The lower crustal xenolith of mafic two_pyroxene granulite (the majority) and hypersthene granulite in the Cenozoic basalt at Hannuoba have the characteristics of igneous blastic structure and granulite facies metamor...The lower crustal xenolith of mafic two_pyroxene granulite (the majority) and hypersthene granulite in the Cenozoic basalt at Hannuoba have the characteristics of igneous blastic structure and granulite facies metamorphic recrystallization. Study on the zircon chronology and REE geochemistry of granulite xenolith shows that the underplating of basic magma into the lower crust during late Mesozoic led to the formation of mafic accumulate, which further through metamorphism of granulite facies formed the high_density and high_velocity crustal bottom layer at the lower crust. This suggests that the underplating of mantle magma is the important way for the vertical overgrowth of continental crust since the Phanerozoic and provides new evidence for crust_mantle interaction.展开更多
The Dalinor volcanic swarm, located south of Xilinhot, Inner Mongolia of China, was a result of multistage eruptions that occurred since the Neogene period. This swarm is mainly composed of volcanic cones and lava tab...The Dalinor volcanic swarm, located south of Xilinhot, Inner Mongolia of China, was a result of multistage eruptions that occurred since the Neogene period. This swarm is mainly composed of volcanic cones and lava tablelands. The objective of this study is to map the topography and morphology of this volcanic swarm. It is based on a variety of data collected from various sources, such as the digital elevation model （DEM）, Landsat images, and a 1：50,000 topographic map, in addition to various software platforms, including ArcGIS, Envi4.8, Global Mapper, and Google Earth for data processing and interpretation. The results show that the overall topography of the volcanic swarm is a platform with a central swell having great undulation, sizable gradient variations, a rough surface, and small terrain relief. According to the undulating characteristics of the line profile, the volcanic swarm can be divided into four stairs with heights of 1,280 m, 1,360 m, 1,440 m, and 1,500 m. The analysis of the swath profile characterizes the two clusters of volcanoes with different height ranges and evolution. The lava tablelands and volcanic cones are distributed in nearly EW-trending belts, where tableland coverage was delineated with superposed layers of gradients and degrees of relief. According to the morphology, the volcanic cones were classified into four types： conical, composite, dome, and shield. The formation causes and classification basis for each type of volcanic cone were analyzed and their parameters were extracted. The HID ratios of all types of volcanic cones were then statistically determined and projected to create a map of volcanic density distribution. Based on the relationship between distribution and time sequence of the formation of different volcanic cones, itcan be inferred that the volcanic eruptions migrated from the margins to the center of the lava plateau. The central area was formed through superposition of multi-stage eruptive materials. In addition, a large number of early shield volcanoes展开更多
Wangtian’ e volcano, about 30 km south of Tianchi volcano is another large scale volcano center on the south slope of Changbaishan with its nearly 4 000 km^2 area of volcanic rocks distributed over the border area of...Wangtian’ e volcano, about 30 km south of Tianchi volcano is another large scale volcano center on the south slope of Changbaishan with its nearly 4 000 km^2 area of volcanic rocks distributed over the border area of the Chinese side. Based on the field occurrence, petrology and K-Ar age dating of its volcanic rocks, it can be shown that the Wangtian’e volcano had experienced two developing stages of shield forming and cone forming, while its volcanic activities can be divided into three periods: Changbai period (? —2.87 Ma), Wangtian’e period (2.69—2.41 Ma) and Hongtoushan period (2.12 Ma). Its petrographic change goes from trachybasalt→basaltic trachyandesite, trachyte→alkalic rhyolite, with a feature of bimodal volcanic rock combination similar to yet a bit different from that of Tianchi volcano, and is a new scene for study of volcanic magma evaluation of Changbaishan volcanoes.展开更多
Hydrogen evolution reaction is a critical reaction in water splitting for hydrogen production.However,developing effective and stable non‐noble‐metal electrocatalysts which work well at high current densities demand...Hydrogen evolution reaction is a critical reaction in water splitting for hydrogen production.However,developing effective and stable non‐noble‐metal electrocatalysts which work well at high current densities demanded by industry still remain great challenge.Herein,taking advantage of the highly tunable metal‐organic framework(MOF)templates,nitrogen doped binary transition metal phosphides electrocatalysts(N‐CoP_(x)/Ni_(2)P)with three‐dimensional(3D)conductive network structure were successfully synthesized.The 3D open porous channels could expose more catalytically active sites;nitrogen doping and the synergistic effect between CoP and Ni_(2)P can increase the electron density of Co atoms at active sites,further optimizing the Gibbs free energy of hydrogen(ΔGH*)and water(ΔG_(H_(2)O*)).As a result,the obtained N‐CoP_(x)/Ni_(2)P catalyst exhibits extraordinary electrocatalytic activity in a wide pH range.Especially,it requires an extremely low overpotential of 152 mV to deliver a high current density of 650 mA cm^(–2) in alkaline media.This work may shed some light on the rational design of cheap electrocatalysts and electrode materials that work well at high current densities.展开更多
文摘The lower crustal xenolith of mafic two_pyroxene granulite (the majority) and hypersthene granulite in the Cenozoic basalt at Hannuoba have the characteristics of igneous blastic structure and granulite facies metamorphic recrystallization. Study on the zircon chronology and REE geochemistry of granulite xenolith shows that the underplating of basic magma into the lower crust during late Mesozoic led to the formation of mafic accumulate, which further through metamorphism of granulite facies formed the high_density and high_velocity crustal bottom layer at the lower crust. This suggests that the underplating of mantle magma is the important way for the vertical overgrowth of continental crust since the Phanerozoic and provides new evidence for crust_mantle interaction.
基金This work was supported by the program ＂Volcanic rock chronology of the Xilinhot volcanic swarm in Inner Mongolia＂ funded by the National Key Laboratory of Earthquake Dynamics, Institute of Geology, China Earthquake Administration （LED2013B05） and the program ＂Genesis and evolution of the Quaternary Dalinor volcanic swarm＂ ffmded by the National Natural Science Foundation of China （Grant No. 41572320）.
文摘The Dalinor volcanic swarm, located south of Xilinhot, Inner Mongolia of China, was a result of multistage eruptions that occurred since the Neogene period. This swarm is mainly composed of volcanic cones and lava tablelands. The objective of this study is to map the topography and morphology of this volcanic swarm. It is based on a variety of data collected from various sources, such as the digital elevation model （DEM）, Landsat images, and a 1：50,000 topographic map, in addition to various software platforms, including ArcGIS, Envi4.8, Global Mapper, and Google Earth for data processing and interpretation. The results show that the overall topography of the volcanic swarm is a platform with a central swell having great undulation, sizable gradient variations, a rough surface, and small terrain relief. According to the undulating characteristics of the line profile, the volcanic swarm can be divided into four stairs with heights of 1,280 m, 1,360 m, 1,440 m, and 1,500 m. The analysis of the swath profile characterizes the two clusters of volcanoes with different height ranges and evolution. The lava tablelands and volcanic cones are distributed in nearly EW-trending belts, where tableland coverage was delineated with superposed layers of gradients and degrees of relief. According to the morphology, the volcanic cones were classified into four types： conical, composite, dome, and shield. The formation causes and classification basis for each type of volcanic cone were analyzed and their parameters were extracted. The HID ratios of all types of volcanic cones were then statistically determined and projected to create a map of volcanic density distribution. Based on the relationship between distribution and time sequence of the formation of different volcanic cones, itcan be inferred that the volcanic eruptions migrated from the margins to the center of the lava plateau. The central area was formed through superposition of multi-stage eruptive materials. In addition, a large number of early shield volcanoes
文摘Wangtian’ e volcano, about 30 km south of Tianchi volcano is another large scale volcano center on the south slope of Changbaishan with its nearly 4 000 km^2 area of volcanic rocks distributed over the border area of the Chinese side. Based on the field occurrence, petrology and K-Ar age dating of its volcanic rocks, it can be shown that the Wangtian’e volcano had experienced two developing stages of shield forming and cone forming, while its volcanic activities can be divided into three periods: Changbai period (? —2.87 Ma), Wangtian’e period (2.69—2.41 Ma) and Hongtoushan period (2.12 Ma). Its petrographic change goes from trachybasalt→basaltic trachyandesite, trachyte→alkalic rhyolite, with a feature of bimodal volcanic rock combination similar to yet a bit different from that of Tianchi volcano, and is a new scene for study of volcanic magma evaluation of Changbaishan volcanoes.
文摘Hydrogen evolution reaction is a critical reaction in water splitting for hydrogen production.However,developing effective and stable non‐noble‐metal electrocatalysts which work well at high current densities demanded by industry still remain great challenge.Herein,taking advantage of the highly tunable metal‐organic framework(MOF)templates,nitrogen doped binary transition metal phosphides electrocatalysts(N‐CoP_(x)/Ni_(2)P)with three‐dimensional(3D)conductive network structure were successfully synthesized.The 3D open porous channels could expose more catalytically active sites;nitrogen doping and the synergistic effect between CoP and Ni_(2)P can increase the electron density of Co atoms at active sites,further optimizing the Gibbs free energy of hydrogen(ΔGH*)and water(ΔG_(H_(2)O*)).As a result,the obtained N‐CoP_(x)/Ni_(2)P catalyst exhibits extraordinary electrocatalytic activity in a wide pH range.Especially,it requires an extremely low overpotential of 152 mV to deliver a high current density of 650 mA cm^(–2) in alkaline media.This work may shed some light on the rational design of cheap electrocatalysts and electrode materials that work well at high current densities.
