He-Ar isotopic compositions of fluid inclusions trapped in pyrites from some representative PGE-polymetallic deposits in Lower Cambrian black rock series in South China were analyzed by using an inert gas isotopic mas...He-Ar isotopic compositions of fluid inclusions trapped in pyrites from some representative PGE-polymetallic deposits in Lower Cambrian black rock series in South China were analyzed by using an inert gas isotopic mass spectrometer. The results show that the ore-forming fluids possess a low 3He/4He ratio, varying from 0.43×10-8 to 26.39×10-8, with corresponding R/Ra value of 0.003-0.189. The 40Ar/36Ar ratios are 258-287, close to those of air saturated water (ASW). He-Ar isotopic indicator studies show that the ore-forming fluids were mainly derived from the formation water or basinal hot brine and sea water, while the content of mantle-derived fluid or deep-derived magmatic water might be negligible. The PGE-polymetallic mineralization might be related to the evolution of the Caledonian miogeosynclines distributed along the southern margin of the Yangtze Craton. During the Early Cambrian, the formation water or basinal hot brine trapped in Caledonian basins which accumulated giant thick sediments was expelled and migrated laterally along strata because of the pressure generated by overlying sediments. The basinal hot brine ascended along faults, mixed with sea water and finally deposited ore minerals.展开更多
The influence of double aging on the microstructure and mechanical properties of ultrahigh strength steel Aermet 100 was analyzed. Under the double aging, there is no apparent decrease in the strength of steel. Howeve...The influence of double aging on the microstructure and mechanical properties of ultrahigh strength steel Aermet 100 was analyzed. Under the double aging, there is no apparent decrease in the strength of steel. However, the impact fatigue life can be prolonged by 35.5% and dynamic fracture toughness be raised by 22.6% respectively, as compared with the normal aging. Based on the observation of microscopic structure, the physical mechanism of the prolongation of impact fatigue life and the enhancement of stability of the reverted austenite, AR, is analyzed further. The results show that this new technique is a breakthrough of combination optimization between strength and toughness for Aermet 100 steel. In the light of the current understanding on this subject, the volume fracture of soften and tough AR formed in process of heat preservation at higher temperature of double aging increases drastically. Moreover, during the treatment of lower temperature of double aging, the carbon separating from the martensitic ferrite will diffuse into AR, resulting that the martensitic brittleness decreases and the stability of AR increases.展开更多
Let G1 and G2 be two graphs of the same order,If G1 is isomorphic to a spanning subgraph of the complement of G2,then we say that G1 and G2 are packable.A graph G is called a (p,m)-graph if G has p vertices and m edge...Let G1 and G2 be two graphs of the same order,If G1 is isomorphic to a spanning subgraph of the complement of G2,then we say that G1 and G2 are packable.A graph G is called a (p,m)-graph if G has p vertices and m edges.The main purpose of this paper is to present a necessary and sufficient condition for a tree of order p and a (p,p+1)-graph to be packable.展开更多
The integrated structure parts are widely used in aircraft. The distortion caused by residual stresses in thick pre-stretched aluminum plates during machining integrated parts is a common and serious problem. To predi...The integrated structure parts are widely used in aircraft. The distortion caused by residual stresses in thick pre-stretched aluminum plates during machining integrated parts is a common and serious problem. To predict and control the machining distortion, the residual stress distribution in the thick plate must be measured firstly. The modified removal method for measuring residual stress in thick pre-stretched aluminum plates is proposed and the stress-strain relation matrix is deduced by elasticity theory. The residual stress distribution in specimen of 7050T7451 plate is measured by using the method, and measurement results are analyzed and compared with data obtained by other methods. The method is effective to measure the residual stress.展开更多
Hydrothermal clay minerals that formed in the main metallogenic stage of the Changkeng disseminated-type gold deposit in central Guangdong were analyzed by the 40Ar/39Ar laser probe. The results give Ar-Ar isochron ag...Hydrothermal clay minerals that formed in the main metallogenic stage of the Changkeng disseminated-type gold deposit in central Guangdong were analyzed by the 40Ar/39Ar laser probe. The results give Ar-Ar isochron ages of 109.9 1.4 to 110.1 1.3 Ma, which are 30 to 50 Ma older than the age of silver ore bodies in the deposit. Both gold and silver mineralizations were not related to hidden granite batholith in the mining district, but probably related to evo-lution of sedimentary basins. This study shows that the 40Ar/39Ar laser probe is a sound dating tool applicable to sediment-hosted disseminated-type gold deposit.展开更多
A novel algorithm based on Radon-Ambiguity Transform (RAT) and Adaptive Signal Decomposition (ASD) is presented for the detection and parameter estimation of multicompo-nent Linear Frequency Modulated (LFM) signals. T...A novel algorithm based on Radon-Ambiguity Transform (RAT) and Adaptive Signal Decomposition (ASD) is presented for the detection and parameter estimation of multicompo-nent Linear Frequency Modulated (LFM) signals. The key problem lies in the chirplet estimation. Genetic algorithm is employed to search for the optimization parameter of chirplet. High estimation accuracy can be obtained even at low Signal-to-Noisc Ratio(SNR). Finally simulation results are provided to demonstrate the performance of the proposed algorithm.展开更多
Freshwater ecosystems provide a host of services to humanity. These services are now rapidly being lost, not least because of the inability of making the impacts measurable. To overcome this obstacle, assessment frame...Freshwater ecosystems provide a host of services to humanity. These services are now rapidly being lost, not least because of the inability of making the impacts measurable. To overcome this obstacle, assessment frameworks for freshwater ecosystem services are needed. A simple water equivalent framework to assess the ecological services provided by freshwater ecosystems was developed in this study. It translated the occupation of freshwater ecosystem services into biologically freshwater volumes and then compares this consumption to the freshwater throughput, that is, the ecological capacity available in this region. In this way, we use the example of Yangzhou Prefecture, to account the main categories of human occupation of water ecosystem services. The result showed that there is a huge gap between the consumption and the supply of freshwater ecosystem services. This must encourage local government to make land-use and water management decisions both economically rational and environmentally sound.展开更多
The automation of traditional Chinese medicine(TCM)pharmaceuticals has driven the development of process analysis from offline to online.Most of common online process analytical technologies are based on spectroscopy,...The automation of traditional Chinese medicine(TCM)pharmaceuticals has driven the development of process analysis from offline to online.Most of common online process analytical technologies are based on spectroscopy,making the identification and quantification of specific ingredients still a challenge.Herein,we developed a quality control(QC)system for monitoring TCM pharmaceuticals based on paper spray ionization miniature mass spectrometry(mini-MS).It enabled real-time online qualitative and quantitative detection of target ingredients in herbal extracts using mini-MS without chromatographic separation for the first time.Dynamic changes of alkaloids in Aconiti Lateralis Radix Praeparata(Fuzi)during decoction were used as examples,and the scientific principle of Fuzi compatibility was also investigated.Finally,the system was verified to work stably at the hourly level for pilot-scale extraction.This mini-MS based online analytical system is expected to be further developed for QC applications in a wider range of pharmaceutical processes.展开更多
Traditional simulation methods are unable to meet the requirements of lunar takeo simulations, such as high force output precision, low cost, and repeated use. Considering that cable-driven parallel mechanisms have th...Traditional simulation methods are unable to meet the requirements of lunar takeo simulations, such as high force output precision, low cost, and repeated use. Considering that cable-driven parallel mechanisms have the advantages of high payload to weight ratio, potentially large workspace, and high-speed motion, these mechanisms have the potential to be used for lunar takeo simulations. Thus, this paper presents a parallel mechanism driven by nine cables. The purpose of this study is to optimize the dimensions of the cable-driven parallel mechanism to meet dynamic workspace requirements under cable tension constraints. The dynamic workspace requirements are derived from the kinematical function requests of the lunar takeo simulation equipment. Experimental design and response surface methods are adopted for building the surrogate mathematical model linking the optimal variables and the optimization indices. A set of dimensional parameters are determined by analyzing the surrogate mathematical model. The volume of the dynamic workspace increased by 46% after optimization. Besides, a force control method is proposed for calculating output vector and sinusoidal forces. A force control loop is introduced into the traditional position control loop to adjust the cable force precisely, while controlling the cable length. The e ectiveness of the proposed control method is verified through experiments. A 5% vector output accuracy and 12 Hz undulation force output can be realized. This paper proposes a cable-driven parallel mechanism which can be used for lunar takeo simulation.展开更多
With sodium dodecyl sulfonate(SDS) as the phase transferring catalyst, N,N-Dilauryl chitosans with a high degree of alkyl group substitution were prepared and characterized by means of FTIR, 1H NMR and elemental ana...With sodium dodecyl sulfonate(SDS) as the phase transferring catalyst, N,N-Dilauryl chitosans with a high degree of alkyl group substitution were prepared and characterized by means of FTIR, 1H NMR and elemental analyses. The results indicate that the average degree of alkyl group substitution on the chitosan increases with decreasing the molecular weight of the chitosan. The fully N,N-dilaurylated chitosan was found to be dissolvable in chloroform. The collapsed pressures of the samples derived from chitosan with 3000, 5000 and 10000 dalton are 47.6, 48.2 and 51.0 mN/m, respectively. The surface area occupied by the monomer unit(glucosamine) of all those samples is 0.6 nm2.展开更多
Based on high-precision data obtained in the past decade from GPS re-measurement in the North China Network, the Crustal Movement Observation Network of China (CMONOC) and GPS measurement along the Shanxi graben zone,...Based on high-precision data obtained in the past decade from GPS re-measurement in the North China Network, the Crustal Movement Observation Network of China (CMONOC) and GPS measurement along the Shanxi graben zone, the status and evolution of horizontal crustal movement in the North China region are analyzed. The results show that(1) the Yanshan tectonic zone (Zhangjiakou-Bohai Sea zone)is an active one with the largest horizontal strain in the North China region; The largest tendency differential movement of adjacent blocks is seen between the Yanshan block and the North China plain block; about 2mm/a (left lateral); (2) The significant horizontal differential movement along the boundaries of the North China region is characterized by right-lateral strike-slip movement at the middle-north segment on its west boundary (composed of Yinchuan and other active tectonic zones) and compressive movement at the south segment; while the Yinshan rift zone located along the west segment on its north boundary is dominated by tensile movement. Other boundaries and zones have no obvious differential movement; (3) On the whole, measurements of each period differ from one another, which might result from the nonlinear movement component as well as from the error effect. In the paper, results of the relative movement and strain in different periods are given for different blocks and boundary zones.展开更多
In this paper, orthogonal/turbo-codes for mobile DS-CDMA communications are considered. We compare the performances of turbo-codes with those of convolutional codes for noncoherent M-ary orthogonal modulation in ...In this paper, orthogonal/turbo-codes for mobile DS-CDMA communications are considered. We compare the performances of turbo-codes with those of convolutional codes for noncoherent M-ary orthogonal modulation in multipath fading channels. One method to calculate the branch transition probability of turbo-codes is suggested.By using the parameter of cut-off rate capacity efficiency, 1/2/5 (37,21) turbo-codes are more efficient for 1/3/9(557,663,711) convolutional codes. Given the same spread gain, turbo-codes will increase system's capacity.If SOVA is used in the decoding for turbo-codes case, the dime-delay caused by turbo-decoding is only 1.2 times of that of convolutional codes. Obviously, turbo-codes show better performances at the cost of the hardware complexity of the encoder and the decoder.展开更多
Fully acylated chitosan and N, N-diacyl chitosan were prepared. The products were characterized by elemental analysis, FTIR and 1H NMR. The experimental results indicate that the average degree of acylation depends ...Fully acylated chitosan and N, N-diacyl chitosan were prepared. The products were characterized by elemental analysis, FTIR and 1H NMR. The experimental results indicate that the average degree of acylation depends on the volume ratio of pyridine to chloroform in the reaction medium, the chain length of the acylation agent used, and the molecular weight of chitosan raw materials. The XRD measurements were carried out for pure chitosan, fully acylated chitosan and N, N-diacyl chitosan to verify the crystallinity change caused by the acylation.展开更多
Simple saccharides have a variety of biological functions,but their structural diversity and inherent structural features pose a major challenge for rapid analysis.In this work,we developed a derivative-free and ion m...Simple saccharides have a variety of biological functions,but their structural diversity and inherent structural features pose a major challenge for rapid analysis.In this work,we developed a derivative-free and ion mobility-free method for the rapid analysis of monosaccharides and disaccharides using paper spray tandem mass spectrometry.Trimeric cluster ions consisting of saccharide analytes,ligands and transition metal ions are used as precursor ions.We defined the R-value as the ratio of the intensity of the product ion that loses one molecule of ligand over the intensity of the product ion that loses one molecule of saccharide via collision induced dissociation(CID).The species and conformation of simple saccharides can be easily differentiated by calculating this R-value.With the capability of directly analyzing clinical samples using paper spray ionization,our method can be used to rapidly quantify the molar ratio of galactose to glucose in dried plasma samples to aid in the diagnosis of galactosemia.The analytical strategy provided herein has good potential to be applied to a wide range of saccharide analysis applications in the future.展开更多
The Songxi deposit is a newly discovered large Ag (Sb) deposit. By using a suite of high-vacuum quadrupole gas mass spectrometer systems, the authors have recognized many kinds of light hydrocarbons in fluid inclusion...The Songxi deposit is a newly discovered large Ag (Sb) deposit. By using a suite of high-vacuum quadrupole gas mass spectrometer systems, the authors have recognized many kinds of light hydrocarbons in fluid inclusions of minerals. These hydrocarbons are mainly composed of C1-C4 saturated alkanes, while the contents of C2-C4 unsaturated alkenes and aromatic hydrocarbons are quite low, suggesting that the metallogenic processes have not been affected by magmatic activities. Chemical equilibrium studies show that these hydrocarbons may be a mixture of organic gases generated by microorganism activity and those by thermal cracking of type-n kerogens (kukersite) in sedimentary host rocks, and the former may constitute more than two-thirds, implying that microorganism might have played an important role in the metallogenesis. The equilibrium temperature of the latter is about 300℃, which is much higher than the geothermal temperature at the estimated depth of metallogenesis. Thus, the light hydrocarbons generated by thermal cracking of kerogens probably originated in the deep part of the sedimentary basins and then migrated through a long distance to shallower horizons of the basin. Based on the composition of light hydrocarbons in fluid inclusions, the authors infer that the Songxi deposit was formed in a continental rift. The analytical data presented in this paper support from one aspect the genetic model that the Songxi deposit may be a sedimentary hot brine transformed deposit instead of a submarine basic volcanic exhalation and low-medium temperature volcanic hydrothermal fluid filling deposit proposed by most previous researchers.展开更多
基金the National Natural Sciences Foundation of China(grants40173025,49928201)Trans-century Training Program Foundation for the Talents by the Ministry of Education the Visiting Scholar Foundation of Labs in Universities.
文摘He-Ar isotopic compositions of fluid inclusions trapped in pyrites from some representative PGE-polymetallic deposits in Lower Cambrian black rock series in South China were analyzed by using an inert gas isotopic mass spectrometer. The results show that the ore-forming fluids possess a low 3He/4He ratio, varying from 0.43×10-8 to 26.39×10-8, with corresponding R/Ra value of 0.003-0.189. The 40Ar/36Ar ratios are 258-287, close to those of air saturated water (ASW). He-Ar isotopic indicator studies show that the ore-forming fluids were mainly derived from the formation water or basinal hot brine and sea water, while the content of mantle-derived fluid or deep-derived magmatic water might be negligible. The PGE-polymetallic mineralization might be related to the evolution of the Caledonian miogeosynclines distributed along the southern margin of the Yangtze Craton. During the Early Cambrian, the formation water or basinal hot brine trapped in Caledonian basins which accumulated giant thick sediments was expelled and migrated laterally along strata because of the pressure generated by overlying sediments. The basinal hot brine ascended along faults, mixed with sea water and finally deposited ore minerals.
基金the National Natural Science Foundation of China(No.50171053) the Aeronautical Basic Science Foundation of China(No.0DG53054).
文摘The influence of double aging on the microstructure and mechanical properties of ultrahigh strength steel Aermet 100 was analyzed. Under the double aging, there is no apparent decrease in the strength of steel. However, the impact fatigue life can be prolonged by 35.5% and dynamic fracture toughness be raised by 22.6% respectively, as compared with the normal aging. Based on the observation of microscopic structure, the physical mechanism of the prolongation of impact fatigue life and the enhancement of stability of the reverted austenite, AR, is analyzed further. The results show that this new technique is a breakthrough of combination optimization between strength and toughness for Aermet 100 steel. In the light of the current understanding on this subject, the volume fracture of soften and tough AR formed in process of heat preservation at higher temperature of double aging increases drastically. Moreover, during the treatment of lower temperature of double aging, the carbon separating from the martensitic ferrite will diffuse into AR, resulting that the martensitic brittleness decreases and the stability of AR increases.
基金This research is partially supported by the National Natural Science Foundation of China(19971053).
文摘Let G1 and G2 be two graphs of the same order,If G1 is isomorphic to a spanning subgraph of the complement of G2,then we say that G1 and G2 are packable.A graph G is called a (p,m)-graph if G has p vertices and m edges.The main purpose of this paper is to present a necessary and sufficient condition for a tree of order p and a (p,p+1)-graph to be packable.
文摘The integrated structure parts are widely used in aircraft. The distortion caused by residual stresses in thick pre-stretched aluminum plates during machining integrated parts is a common and serious problem. To predict and control the machining distortion, the residual stress distribution in the thick plate must be measured firstly. The modified removal method for measuring residual stress in thick pre-stretched aluminum plates is proposed and the stress-strain relation matrix is deduced by elasticity theory. The residual stress distribution in specimen of 7050T7451 plate is measured by using the method, and measurement results are analyzed and compared with data obtained by other methods. The method is effective to measure the residual stress.
基金supported by the National Natural Science Foundation of China(Grant Nos.49773195,49502029 and 49928201)the Key Scientific and Technology Project from the Land and Resources Ministry of China(Grant No.200206)+3 种基金Trans—century Training Programme Foundation for the Talents from the Ministry of Education of ChinaVisiting Scholar Foundation of the State Key Laboratory of Mineral Deposit Research in Naniing Universitythe Visiting Scholar Foundation of Labs in Universitiesalso by the Lingnan Foundation of USA.
文摘Hydrothermal clay minerals that formed in the main metallogenic stage of the Changkeng disseminated-type gold deposit in central Guangdong were analyzed by the 40Ar/39Ar laser probe. The results give Ar-Ar isochron ages of 109.9 1.4 to 110.1 1.3 Ma, which are 30 to 50 Ma older than the age of silver ore bodies in the deposit. Both gold and silver mineralizations were not related to hidden granite batholith in the mining district, but probably related to evo-lution of sedimentary basins. This study shows that the 40Ar/39Ar laser probe is a sound dating tool applicable to sediment-hosted disseminated-type gold deposit.
文摘A novel algorithm based on Radon-Ambiguity Transform (RAT) and Adaptive Signal Decomposition (ASD) is presented for the detection and parameter estimation of multicompo-nent Linear Frequency Modulated (LFM) signals. The key problem lies in the chirplet estimation. Genetic algorithm is employed to search for the optimization parameter of chirplet. High estimation accuracy can be obtained even at low Signal-to-Noisc Ratio(SNR). Finally simulation results are provided to demonstrate the performance of the proposed algorithm.
文摘Freshwater ecosystems provide a host of services to humanity. These services are now rapidly being lost, not least because of the inability of making the impacts measurable. To overcome this obstacle, assessment frameworks for freshwater ecosystem services are needed. A simple water equivalent framework to assess the ecological services provided by freshwater ecosystems was developed in this study. It translated the occupation of freshwater ecosystem services into biologically freshwater volumes and then compares this consumption to the freshwater throughput, that is, the ecological capacity available in this region. In this way, we use the example of Yangzhou Prefecture, to account the main categories of human occupation of water ecosystem services. The result showed that there is a huge gap between the consumption and the supply of freshwater ecosystem services. This must encourage local government to make land-use and water management decisions both economically rational and environmentally sound.
基金supported by Ministry of Science and Technology of the People's Republic of China(Grant No.:2022YFC3502300)Beijing Natural Science Foundation(Grant No.:L222150)+2 种基金the National Natural Science Foundation of China(Grant No.:82072247)the second batch of“Ten thousand plan”National High Level Talents Special Support Plan(Grant No.:W02020052)Beijing University of Chinese Medicine(Grant Nos.:XJYS21005,JY21024,MSGZF-202001,2022-syjs-05,and 2022-syjs-10).
文摘The automation of traditional Chinese medicine(TCM)pharmaceuticals has driven the development of process analysis from offline to online.Most of common online process analytical technologies are based on spectroscopy,making the identification and quantification of specific ingredients still a challenge.Herein,we developed a quality control(QC)system for monitoring TCM pharmaceuticals based on paper spray ionization miniature mass spectrometry(mini-MS).It enabled real-time online qualitative and quantitative detection of target ingredients in herbal extracts using mini-MS without chromatographic separation for the first time.Dynamic changes of alkaloids in Aconiti Lateralis Radix Praeparata(Fuzi)during decoction were used as examples,and the scientific principle of Fuzi compatibility was also investigated.Finally,the system was verified to work stably at the hourly level for pilot-scale extraction.This mini-MS based online analytical system is expected to be further developed for QC applications in a wider range of pharmaceutical processes.
基金Supported by National Natural Science Foundation of China(Grant No.51405024)
文摘Traditional simulation methods are unable to meet the requirements of lunar takeo simulations, such as high force output precision, low cost, and repeated use. Considering that cable-driven parallel mechanisms have the advantages of high payload to weight ratio, potentially large workspace, and high-speed motion, these mechanisms have the potential to be used for lunar takeo simulations. Thus, this paper presents a parallel mechanism driven by nine cables. The purpose of this study is to optimize the dimensions of the cable-driven parallel mechanism to meet dynamic workspace requirements under cable tension constraints. The dynamic workspace requirements are derived from the kinematical function requests of the lunar takeo simulation equipment. Experimental design and response surface methods are adopted for building the surrogate mathematical model linking the optimal variables and the optimization indices. A set of dimensional parameters are determined by analyzing the surrogate mathematical model. The volume of the dynamic workspace increased by 46% after optimization. Besides, a force control method is proposed for calculating output vector and sinusoidal forces. A force control loop is introduced into the traditional position control loop to adjust the cable force precisely, while controlling the cable length. The e ectiveness of the proposed control method is verified through experiments. A 5% vector output accuracy and 12 Hz undulation force output can be realized. This paper proposes a cable-driven parallel mechanism which can be used for lunar takeo simulation.
基金Supported by the National Natural Science Foundation of China(No.2 0 2 74 0 13) ,Key Project of the Fujian ProvincialScience and Technology(No.2 0 0 2 I0 0 4 ) and the Fujian Provincial Science Foundation of China(No.E0 110 0 2 7and C0 310 0 0 9)
文摘With sodium dodecyl sulfonate(SDS) as the phase transferring catalyst, N,N-Dilauryl chitosans with a high degree of alkyl group substitution were prepared and characterized by means of FTIR, 1H NMR and elemental analyses. The results indicate that the average degree of alkyl group substitution on the chitosan increases with decreasing the molecular weight of the chitosan. The fully N,N-dilaurylated chitosan was found to be dissolvable in chloroform. The collapsed pressures of the samples derived from chitosan with 3000, 5000 and 10000 dalton are 47.6, 48.2 and 51.0 mN/m, respectively. The surface area occupied by the monomer unit(glucosamine) of all those samples is 0.6 nm2.
文摘Based on high-precision data obtained in the past decade from GPS re-measurement in the North China Network, the Crustal Movement Observation Network of China (CMONOC) and GPS measurement along the Shanxi graben zone, the status and evolution of horizontal crustal movement in the North China region are analyzed. The results show that(1) the Yanshan tectonic zone (Zhangjiakou-Bohai Sea zone)is an active one with the largest horizontal strain in the North China region; The largest tendency differential movement of adjacent blocks is seen between the Yanshan block and the North China plain block; about 2mm/a (left lateral); (2) The significant horizontal differential movement along the boundaries of the North China region is characterized by right-lateral strike-slip movement at the middle-north segment on its west boundary (composed of Yinchuan and other active tectonic zones) and compressive movement at the south segment; while the Yinshan rift zone located along the west segment on its north boundary is dominated by tensile movement. Other boundaries and zones have no obvious differential movement; (3) On the whole, measurements of each period differ from one another, which might result from the nonlinear movement component as well as from the error effect. In the paper, results of the relative movement and strain in different periods are given for different blocks and boundary zones.
文摘In this paper, orthogonal/turbo-codes for mobile DS-CDMA communications are considered. We compare the performances of turbo-codes with those of convolutional codes for noncoherent M-ary orthogonal modulation in multipath fading channels. One method to calculate the branch transition probability of turbo-codes is suggested.By using the parameter of cut-off rate capacity efficiency, 1/2/5 (37,21) turbo-codes are more efficient for 1/3/9(557,663,711) convolutional codes. Given the same spread gain, turbo-codes will increase system's capacity.If SOVA is used in the decoding for turbo-codes case, the dime-delay caused by turbo-decoding is only 1.2 times of that of convolutional codes. Obviously, turbo-codes show better performances at the cost of the hardware complexity of the encoder and the decoder.
文摘Fully acylated chitosan and N, N-diacyl chitosan were prepared. The products were characterized by elemental analysis, FTIR and 1H NMR. The experimental results indicate that the average degree of acylation depends on the volume ratio of pyridine to chloroform in the reaction medium, the chain length of the acylation agent used, and the molecular weight of chitosan raw materials. The XRD measurements were carried out for pure chitosan, fully acylated chitosan and N, N-diacyl chitosan to verify the crystallinity change caused by the acylation.
基金supported by NNSF China(No.82072247)Research Projects of Beijing University of Chinese Medicine(Nos.2021-JYB-XJSJJ-001,XJYS21005 and 2021-SYJS-007)。
文摘Simple saccharides have a variety of biological functions,but their structural diversity and inherent structural features pose a major challenge for rapid analysis.In this work,we developed a derivative-free and ion mobility-free method for the rapid analysis of monosaccharides and disaccharides using paper spray tandem mass spectrometry.Trimeric cluster ions consisting of saccharide analytes,ligands and transition metal ions are used as precursor ions.We defined the R-value as the ratio of the intensity of the product ion that loses one molecule of ligand over the intensity of the product ion that loses one molecule of saccharide via collision induced dissociation(CID).The species and conformation of simple saccharides can be easily differentiated by calculating this R-value.With the capability of directly analyzing clinical samples using paper spray ionization,our method can be used to rapidly quantify the molar ratio of galactose to glucose in dried plasma samples to aid in the diagnosis of galactosemia.The analytical strategy provided herein has good potential to be applied to a wide range of saccharide analysis applications in the future.
基金supported by the National Natural Science Foundation of China(grants 49502029,49928201 and 49773195)the Natural Sciences Foundation of Guangdong Province(No.970123)+3 种基金the Visiting Scholar Foundation of Labs in Universitiesthe Research Foundation of the State Key Laboratory for Mineral Deposits Research in Nanjing UniversityResearch Foundation of Young(originally translated as Youth)Teachers of the National Educational Department and the Training Program of Middle-aged and Young(originally translated as Medium-Youth)Teachers supported by the Lingnan Foundationsupported by the Trans-century Training Program Foundation for the Talents by the Ministry of Education
文摘The Songxi deposit is a newly discovered large Ag (Sb) deposit. By using a suite of high-vacuum quadrupole gas mass spectrometer systems, the authors have recognized many kinds of light hydrocarbons in fluid inclusions of minerals. These hydrocarbons are mainly composed of C1-C4 saturated alkanes, while the contents of C2-C4 unsaturated alkenes and aromatic hydrocarbons are quite low, suggesting that the metallogenic processes have not been affected by magmatic activities. Chemical equilibrium studies show that these hydrocarbons may be a mixture of organic gases generated by microorganism activity and those by thermal cracking of type-n kerogens (kukersite) in sedimentary host rocks, and the former may constitute more than two-thirds, implying that microorganism might have played an important role in the metallogenesis. The equilibrium temperature of the latter is about 300℃, which is much higher than the geothermal temperature at the estimated depth of metallogenesis. Thus, the light hydrocarbons generated by thermal cracking of kerogens probably originated in the deep part of the sedimentary basins and then migrated through a long distance to shallower horizons of the basin. Based on the composition of light hydrocarbons in fluid inclusions, the authors infer that the Songxi deposit was formed in a continental rift. The analytical data presented in this paper support from one aspect the genetic model that the Songxi deposit may be a sedimentary hot brine transformed deposit instead of a submarine basic volcanic exhalation and low-medium temperature volcanic hydrothermal fluid filling deposit proposed by most previous researchers.
