Nanosized Pt catalysts are the catalyst-of-choice for proton exchange membrane fuel cell(PEMFC)anode,but are limited by their extreme sensitivity to CO in parts per million(ppm)level,thereby making the use of ultrapur...Nanosized Pt catalysts are the catalyst-of-choice for proton exchange membrane fuel cell(PEMFC)anode,but are limited by their extreme sensitivity to CO in parts per million(ppm)level,thereby making the use of ultrapure H_(2)a prerequisite to ensure acceptable performance.Herein,we confront the CO poisoning issue by bringing the Ir/Rh single atom sites to synergistically working with their metallic counterparts.In presence of 1000 ppm CO,the catalyst represents not only undisturbed H_(2)oxidation reaction(HOR)catalytic behavior in electrochemical cell,but also unparalleled peak power density at 643 mW cm^(-2)in single cell,27-fold in mass activity of the best PtRu/C catalysts available.Pre-poisoning experiments and surface-enhanced Raman scattering spectroscopy(SERS)and calculation results in combine suggest the presence of adjacent Ir/Rh single atom sites(SASs)to the nanoparticles(NPs)as the origin for this prominent catalytic behavior.The single sites not only exhibit superb CO oxidation performance by themselves,but can also scavenge the CO adsorbed on approximated NPs via supplying reactive OH*species.We open up a new route here to conquer the formidable CO poisoning issue through single atom and nanoparticle synergistic catalysis,and pave the way towards a more robust PEMFC future.展开更多
In this work, hierarchical BiOBr<sub>1<span style="white-space:nowrap;">−</span>x</sub>I<sub>x</sub>/BiOBr heterojunction photocatalyst with a microsphere morphol...In this work, hierarchical BiOBr<sub>1<span style="white-space:nowrap;">−</span>x</sub>I<sub>x</sub>/BiOBr heterojunction photocatalyst with a microsphere morphology was synthesized by a facile solvothermal process. It demonstrated that the local structure of the photocatalysts was highly distorted due to the substitution of bromide ions by iodine ions. The photocatalytic properties were evaluated by the photodecomposition of aqueous phenol solution under visible-light irradiation. The results indicated that all the composite photocatalysts exhibited high photocatalytic activity. In particularly, the BiOBr<sub>1<span style="white-space:nowrap;">−</span>x</sub>I<sub>x</sub>/BiOBr (x = 0.25) sample exhibited over 92% degradation efficiency of phenol within 150 min, which is 24.6 and 3.08 fold enhancement in the photocatalytic activity over the pure phased BiOBr and BiOI, respectively. Moreover, this excellent photocatalytic property can be expanded to other colorless organic contaminants, verifying the common applicability of BiOBr<sub>1<span style="white-space:nowrap;">−</span>x</sub>I<sub>x</sub>/BiOBr (x = 0.25) as an excellent visible-light photocatalyst for organics decomposition. The significant improvement in the photocatalytic activity can be explained by the high efficiency of charge separation due to the enhancement in the internal electric fields and band match that comes from the local structure distortion. This work provides valuable information for the design of highly active photocatalysts toward the environmental remediation.展开更多
In this paper,we study the following Schrodinger-Poisson system with critical growth:■We establish the existence of a positive ground state solution and a least energy sign-changing solution,providing that the nonlin...In this paper,we study the following Schrodinger-Poisson system with critical growth:■We establish the existence of a positive ground state solution and a least energy sign-changing solution,providing that the nonlinearity f is super-cubic,subcritical and that the potential V(x)has a potential well.展开更多
引力波是爱因斯坦最重要的预言之一,是检验广义相对论正确性的重要工具.引力波理论及其探测一直以来都是理论物理学家和实验物理学家感兴趣的研究领域.事实上,随着科学技术的发展,人类已经具备了建造极度灵敏的地面探测器以及空间探测...引力波是爱因斯坦最重要的预言之一,是检验广义相对论正确性的重要工具.引力波理论及其探测一直以来都是理论物理学家和实验物理学家感兴趣的研究领域.事实上,随着科学技术的发展,人类已经具备了建造极度灵敏的地面探测器以及空间探测器的能力,直接探测引力波已经成为现实.2015年9月14日,LIGO首次直接探测到引力波,该信号源自一次双黑洞并合事件,自此人类进入引力波常规化探测阶段,终于拉开了引力波天文学时代的序幕.地面引力波探测器最主要的波源是处于旋近和并合阶段的致密双星.如果在探测到这些波源所辐射出的引力波信号的同时,又能观测到波源对应的电磁波信号,那么引力波信号和电磁波信号可以相互补充,形成新的观测模式.然而单个地面引力波探测器很难准确地探测引力波信号,也不能进行波源精确定位,将多个探测器联网组合,这样既能准确探测引力波信号,又能大幅提高引力波波源的定位精度.本文中,首先介绍探测器联网对引力波信号GW150914源的定位情况,然后介绍了两种最常用的估计定位精度的方法,即马尔科夫链蒙特卡罗(Markov Chain Monte Carlo,MCMC)的方法和解析的方法.最后,选用一种解析的方法讨论未来中国引力波探测器与日本及澳大利亚所组成的探测器网络的定位精度,并给出了中国的较优台址.最后,还讨论了中国加入世界引力波探测器网络行列对引力波波源定位的贡献.展开更多
基金supported by the National Key Research and Development Program of China(2022YFB4004100)the National Natural Science Foundation of China(U22A20396 and 22209168)+1 种基金the Natural Science Foundation of Anhui Province(2208085UD04)China Postdoctoral Science Foundation(2023M743375)。
文摘Nanosized Pt catalysts are the catalyst-of-choice for proton exchange membrane fuel cell(PEMFC)anode,but are limited by their extreme sensitivity to CO in parts per million(ppm)level,thereby making the use of ultrapure H_(2)a prerequisite to ensure acceptable performance.Herein,we confront the CO poisoning issue by bringing the Ir/Rh single atom sites to synergistically working with their metallic counterparts.In presence of 1000 ppm CO,the catalyst represents not only undisturbed H_(2)oxidation reaction(HOR)catalytic behavior in electrochemical cell,but also unparalleled peak power density at 643 mW cm^(-2)in single cell,27-fold in mass activity of the best PtRu/C catalysts available.Pre-poisoning experiments and surface-enhanced Raman scattering spectroscopy(SERS)and calculation results in combine suggest the presence of adjacent Ir/Rh single atom sites(SASs)to the nanoparticles(NPs)as the origin for this prominent catalytic behavior.The single sites not only exhibit superb CO oxidation performance by themselves,but can also scavenge the CO adsorbed on approximated NPs via supplying reactive OH*species.We open up a new route here to conquer the formidable CO poisoning issue through single atom and nanoparticle synergistic catalysis,and pave the way towards a more robust PEMFC future.
文摘In this work, hierarchical BiOBr<sub>1<span style="white-space:nowrap;">−</span>x</sub>I<sub>x</sub>/BiOBr heterojunction photocatalyst with a microsphere morphology was synthesized by a facile solvothermal process. It demonstrated that the local structure of the photocatalysts was highly distorted due to the substitution of bromide ions by iodine ions. The photocatalytic properties were evaluated by the photodecomposition of aqueous phenol solution under visible-light irradiation. The results indicated that all the composite photocatalysts exhibited high photocatalytic activity. In particularly, the BiOBr<sub>1<span style="white-space:nowrap;">−</span>x</sub>I<sub>x</sub>/BiOBr (x = 0.25) sample exhibited over 92% degradation efficiency of phenol within 150 min, which is 24.6 and 3.08 fold enhancement in the photocatalytic activity over the pure phased BiOBr and BiOI, respectively. Moreover, this excellent photocatalytic property can be expanded to other colorless organic contaminants, verifying the common applicability of BiOBr<sub>1<span style="white-space:nowrap;">−</span>x</sub>I<sub>x</sub>/BiOBr (x = 0.25) as an excellent visible-light photocatalyst for organics decomposition. The significant improvement in the photocatalytic activity can be explained by the high efficiency of charge separation due to the enhancement in the internal electric fields and band match that comes from the local structure distortion. This work provides valuable information for the design of highly active photocatalysts toward the environmental remediation.
基金supported by the National NaturalScience Foundation of China(12071170,11961043,11931012,12271196)supported by the excellent doctoral dissertation cultivation grant(2022YBZZ034)from Central China Normal University。
文摘In this paper,we study the following Schrodinger-Poisson system with critical growth:■We establish the existence of a positive ground state solution and a least energy sign-changing solution,providing that the nonlinearity f is super-cubic,subcritical and that the potential V(x)has a potential well.
文摘引力波是爱因斯坦最重要的预言之一,是检验广义相对论正确性的重要工具.引力波理论及其探测一直以来都是理论物理学家和实验物理学家感兴趣的研究领域.事实上,随着科学技术的发展,人类已经具备了建造极度灵敏的地面探测器以及空间探测器的能力,直接探测引力波已经成为现实.2015年9月14日,LIGO首次直接探测到引力波,该信号源自一次双黑洞并合事件,自此人类进入引力波常规化探测阶段,终于拉开了引力波天文学时代的序幕.地面引力波探测器最主要的波源是处于旋近和并合阶段的致密双星.如果在探测到这些波源所辐射出的引力波信号的同时,又能观测到波源对应的电磁波信号,那么引力波信号和电磁波信号可以相互补充,形成新的观测模式.然而单个地面引力波探测器很难准确地探测引力波信号,也不能进行波源精确定位,将多个探测器联网组合,这样既能准确探测引力波信号,又能大幅提高引力波波源的定位精度.本文中,首先介绍探测器联网对引力波信号GW150914源的定位情况,然后介绍了两种最常用的估计定位精度的方法,即马尔科夫链蒙特卡罗(Markov Chain Monte Carlo,MCMC)的方法和解析的方法.最后,选用一种解析的方法讨论未来中国引力波探测器与日本及澳大利亚所组成的探测器网络的定位精度,并给出了中国的较优台址.最后,还讨论了中国加入世界引力波探测器网络行列对引力波波源定位的贡献.
