strong blue fluorescence due to the efficient energy migration from the extended n-electronic structure of the polymers to the chiral binaphthyl core and are expected to provide understanding of the relationship between molecular structure and fluorescent property of the chiral polymers.
