Supercapacitor is considered as one of the most promising energy storage systems because of its high power density, long life and low production cost. Electrode materials play important roles in the performance of Sup...Supercapacitor is considered as one of the most promising energy storage systems because of its high power density, long life and low production cost. Electrode materials play important roles in the performance of Supercapacitor (SC). In this study, Zn-based hydrotalcite structure materials are prepared by hydrothermal method. The influence of Zn/Al ratio in precursors on electrochemical properties of electrode materials is investigated. The results show that Al(III) promotes the formation of relatively ordered active substances and participates in redox reaction on electrode surface. Specific capacitance of Zn-based electrode reaches 2557 F<span style="white-space:nowrap;">·</span>g<sup>-1</sup> (1.0 A<span style="white-space:nowrap;">·</span>g<sup>-1</sup>) at Zn/Al molar ratio of 1:1 in precursors. This method is simple and environmentally friendly. The electrode exhibits excellent electrochemical activity and stability, showing this material application prospect for supercapacitor.展开更多
基金supported by the National Key R&D Program of China(2019YFA0906003)the National Natural Science Foundation of China(32000989)+5 种基金China Postdoctoral Science Foundation Grant(2020M682911 and 2020M670051ZX)Guangdong Special Support Program(2021JC06Y578)the Shenzhen Municipal Government of China(JCYJ20200109120016553,CJGJZD20200617102403009,and RCBS20210706092256081)the Sanming Project of Shenzhen Health and Family Planning Commission(SZSM202011017)Shenzhen Institute of Synthetic Biology Scientific Research Program(ZTXM20214005)the Shenzhen High-level Hospital Construction Fund。
文摘Supercapacitor is considered as one of the most promising energy storage systems because of its high power density, long life and low production cost. Electrode materials play important roles in the performance of Supercapacitor (SC). In this study, Zn-based hydrotalcite structure materials are prepared by hydrothermal method. The influence of Zn/Al ratio in precursors on electrochemical properties of electrode materials is investigated. The results show that Al(III) promotes the formation of relatively ordered active substances and participates in redox reaction on electrode surface. Specific capacitance of Zn-based electrode reaches 2557 F<span style="white-space:nowrap;">·</span>g<sup>-1</sup> (1.0 A<span style="white-space:nowrap;">·</span>g<sup>-1</sup>) at Zn/Al molar ratio of 1:1 in precursors. This method is simple and environmentally friendly. The electrode exhibits excellent electrochemical activity and stability, showing this material application prospect for supercapacitor.
