In the field of dual-pulse laser-induced breakdown spectroscopy(DP-LIBS)research,the pursuit of methods for determining pulse intervals and other parameters quickly and conveniently in order to achieve optimal spectra...In the field of dual-pulse laser-induced breakdown spectroscopy(DP-LIBS)research,the pursuit of methods for determining pulse intervals and other parameters quickly and conveniently in order to achieve optimal spectral signal enhancement is paramount.To aid researchers in identification of optimal signal enhancement conditions and more accurate interpretation of the underlying signal enhancement mechanisms,theoretical simulations of the spatiotemporal processes of coaxial DP-LIBS-induced plasma have been established in this work.Using a model based on laser ablation and two-dimensional axisymmetric fluid dynamics,plasma evolutions during aluminum–magnesium alloy laser ablation under single-pulse and coaxial dualpulse excitations have been simulated.The influences of factors,such as delay time,laser fluence,plasma temperature,and particle number density,on the DP-LIBS spectral signals are investigated.Under pulse intervals ranging from 50 to 1500 ns,the time evolutions of spectral line intensity,dual-pulse emission enhancement relative to the single-pulse results,laser irradiance,spatial distribution of plasma temperature and species number density,as well as laser irradiance shielded by plasma have been obtained.The study indicates that the main reason behind the radiation signal enhancement in coaxial DP-LIBS-induced plasma is attributed to the increased species number density and plasma temperature caused by the second laser,and it is inferred that the shielding effect of the plasma mainly occurs in the boundary layer of the stagnation point flow over the target surface.This research provides a theoretical basis for experimental research,parameter optimization,and signal enhancement tracing in DP-LIBS.展开更多
The dual-mode stabilization scheme has been demonstrated as an efficient way to stabilize laser frequency.In this study,we propose a novel dual-mode stabilization scheme that employs a sizable Fabry-Pérot cavity ...The dual-mode stabilization scheme has been demonstrated as an efficient way to stabilize laser frequency.In this study,we propose a novel dual-mode stabilization scheme that employs a sizable Fabry-Pérot cavity instead of the microcavity used in previous studies and has enabled higher bandwidth for locking.The results demonstrate a 30-fold reduction in laser frequency drift,with frequency instability below 169 kHz for integration time exceeding 1 h and a minimum value of 33.8 kHz at 54 min.Further improvement could be achieved by optimizing the phase locking.This scheme has potential for use in precision spectroscopic measurement.展开更多
基金supported by the National Key R&D Program of China (No. 2017YFA0304203)the National Energy R&D Center of Petroleum Refining Technology (RIPP, SINOPEC)+3 种基金Changjiang Scholars and Innovative Research Team at the University of the Ministry of Education of China (No. IRT_17R70)National Natural Science Foundation of China (NSFC) (Nos. 61975103, 61875108 and 627010407)111 Project (No. D18001)Fund for Shanxi (No. 1331KSC)
文摘In the field of dual-pulse laser-induced breakdown spectroscopy(DP-LIBS)research,the pursuit of methods for determining pulse intervals and other parameters quickly and conveniently in order to achieve optimal spectral signal enhancement is paramount.To aid researchers in identification of optimal signal enhancement conditions and more accurate interpretation of the underlying signal enhancement mechanisms,theoretical simulations of the spatiotemporal processes of coaxial DP-LIBS-induced plasma have been established in this work.Using a model based on laser ablation and two-dimensional axisymmetric fluid dynamics,plasma evolutions during aluminum–magnesium alloy laser ablation under single-pulse and coaxial dualpulse excitations have been simulated.The influences of factors,such as delay time,laser fluence,plasma temperature,and particle number density,on the DP-LIBS spectral signals are investigated.Under pulse intervals ranging from 50 to 1500 ns,the time evolutions of spectral line intensity,dual-pulse emission enhancement relative to the single-pulse results,laser irradiance,spatial distribution of plasma temperature and species number density,as well as laser irradiance shielded by plasma have been obtained.The study indicates that the main reason behind the radiation signal enhancement in coaxial DP-LIBS-induced plasma is attributed to the increased species number density and plasma temperature caused by the second laser,and it is inferred that the shielding effect of the plasma mainly occurs in the boundary layer of the stagnation point flow over the target surface.This research provides a theoretical basis for experimental research,parameter optimization,and signal enhancement tracing in DP-LIBS.
基金supported by the National Key R&D Program of China(No.2022YFC3700329)the National Natural Science Foundation of China(Nos.61905134,61905136,and62175139)+1 种基金the Shanxi Province Science and Technology Activities for Returned Overseas Researcher(No.20220001)the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(No.2019L0062)。
文摘The dual-mode stabilization scheme has been demonstrated as an efficient way to stabilize laser frequency.In this study,we propose a novel dual-mode stabilization scheme that employs a sizable Fabry-Pérot cavity instead of the microcavity used in previous studies and has enabled higher bandwidth for locking.The results demonstrate a 30-fold reduction in laser frequency drift,with frequency instability below 169 kHz for integration time exceeding 1 h and a minimum value of 33.8 kHz at 54 min.Further improvement could be achieved by optimizing the phase locking.This scheme has potential for use in precision spectroscopic measurement.
