文摘利用激光诱导击穿光谱(LIBS,laser-induced breakdown spectroscopy)技术对掺杂Cu、Pb元素的土壤样品进行定量分析,寻找最优实验条件。实验使用直接定标法和内标法对元素特征谱线进行拟合,根据计算相关系数及检出限选择合适的数据处理方法。由实验结果可知,能量设定在70 m J,延迟时间为2μs可以达到元素谱线强度和信背比的最优实验条件。以Fe元素谱线作为内标校准曲线与直接定标相比,两种掺杂的重金属元素的拟合系数R2分别比直接定标提高了1.4%和3.7%。实验表明,通过Fe元素作为内标元素,能够降低激光器能量波动的影响,提高拟合精准度。
基金Open Fund of National Defense Key Disciplines Laboratory of Light Alloy Processing Science and Technology(EG202203331)Open Fund of State Key Laboratory of Advanced Welding and Joining(AWJ-23R03)+1 种基金Open Fund of Jiangxi Key Laboratory of Forming and Joining Technology for Aerospace Components(EL202203323)Start-up Fund of Nanchang Hangkong University(EA202203138)。