Efficient sterilization by a plasma photocatalytic system(PPS)requires strong synergy between plasma and photocatalyst to inactivate microorganisms while suppressing the formation of secondary pollutants.Here,we repor...Efficient sterilization by a plasma photocatalytic system(PPS)requires strong synergy between plasma and photocatalyst to inactivate microorganisms while suppressing the formation of secondary pollutants.Here,we report that a PPS constructed from a needle array corona discharge and Au/TiO2plasmonic nanocatalyst could remarkably improve the sterilization of Escherichia coli(E.coli)and alleviate formation of the discharge pollutant O3.At 6 kV,the combination of corona discharge and Au/TiO2achieves sterilization efficiency of 100%within an exposure time of 5 min.At 5 kV and an exposure time of 8 min,the presence of Au/TiO2improves sterilization efficiency of the corona discharge from 73%to 91%and reduces the O3concentration from 0.38 to 0.04 ppm,whereas the presence of TiO2reduces the sterilization efficiency and O3concentration to 66%and 0.17 ppm,respectively.The Au/TiO2in the PPS enables a uniform corona discharge,enhances the interaction between plasma,E.coli and nanocatalysts,and suppresses the formation of O3.Further,the Au/TiO2can be excited by ultraviolet-visible light emitted from the plasma to generate electron-hole pairs,and thus contributes to the formation of reactive radicals and the oxidative inactivation of E.coli.The PPS constructed from a needle array corona discharge and Au-based plasmonic nanocatalyst provides a promising approach for developing high-efficiency sterilization techniques.展开更多
根据2006-2010年春季(3-5月)大型罩网渔船的生产监测数据,运用广义线性模型(Generalized Linear Model,GLM)对鸢乌贼单位捕捞努力量渔获量(Catch Per Unit Effort,CPUE)进行标准化,同时结合卫星遥感数据(海表温度、叶绿素a浓度及海面风...根据2006-2010年春季(3-5月)大型罩网渔船的生产监测数据,运用广义线性模型(Generalized Linear Model,GLM)对鸢乌贼单位捕捞努力量渔获量(Catch Per Unit Effort,CPUE)进行标准化,同时结合卫星遥感数据(海表温度、叶绿素a浓度及海面风场)对西沙-中沙海域春季鸢乌贼资源量变化和海洋环境的关系进行统计分析。结果表明,春季鸢乌贼资源在海表温度(Sea Surface Temperature,SST)25~28.5℃、叶绿素a浓度(chlorophyll aconcentration,Chl a)0.1~0.16mg/m3时随着水温的升高和叶绿素a浓度的降低而增大,资源量最高的SST范围为27~28.5℃、Chl a范围为0.1~0.13mg/m3。西沙-中沙海域春季Chl a峰值出现在3月份,该时期为鸢乌贼的繁殖高峰期。鸢乌贼的资源量在5月份达到峰值,其对Chl a的响应时间延迟约2个月。此外,2008年春季鸢乌贼资源量波动较大,与2007-2008年的拉尼娜事件引起的气候异常有关。研究结果对于了解西沙-中沙海域鸢乌贼资源变动规律、指导鸢乌贼资源科学生产、开发南海外海渔业资源等具有重要意义。展开更多
基金National Natural Science Foundation of China(Nos.52041001,21808024)Natural Science Foundation of Liaoning Province(No.2020-MS-126)Special Foundation for Key Fields of Colleges and Universities in Guangdong Province(No.2021ZDZX4094)。
文摘Efficient sterilization by a plasma photocatalytic system(PPS)requires strong synergy between plasma and photocatalyst to inactivate microorganisms while suppressing the formation of secondary pollutants.Here,we report that a PPS constructed from a needle array corona discharge and Au/TiO2plasmonic nanocatalyst could remarkably improve the sterilization of Escherichia coli(E.coli)and alleviate formation of the discharge pollutant O3.At 6 kV,the combination of corona discharge and Au/TiO2achieves sterilization efficiency of 100%within an exposure time of 5 min.At 5 kV and an exposure time of 8 min,the presence of Au/TiO2improves sterilization efficiency of the corona discharge from 73%to 91%and reduces the O3concentration from 0.38 to 0.04 ppm,whereas the presence of TiO2reduces the sterilization efficiency and O3concentration to 66%and 0.17 ppm,respectively.The Au/TiO2in the PPS enables a uniform corona discharge,enhances the interaction between plasma,E.coli and nanocatalysts,and suppresses the formation of O3.Further,the Au/TiO2can be excited by ultraviolet-visible light emitted from the plasma to generate electron-hole pairs,and thus contributes to the formation of reactive radicals and the oxidative inactivation of E.coli.The PPS constructed from a needle array corona discharge and Au-based plasmonic nanocatalyst provides a promising approach for developing high-efficiency sterilization techniques.
文摘根据2006-2010年春季(3-5月)大型罩网渔船的生产监测数据,运用广义线性模型(Generalized Linear Model,GLM)对鸢乌贼单位捕捞努力量渔获量(Catch Per Unit Effort,CPUE)进行标准化,同时结合卫星遥感数据(海表温度、叶绿素a浓度及海面风场)对西沙-中沙海域春季鸢乌贼资源量变化和海洋环境的关系进行统计分析。结果表明,春季鸢乌贼资源在海表温度(Sea Surface Temperature,SST)25~28.5℃、叶绿素a浓度(chlorophyll aconcentration,Chl a)0.1~0.16mg/m3时随着水温的升高和叶绿素a浓度的降低而增大,资源量最高的SST范围为27~28.5℃、Chl a范围为0.1~0.13mg/m3。西沙-中沙海域春季Chl a峰值出现在3月份,该时期为鸢乌贼的繁殖高峰期。鸢乌贼的资源量在5月份达到峰值,其对Chl a的响应时间延迟约2个月。此外,2008年春季鸢乌贼资源量波动较大,与2007-2008年的拉尼娜事件引起的气候异常有关。研究结果对于了解西沙-中沙海域鸢乌贼资源变动规律、指导鸢乌贼资源科学生产、开发南海外海渔业资源等具有重要意义。
