INTRODUCTIONThe prevalence of hyperuricenlia （HUA） has increased in China in the recent years in relation to socioeconomic developments and changing lifestyles and diets, with a trend toward onset at younger age. HU...INTRODUCTIONThe prevalence of hyperuricenlia （HUA） has increased in China in the recent years in relation to socioeconomic developments and changing lifestyles and diets, with a trend toward onset at younger age. HUA has become the second most common metabolic disease after diabetes mellitus. Like gout, HUA is also associated with the occurrence and progression of disorders of the urinary, endocrine, metabolic, cardio-cerebrovascular, and other systems.展开更多
High alumina slag will cause severe corrosion at the interface of alumina refractory,and the wetting behavior of slag is a key factor influencing the corrosion resistance of refractory ceramics.The static magnetic fie...High alumina slag will cause severe corrosion at the interface of alumina refractory,and the wetting behavior of slag is a key factor influencing the corrosion resistance of refractory ceramics.The static magnetic field is a promising solution for improvement in the slag resistance of refractory.The wetting of alumina refractory ceramics with different basicities of high alumina slags under a weak static magnetic field was analyzed,given that a weak static magnetic field can affect the corrosion behavior of refractory ceramics.Taking slag S_(3) as an example,when there was an external static magnetic field of 1.0 mT at 1600 ℃,the thickness of calcium aluminate reaction layer at the interface decreased by 36.7%,the denting depth of interface decreased by 35.6%,and the apparent wetting angle increased by 20%.The living radicals and their formation path in oxide melts were verified by first-principles calculation combined with electron paramagnetic resonance spectroscopy analysis.The influence of the flux density of a weak static magnetic field on the wetting behavior of slags was also explored.The contact angle of the slags increased owing to the inhibitory effect of magnetic field on the radicalinvolved reaction at the interface of the slag and the alumina refractory ceramic.The relationships between the magnetic flux density,diffusion coefficient,slag microstructure(hyperfine coupling constant),and contact angle were established.This provides a theoretical basis for the field control of radical involved reactive wetting between inorganic oxide slags and solid oxide ceramics.展开更多
Gleeble-1500D thermal simulator was used to simulate the thermal cycle of different welding processes in C-Mn steel. The toughness of steel matrix and heat-affected zone （HAZ） was investigated, and the microstructur...Gleeble-1500D thermal simulator was used to simulate the thermal cycle of different welding processes in C-Mn steel. The toughness of steel matrix and heat-affected zone （HAZ） was investigated, and the microstructure and inclusion were characterized as well. The results showed that the welding process has a great influence on the microstructure in HAZ. When t8/5 （the cooling time from 800 to 500℃ ） value of the welding process is less than 111 s, the microstructure in HAZ is mainly bainite/Widmanstatten in spite of the addition of rare earth. However, when t8/5 value is more than 250 s, there are a lot of acicular ferrites in the steel containing rare earth, while the main microstructures are grain boundary ferrite and bainite/Widmanstatten in the steel without rare earth. The impact toughness of the HAZ at ambient temperature first decreases and then increases with the increase in t8/5 value. The impact toughness is the worst when t8/5 value is 111 s. Rare earth can improve the impact performance of HAZ at ambient temperature, especially when t8/5 value of the welding process is 445 s. After the rare earth treatment, the cooling rate of forming acicular ferrite is about 0.5-7.5 ℃/s. Acicular ferrite can form even during the welding process with larger t8/5 value up to 600 s in rare earth-treated steel.展开更多
The composition,morphology,size,and number of inclusions in Fe-22Mn-xAl-0.7C(x=0.5%,5.2%,and 10.5%)lightweight steels after smelting and heat treatment experiments are characterized by scanning electron microscopy and...The composition,morphology,size,and number of inclusions in Fe-22Mn-xAl-0.7C(x=0.5%,5.2%,and 10.5%)lightweight steels after smelting and heat treatment experiments are characterized by scanning electron microscopy and energy-dispersive X-ray spectroscopy from both 2D and 3D perspectives.The inclusions are classified into eight categories according to chemistry and morphology.For the steel sample with a low Al content(0.5%),the inclusions are MnS,AlN-MnS,and Al_(2)O_(3)-MnS,among which Al_(2)O_(3)-MnS is the primary type.With the increase in Al content in the steel sample(to 5.2%),the populations of AlN and AlN-MnS inclusions of 1-3μm in diameter increase.A further increase in Al content(to 10.5%)leads to a significant decrease in the amount of AlN inclusions of 1-3μm in diameter,and an increase in the amount of AlN-MnS inclusions.The precipitation behavior during the phase transformation is also studied by FactSage 8.0 thermodynamic software,and a precipitation mechanism is proposed based on the calculation results.During the heat treatment,AlN inclusions re-precipitate out,due to the interactions between Al and dissolved N in the steel matrix.However,AlN inclusions cannot grow large because of unfavorable kinetic conditions.The re-precipitation phenomenon of AlN is predominant under low Al and high N conditions but not at high Al cases.展开更多
文摘INTRODUCTIONThe prevalence of hyperuricenlia （HUA） has increased in China in the recent years in relation to socioeconomic developments and changing lifestyles and diets, with a trend toward onset at younger age. HUA has become the second most common metabolic disease after diabetes mellitus. Like gout, HUA is also associated with the occurrence and progression of disorders of the urinary, endocrine, metabolic, cardio-cerebrovascular, and other systems.
基金supported by the National Natural Science Foundation of China(52272022)Key Program of the Natural Science Foundation of Hubei Province of China(2021CFA071).
文摘High alumina slag will cause severe corrosion at the interface of alumina refractory,and the wetting behavior of slag is a key factor influencing the corrosion resistance of refractory ceramics.The static magnetic field is a promising solution for improvement in the slag resistance of refractory.The wetting of alumina refractory ceramics with different basicities of high alumina slags under a weak static magnetic field was analyzed,given that a weak static magnetic field can affect the corrosion behavior of refractory ceramics.Taking slag S_(3) as an example,when there was an external static magnetic field of 1.0 mT at 1600 ℃,the thickness of calcium aluminate reaction layer at the interface decreased by 36.7%,the denting depth of interface decreased by 35.6%,and the apparent wetting angle increased by 20%.The living radicals and their formation path in oxide melts were verified by first-principles calculation combined with electron paramagnetic resonance spectroscopy analysis.The influence of the flux density of a weak static magnetic field on the wetting behavior of slags was also explored.The contact angle of the slags increased owing to the inhibitory effect of magnetic field on the radicalinvolved reaction at the interface of the slag and the alumina refractory ceramic.The relationships between the magnetic flux density,diffusion coefficient,slag microstructure(hyperfine coupling constant),and contact angle were established.This provides a theoretical basis for the field control of radical involved reactive wetting between inorganic oxide slags and solid oxide ceramics.
基金Acknowledgements The authors are grateful for the support of the National Natural Science Foundation of China （NSFC） （Grant Nos. 51804229, 51604198 and 51474163）, the Wuhan University of Science and Technology （WUST） Backbone Training Project of Scientific and Technological （Grant No. 2017xz001） and the Open Fund of Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education （Grant No. FMRUlab17-6）.
文摘Gleeble-1500D thermal simulator was used to simulate the thermal cycle of different welding processes in C-Mn steel. The toughness of steel matrix and heat-affected zone （HAZ） was investigated, and the microstructure and inclusion were characterized as well. The results showed that the welding process has a great influence on the microstructure in HAZ. When t8/5 （the cooling time from 800 to 500℃ ） value of the welding process is less than 111 s, the microstructure in HAZ is mainly bainite/Widmanstatten in spite of the addition of rare earth. However, when t8/5 value is more than 250 s, there are a lot of acicular ferrites in the steel containing rare earth, while the main microstructures are grain boundary ferrite and bainite/Widmanstatten in the steel without rare earth. The impact toughness of the HAZ at ambient temperature first decreases and then increases with the increase in t8/5 value. The impact toughness is the worst when t8/5 value is 111 s. Rare earth can improve the impact performance of HAZ at ambient temperature, especially when t8/5 value of the welding process is 445 s. After the rare earth treatment, the cooling rate of forming acicular ferrite is about 0.5-7.5 ℃/s. Acicular ferrite can form even during the welding process with larger t8/5 value up to 600 s in rare earth-treated steel.
基金This work was supported by the National Natural Science Foundation of China(Grant No.U20A20270).
文摘The composition,morphology,size,and number of inclusions in Fe-22Mn-xAl-0.7C(x=0.5%,5.2%,and 10.5%)lightweight steels after smelting and heat treatment experiments are characterized by scanning electron microscopy and energy-dispersive X-ray spectroscopy from both 2D and 3D perspectives.The inclusions are classified into eight categories according to chemistry and morphology.For the steel sample with a low Al content(0.5%),the inclusions are MnS,AlN-MnS,and Al_(2)O_(3)-MnS,among which Al_(2)O_(3)-MnS is the primary type.With the increase in Al content in the steel sample(to 5.2%),the populations of AlN and AlN-MnS inclusions of 1-3μm in diameter increase.A further increase in Al content(to 10.5%)leads to a significant decrease in the amount of AlN inclusions of 1-3μm in diameter,and an increase in the amount of AlN-MnS inclusions.The precipitation behavior during the phase transformation is also studied by FactSage 8.0 thermodynamic software,and a precipitation mechanism is proposed based on the calculation results.During the heat treatment,AlN inclusions re-precipitate out,due to the interactions between Al and dissolved N in the steel matrix.However,AlN inclusions cannot grow large because of unfavorable kinetic conditions.The re-precipitation phenomenon of AlN is predominant under low Al and high N conditions but not at high Al cases.
