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铽与4-酰代吡唑啉酮-5的三元配合物的合成与荧光性质 被引量:6
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作者 李琴 周德建 +3 位作者 黄春辉 姚光庆 S.umetani M.Matsui 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1997年第6期829-833,共5页
合成并表征了一系列铽与含不同个酰代-的1-苯基-3-甲基-吡唑啉酮-5的三元配合物Tb(L)3·2H2O和Tb(L)3·Dipy[L=1-苯基-3-甲基-4乙酰基吡唑啉酮-5(PMAP),1-苯基-3-甲基-4-丙酰基吡唑啉酮-5(PMPP),1-苯基-3-甲基-个异... 合成并表征了一系列铽与含不同个酰代-的1-苯基-3-甲基-吡唑啉酮-5的三元配合物Tb(L)3·2H2O和Tb(L)3·Dipy[L=1-苯基-3-甲基-4乙酰基吡唑啉酮-5(PMAP),1-苯基-3-甲基-4-丙酰基吡唑啉酮-5(PMPP),1-苯基-3-甲基-个异丁酰基吡唑啉酮-5(PMIBP),1-苯基-3甲基-4-特戊酰基吡唑啉酮-5(PMPVP),1-苯基-3-甲基-4-苯甲酰基吡唑啉酮-5(PMBP),Dipy=2,2’联吡啶].用频域法测定了它们在溶液中的荧光寿命.结果表明,4-烷基酰代吡唑啉酮-5配合物的荧光强度比4-苯甲酰基吡唑啉酮-5配合物强3个数量级. 展开更多
关键词 苯基 甲基 酰代吡唑啉酮 配合物 荧光性质
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Direct Observation of Thermoelectric Magnetic Convection in Unidirectionally Solidified Al-Cu Alloys
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作者 Hideyuki Yasuda Keisuke Inoue +4 位作者 Yudai Minami Tomoya Nagira Masato Yoshiya Kentaro Uesugi Keiji umetani 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2012年第S1期34-39,共6页
This study performed the time-resolved and in-situ observation of unidirectional solidification of A1-Cu and Sn-Bi alloys under a static magnetic field up to 0.45 T.Irt the case of Sn-Bi alloy,the static magnetic fiel... This study performed the time-resolved and in-situ observation of unidirectional solidification of A1-Cu and Sn-Bi alloys under a static magnetic field up to 0.45 T.Irt the case of Sn-Bi alloy,the static magnetic field reduced the local convection around the primary dendrite arms.No thermoelectric convection was detected.On the other hand,the thermoelectric convection was clearly observed in Al-Cu alloy.The observed convection was consistently explained by the thermoelectric magnetic convection.According to a simplified model,the thermoelectric magnetic convection can be induced if the difference in the thermoelectric power between the solid and the liquid phases is in the order of 1 μV/K and temperature gradient is several K/mm. 展开更多
关键词 static magnetic field natural convection thermoelectric effect DENDRITE
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