Tungsten is a strategic metal that is widely used in various fields such as electron communication,aeronautics and astronautics,materials and chemical engineering,due to its special properties.China has the largest re...Tungsten is a strategic metal that is widely used in various fields such as electron communication,aeronautics and astronautics,materials and chemical engineering,due to its special properties.China has the largest reserves of tungsten resources and the largest output of tungsten concentrate in the world,and plays a decisive role in the world tungsten market.In this work,firstly,the reserves and distribution characteristics of tungsten resources in China were summarized,and the production situation of tungsten concentrate in China was reviewed.Based on the gross domestic product per capita(GDP/capita),five different annual GDP growth rates were used to estimate China’s tungsten concentrate production in the future.The estimation results suggested that if China’s economy continues to grow at the current rate,the accumulative production of tungsten concentrate will exceed current reserves by approximately 2032.Then,from the aspects of process flow,beneficiation equipment and flotation reagents,the beneficiation technology development of different types of tungsten ore in China was also reviewed,including wolframite,scheelite and tungsten-bearing slime.Finally,taking several representative tungsten mines in China as examples,the classic beneficiation technology of different types of tungsten ores was elucidated in detail.Meanwhile,the development direction of tungsten beneficiation technology in the future was put forward,which was of great significance to maintain the superiority of tungsten resources in China.展开更多
The depression mechanism of zinc sulfate(ZnSO4)and sodium dimethyl dithiocarbamate(DMDC)as the combined depressant on sphalerite was investigated by micro-flotation experiments,ion complexing tests,contact angle tests...The depression mechanism of zinc sulfate(ZnSO4)and sodium dimethyl dithiocarbamate(DMDC)as the combined depressant on sphalerite was investigated by micro-flotation experiments,ion complexing tests,contact angle tests and X-ray photoelectron spectroscopy(XPS)analysis.The micro-flotation tests revealed that ZnSO4+DMDC had a better selective depression effect on sphalerite than using single ZnSO4 or DMDC.Ion complexing tests confirmed that DMDC had a strong complexing capacity with lead ions or hydroxy complexes.Contact angle tests illustrated that ZnSO4+DMDC makes the sphalerite surface more hydrophilic than ZnSO4 or DMDC.XPS analysis indicated that the combined depressant could prevent collector adsorbing on the Pb-activated sphalerite surface by a competitive adsorption method,while the combined depressant and collector were co-adsorbed on galena surface.展开更多
Luanchuan area is one of the regions with the largest scale of scheelite beneficiation and the largest output of scheelite concentrate in the world. After years of innovation and progress, the beneficiation technology...Luanchuan area is one of the regions with the largest scale of scheelite beneficiation and the largest output of scheelite concentrate in the world. After years of innovation and progress, the beneficiation technology of low-grade scheelite associated with molybdenum tailings in Luanchuan area is becoming more and more perfect. In this study, the development process of low-grade scheelite recycling technology in Luanchuan area was reviewed, including raw ore properties, beneficiation process, flotation equipment and flotation reagents. Meanwhile, taking Luoyang Yulu Mining Co., Ltd. as an example, the effects of various technical transformations such as the optimization of the beneficiation process, the column-machine combined process, and the high-efficiency flotation reagents were elucidated in detail. However, the recycling technology of low-grade scheelite of Luanchuan area is still possible to be improved. As a result, coupled with the latest research progress, the development direction of low-grade scheelite beneficiation in Luanchuan area was also prospected. It is of great significance to further improve the recovery efficiency of low-grade scheelite resources in Luanchuan area and this can provide technical reference for other scheelite plants.展开更多
The flotation and surface interaction of rutile with nonyl hydroxamic acid were investigated in this work. The results show that the adsorption density and flotation recovery of rutile have similar tendency, especiall...The flotation and surface interaction of rutile with nonyl hydroxamic acid were investigated in this work. The results show that the adsorption density and flotation recovery of rutile have similar tendency, especially the maximum recovery and adsorption occur at pH about 7.5. In terms of Fourier transform infrared（FTIR） spectroscopic analysis, chemical adsorption is identified on the surface of rutile, where a chelate of O,O-five-membered rings with Ti^4＋ on the surface of rutile may form. Adsorption measurements, Zeta potential test, IR spectrum analyses, and solution chemistry calculations illustrate that the adsorption on the rutile surface involves both physical and chemical adsorption, while chemical adsorption is dominant.展开更多
The hydrophobic flocculation flotation of rutile fines in the presence of styryl phosphonic acid（SPA） was investigated by flotation tests, zeta-potential measurement, optical microscope observation, laser-based part...The hydrophobic flocculation flotation of rutile fines in the presence of styryl phosphonic acid（SPA） was investigated by flotation tests, zeta-potential measurement, optical microscope observation, laser-based particle size analysis, adsorption measurements and DLVO theory. The flotation tests indicated that rutile fines could be flocculated by SPA, and pH, shear force（stirring speed） and stirring time played significant roles in flocculation. The isoelectric point（IEP） and zeta-potential in whole range all moved to negative values as SPA was added according to the results from zeta-potential measurement. It was demonstrated that the primary reason for above was chemical adsorption. The laser-based particle size results showed the particle size at a stirring speed of 1800 r/min and 1000 mg/L SPA was the largest in all experiments. Furthermore, using the optical microscope observation and flotation tests, it was important for flotation of rutile fines to produce the flocculant. In the light of above-mentioned facts, floc flotation of rutile fines could be induced in the form of chemical adsorption by SPA to increase particle size. The data calculated from DLVO theory also indicated that chemical adsorption was the main reason for the formation of flocculant.展开更多
Environmentally friendly flotation reagent,polyaspartic acid(PAPA),was tested as a potential selective depressant in the flotation separation of chalcopyrite and Cu-activated sphalerite.The depression mechanism of PAP...Environmentally friendly flotation reagent,polyaspartic acid(PAPA),was tested as a potential selective depressant in the flotation separation of chalcopyrite and Cu-activated sphalerite.The depression mechanism of PAPA was revealed by contact angle measurements,Zeta potential measurements,Fourier transform infrared spectroscopy(FT-IR)analysis and inductively coupled plasma(ICP)measurement.The micro-flotation tests with single minerals showed that PAPA selectively depressed Cu-activated sphalerite,while chalcopyrite remained floatable.Moreover,a concentrate containing 31.40%Cu with a recovery of 92.43%was obtained in flotation tests of artificially mixed minerals.Results of contact angle measurements,Zeta potential measurements and FT-IR spectrum revealed that PAPA exerted a much stronger adsorption on Cu-activated sphalerite surface than on chalcopyrite surface,preventing the further adsorption of sodium diethyl dithiocarbamate(DDTC)on its surface.ICP measurements indicated that PAPA had an excellent complexing ability with Cu^(2+)in flotation pulp,weakening the activation of Cu species on sphalerite surface and producing selective depression.展开更多
Sialyltransferases （SlaTs） exist widely in vertebrates and play important roles in a variety of biological processes. In plants, several genes have also been identified to encode the proteins that share homology wit...Sialyltransferases （SlaTs） exist widely in vertebrates and play important roles in a variety of biological processes. In plants, several genes have also been identified to encode the proteins that share homology with the vertebrate SlaTs. However, very little is known about their functions in plants. Here we report the identification and characterization of a novel Arabidopsis gene, MALE GAMETOPHYTE DEFECTIVE 2 （MGP2） that encodes a sialyltransferase-like protein. MGP2 was expressed in all tissues including pollen grains and pollen tubes. The MGP2 protein was targeted to Golgi apparatus. Knockout of MGP2 significantly inhibited the pollen germination and retarded pollen tube growth in vitro and in vivo, but did not affect female gametophytic functions. These results suggest that the sialyltransferase-like protein MGP2 is important for normal pollen germination and pollen tube growth, giving a novel insight into the biological roles of the sialyltransferase.like proteins in plants.展开更多
The flotation separation of smithsonite from calcite and quartz using a alkyl diamine ether(GE-609)as the collector was investigated through micro-flotation experiments and the real ore flotation experiments.The resul...The flotation separation of smithsonite from calcite and quartz using a alkyl diamine ether(GE-609)as the collector was investigated through micro-flotation experiments and the real ore flotation experiments.The results show that GE-609exhibits good collecting capability to three minerals without selectivity.The presence of sodium sulfide enhances the flotation of smithsonite and calcite while inhibits quartz.Moreover,both sodium silicate and sodium hexametaphosphate exhibit good selective inhibition to calcite.The real ore test results show that a zinc concentrate containing23.51%Zn with the recovery of71.02%is obtained in the closed-circuit test.To understand the adsorption of GE-609on smithsonite surface,zeta potential measurement and FTIR analysis were carried out,and the results indicate that the collector GE-609can adsorb on smithsonite surface through both electrostatic adsorption and chemical adsorption,and the presence of sodium sulfide enhances the adsorption of GE-609.展开更多
Tibetan Plateau is known as the roof of the world.Due to the continuous uplift of the Tibetan Plateau,many active fault zones are present.These active fault zones such as the Anninghe fault zone have a significant inf...Tibetan Plateau is known as the roof of the world.Due to the continuous uplift of the Tibetan Plateau,many active fault zones are present.These active fault zones such as the Anninghe fault zone have a significant influence on the formation of special geomorphology and the distribution of geological hazards at the eastern edge of the Tibetan Plateau.The Anninghe fault zone is a key part of the Y-shaped fault pattern in the Sichuan-Yunnan block of China.In this paper,high-resolution topographic data,multitemporal remote sensing images,numerical calculations,seismic records,and comprehensive field investigations were employed to study the landslide distribution along the active part of the Anninghe.The influence of active faults on the lithology,rock mass structures and slope stress fields were also studied.The results show that the faults within the Anninghe fault zone have damaged the structure and integrity of the slope rock mass,reduced the mechanical strength of the rock mass and controlled the slope failure modes.The faults have also controlled the stress field,the distribution of the plastic strain zone and the maximum shear strain zone of the slope,thus have promoted the formation and evolution of landslides.We find that the studied landslides are linearly distributed along the Anninghe fault zone,and more than 80%of these landslides are within 2–3 km of the fault rupture zone.Moreover,the Anninghe fault zone provides abundant substance for landslides or debris flows.This paper presents four types of sliding mode control of the Anninghe fault zone,e.g.,constituting the whole landslide body,controlling the lateral boundary of the landslide,controlling the crown of the landslide,and constituting the toe of the landslide.The results presented merit close attention as a valuable reference source for local infrastructure planning and engineering projects.展开更多
基金financially suppored by the National Natural Science Foundation of China (Nos.51904339,51974364)the Key Laboratory of Hunan Province for Clean and Efficient Utilization of Strategic Calcium-containing Mineral Resources,China (No.2018TP1002)the Co-innovation Centre for Clean and Efficient Utilization of Strategic Metal Mineral Resources,China。
文摘Tungsten is a strategic metal that is widely used in various fields such as electron communication,aeronautics and astronautics,materials and chemical engineering,due to its special properties.China has the largest reserves of tungsten resources and the largest output of tungsten concentrate in the world,and plays a decisive role in the world tungsten market.In this work,firstly,the reserves and distribution characteristics of tungsten resources in China were summarized,and the production situation of tungsten concentrate in China was reviewed.Based on the gross domestic product per capita(GDP/capita),five different annual GDP growth rates were used to estimate China’s tungsten concentrate production in the future.The estimation results suggested that if China’s economy continues to grow at the current rate,the accumulative production of tungsten concentrate will exceed current reserves by approximately 2032.Then,from the aspects of process flow,beneficiation equipment and flotation reagents,the beneficiation technology development of different types of tungsten ore in China was also reviewed,including wolframite,scheelite and tungsten-bearing slime.Finally,taking several representative tungsten mines in China as examples,the classic beneficiation technology of different types of tungsten ores was elucidated in detail.Meanwhile,the development direction of tungsten beneficiation technology in the future was put forward,which was of great significance to maintain the superiority of tungsten resources in China.
基金Projects(51974364,51904339)supported by the National Natural Science Foundation of ChinaProject(2018TP1002)supported by the Hunan Province for Clean and Efficiency Utilization of Strategic Calcium-containing Mineral,China。
文摘The depression mechanism of zinc sulfate(ZnSO4)and sodium dimethyl dithiocarbamate(DMDC)as the combined depressant on sphalerite was investigated by micro-flotation experiments,ion complexing tests,contact angle tests and X-ray photoelectron spectroscopy(XPS)analysis.The micro-flotation tests revealed that ZnSO4+DMDC had a better selective depression effect on sphalerite than using single ZnSO4 or DMDC.Ion complexing tests confirmed that DMDC had a strong complexing capacity with lead ions or hydroxy complexes.Contact angle tests illustrated that ZnSO4+DMDC makes the sphalerite surface more hydrophilic than ZnSO4 or DMDC.XPS analysis indicated that the combined depressant could prevent collector adsorbing on the Pb-activated sphalerite surface by a competitive adsorption method,while the combined depressant and collector were co-adsorbed on galena surface.
基金the financial support from the National Natural Science Foundation of China (No. 51974364)Postgraduate Independent Exploration and Innovation Project of Central South University, China (No. 2018zzts224)the Key Laboratory of Hunan Province for Clean and Efficiency Utilization of Strategic Calcium-containing Mineral Resources, China (No. 2018TP1002)。
文摘Luanchuan area is one of the regions with the largest scale of scheelite beneficiation and the largest output of scheelite concentrate in the world. After years of innovation and progress, the beneficiation technology of low-grade scheelite associated with molybdenum tailings in Luanchuan area is becoming more and more perfect. In this study, the development process of low-grade scheelite recycling technology in Luanchuan area was reviewed, including raw ore properties, beneficiation process, flotation equipment and flotation reagents. Meanwhile, taking Luoyang Yulu Mining Co., Ltd. as an example, the effects of various technical transformations such as the optimization of the beneficiation process, the column-machine combined process, and the high-efficiency flotation reagents were elucidated in detail. However, the recycling technology of low-grade scheelite of Luanchuan area is still possible to be improved. As a result, coupled with the latest research progress, the development direction of low-grade scheelite beneficiation in Luanchuan area was also prospected. It is of great significance to further improve the recovery efficiency of low-grade scheelite resources in Luanchuan area and this can provide technical reference for other scheelite plants.
基金financially supported by the National Natural Science Foundation of China (No. 51474254)the Ph.D. Programs Foundation of Ministry of Education of China (No. 20120162110008)+2 种基金China Postdoctoral Science Foundation (No. 2013M531813)the Planned Science and Technology Project of Hunan Province, China (No. 2012SK3233)the Independent Exploration and Innovation Projects of Master of Central South University (No. 2014zzts275)
文摘The flotation and surface interaction of rutile with nonyl hydroxamic acid were investigated in this work. The results show that the adsorption density and flotation recovery of rutile have similar tendency, especially the maximum recovery and adsorption occur at pH about 7.5. In terms of Fourier transform infrared（FTIR） spectroscopic analysis, chemical adsorption is identified on the surface of rutile, where a chelate of O,O-five-membered rings with Ti^4＋ on the surface of rutile may form. Adsorption measurements, Zeta potential test, IR spectrum analyses, and solution chemistry calculations illustrate that the adsorption on the rutile surface involves both physical and chemical adsorption, while chemical adsorption is dominant.
基金Projects(51474254,51774332,51320105006) supported by the National Natural Science Foundation of ChinaProject(NCET-13-0595) supported by the Program for New Century Excellent Talents in University,ChinaProjects(2017zzts579,2017zzts379) supported by the Fundamental Research Funds for the Central Universities of China
文摘The hydrophobic flocculation flotation of rutile fines in the presence of styryl phosphonic acid（SPA） was investigated by flotation tests, zeta-potential measurement, optical microscope observation, laser-based particle size analysis, adsorption measurements and DLVO theory. The flotation tests indicated that rutile fines could be flocculated by SPA, and pH, shear force（stirring speed） and stirring time played significant roles in flocculation. The isoelectric point（IEP） and zeta-potential in whole range all moved to negative values as SPA was added according to the results from zeta-potential measurement. It was demonstrated that the primary reason for above was chemical adsorption. The laser-based particle size results showed the particle size at a stirring speed of 1800 r/min and 1000 mg/L SPA was the largest in all experiments. Furthermore, using the optical microscope observation and flotation tests, it was important for flotation of rutile fines to produce the flocculant. In the light of above-mentioned facts, floc flotation of rutile fines could be induced in the form of chemical adsorption by SPA to increase particle size. The data calculated from DLVO theory also indicated that chemical adsorption was the main reason for the formation of flocculant.
基金financial supports from the National Natural Science Foundation of China(Nos.51974364,51904339)Hunan Province for Clean and Efficient Utilization of Strategic Calcium-containing Mineral,China(No.2018TP1002)。
文摘Environmentally friendly flotation reagent,polyaspartic acid(PAPA),was tested as a potential selective depressant in the flotation separation of chalcopyrite and Cu-activated sphalerite.The depression mechanism of PAPA was revealed by contact angle measurements,Zeta potential measurements,Fourier transform infrared spectroscopy(FT-IR)analysis and inductively coupled plasma(ICP)measurement.The micro-flotation tests with single minerals showed that PAPA selectively depressed Cu-activated sphalerite,while chalcopyrite remained floatable.Moreover,a concentrate containing 31.40%Cu with a recovery of 92.43%was obtained in flotation tests of artificially mixed minerals.Results of contact angle measurements,Zeta potential measurements and FT-IR spectrum revealed that PAPA exerted a much stronger adsorption on Cu-activated sphalerite surface than on chalcopyrite surface,preventing the further adsorption of sodium diethyl dithiocarbamate(DDTC)on its surface.ICP measurements indicated that PAPA had an excellent complexing ability with Cu^(2+)in flotation pulp,weakening the activation of Cu species on sphalerite surface and producing selective depression.
基金supported by the research grants from the National Natural Science Foundation of China(30530060)State Key Basic Research and Development Plan of China(2007CB108700)the Ministry of Education (111 project B06003)
文摘Sialyltransferases （SlaTs） exist widely in vertebrates and play important roles in a variety of biological processes. In plants, several genes have also been identified to encode the proteins that share homology with the vertebrate SlaTs. However, very little is known about their functions in plants. Here we report the identification and characterization of a novel Arabidopsis gene, MALE GAMETOPHYTE DEFECTIVE 2 （MGP2） that encodes a sialyltransferase-like protein. MGP2 was expressed in all tissues including pollen grains and pollen tubes. The MGP2 protein was targeted to Golgi apparatus. Knockout of MGP2 significantly inhibited the pollen germination and retarded pollen tube growth in vitro and in vivo, but did not affect female gametophytic functions. These results suggest that the sialyltransferase-like protein MGP2 is important for normal pollen germination and pollen tube growth, giving a novel insight into the biological roles of the sialyltransferase.like proteins in plants.
基金Project(2016RS2016) supported by Innovation Team of Interface Chemistry of Efficient and Clean Utilization of Complex Mineral Resources,China
文摘The flotation separation of smithsonite from calcite and quartz using a alkyl diamine ether(GE-609)as the collector was investigated through micro-flotation experiments and the real ore flotation experiments.The results show that GE-609exhibits good collecting capability to three minerals without selectivity.The presence of sodium sulfide enhances the flotation of smithsonite and calcite while inhibits quartz.Moreover,both sodium silicate and sodium hexametaphosphate exhibit good selective inhibition to calcite.The real ore test results show that a zinc concentrate containing23.51%Zn with the recovery of71.02%is obtained in the closed-circuit test.To understand the adsorption of GE-609on smithsonite surface,zeta potential measurement and FTIR analysis were carried out,and the results indicate that the collector GE-609can adsorb on smithsonite surface through both electrostatic adsorption and chemical adsorption,and the presence of sodium sulfide enhances the adsorption of GE-609.
基金supported by China Geological Survey Projects(Grant No.20160272,20211379)the Second Tibetan Plateau Scientific Expedition and Research Program(Grant No.2019QZKK0904)Sichuan Science and Technology Program of China(Grant No.2020YFS0296).
文摘Tibetan Plateau is known as the roof of the world.Due to the continuous uplift of the Tibetan Plateau,many active fault zones are present.These active fault zones such as the Anninghe fault zone have a significant influence on the formation of special geomorphology and the distribution of geological hazards at the eastern edge of the Tibetan Plateau.The Anninghe fault zone is a key part of the Y-shaped fault pattern in the Sichuan-Yunnan block of China.In this paper,high-resolution topographic data,multitemporal remote sensing images,numerical calculations,seismic records,and comprehensive field investigations were employed to study the landslide distribution along the active part of the Anninghe.The influence of active faults on the lithology,rock mass structures and slope stress fields were also studied.The results show that the faults within the Anninghe fault zone have damaged the structure and integrity of the slope rock mass,reduced the mechanical strength of the rock mass and controlled the slope failure modes.The faults have also controlled the stress field,the distribution of the plastic strain zone and the maximum shear strain zone of the slope,thus have promoted the formation and evolution of landslides.We find that the studied landslides are linearly distributed along the Anninghe fault zone,and more than 80%of these landslides are within 2–3 km of the fault rupture zone.Moreover,the Anninghe fault zone provides abundant substance for landslides or debris flows.This paper presents four types of sliding mode control of the Anninghe fault zone,e.g.,constituting the whole landslide body,controlling the lateral boundary of the landslide,controlling the crown of the landslide,and constituting the toe of the landslide.The results presented merit close attention as a valuable reference source for local infrastructure planning and engineering projects.
