Duplexα/β-SiAlON ceramic cutting inserts(30α:70β)were synthesized by microwave sintering.The effects of solid solution parameters(m,n,z),synthesis temperature,and amount of excess Y_(2)O_(3) synthesis additive on ...Duplexα/β-SiAlON ceramic cutting inserts(30α:70β)were synthesized by microwave sintering.The effects of solid solution parameters(m,n,z),synthesis temperature,and amount of excess Y_(2)O_(3) synthesis additive on phase assemblage,microstructure,mechanical properties,and cutting performance were systematically investigated.It was found that increasing m value could improve the formation ofαphase while high z value over 1.0 resulted in the dissolution ofαphase intoβphase and intergranular phase.Increasing the amount of excess Y_(2)O_(3) could promote densification and elongatedβgrain growth;however,the excess Y_(2)O_(3) amount above 4 wt%resulted in substantial crystallization of M'SS phase,thus declining the mechanical properties and wear resistance.The microwave-synthesizedα/β-SiAlON cutting insert with modified parameters(m=1.7,n=1.0,z=0.7,and 3 wt%excess Y_(2)O_(3))was obtained with optimal comprehensive properties,whose tool life was found to increase by approximately 75%in high-speed milling of Inconel 718 superalloy compared to the commercialα/β-SiAlON cutting insert.展开更多
In this study, powder mixtures containing(Ti, W)C additions(10, 20, 30 and 40 wt%) were prepared and then consolidated at 1200, 1250, 1300 and 1350 °C by spark plasma sintering. The effect of(Ti, W)C additions on...In this study, powder mixtures containing(Ti, W)C additions(10, 20, 30 and 40 wt%) were prepared and then consolidated at 1200, 1250, 1300 and 1350 °C by spark plasma sintering. The effect of(Ti, W)C additions on the microstructure and mechanical properties of ultrafine WC–Co materials was investigated. The results demonstrate that the(Ti, W)C not only retards the sintering densification but also increases the porosity of sintered samples. The increasing sintering temperature is beneficial to the densification but results in the grain coarsening and the dissolution of W in(Ti, W)C. Moreover, there are no(Ti, W)C grains with obvious core/rim structure in the microstructure. With the(Ti, W)C increasing from 10 to 20 wt%, the hardness increases and fracture toughness changes hardly. However, the hardness and fracture toughness decrease slightly as the(Ti, W)C further increases. The transgranular fracture of(Ti, W)C phases is responsible for the slight reduction in fracture toughness. The sample with 20 wt%(Ti, W)C has high hardness and fracture toughness( HV : 21.3 GPa, KIC: 9.8 MPa m1/2).展开更多
Spark plasma sintering(SPS)is a highly efficient method for the preparation ofα/β-SiAlON ceramics.However,the rapid preparation of large-scaleα/β-SiAlON ceramic components with reliable mechanical properties is di...Spark plasma sintering(SPS)is a highly efficient method for the preparation ofα/β-SiAlON ceramics.However,the rapid preparation of large-scaleα/β-SiAlON ceramic components with reliable mechanical properties is difficult via SPS due to their near-insulating properties.In this study,high-performanceα/β-SiAlON ceramic end mill rods with large aspect ratios were successfully prepared via SPS.Two different types of sintering processes(namely vertical-round-rod(VRR)and horizontal-square-rod(HSR)processes)were developed,and their effects on the phase composition,microstructure,mechanical properties,and machining performance of theα/β-SiAlON ceramic end mill rods were studied.The electric and temperature field distributions during sintering were studied through an electro–thermal simulation.The simulated and experimental temperature distributions are in good agreement.In contrast to VRR samples,HSR samples with a small axial size show a uniform temperature distribution and satisfactory microstructures within a certain range of dimensions as well as the expected phase composition;furthermore,elongatedβ-SiAlON grains are preferentially oriented in the direction perpendicular to the sintering pressure direction.As a result,the HSR samples exhibit better mechanical properties and machining performance than the VRR samples.展开更多
基金The work is supported by the National Natural Science Foundation of China(Nos.51875291 and 52075266)the Excellent Youth Fund of Jiangsu Province(No.BK20190070)the Fundamental Research Funds for the Central Universities(No.30920032206).
文摘Duplexα/β-SiAlON ceramic cutting inserts(30α:70β)were synthesized by microwave sintering.The effects of solid solution parameters(m,n,z),synthesis temperature,and amount of excess Y_(2)O_(3) synthesis additive on phase assemblage,microstructure,mechanical properties,and cutting performance were systematically investigated.It was found that increasing m value could improve the formation ofαphase while high z value over 1.0 resulted in the dissolution ofαphase intoβphase and intergranular phase.Increasing the amount of excess Y_(2)O_(3) could promote densification and elongatedβgrain growth;however,the excess Y_(2)O_(3) amount above 4 wt%resulted in substantial crystallization of M'SS phase,thus declining the mechanical properties and wear resistance.The microwave-synthesizedα/β-SiAlON cutting insert with modified parameters(m=1.7,n=1.0,z=0.7,and 3 wt%excess Y_(2)O_(3))was obtained with optimal comprehensive properties,whose tool life was found to increase by approximately 75%in high-speed milling of Inconel 718 superalloy compared to the commercialα/β-SiAlON cutting insert.
基金the National Natural Science Foundation of China(Nos.51775280 and 51675285)the Six Talent Peaks Project in Jiangsu Province(No.2016-HKHT-019)。
文摘In this study, powder mixtures containing(Ti, W)C additions(10, 20, 30 and 40 wt%) were prepared and then consolidated at 1200, 1250, 1300 and 1350 °C by spark plasma sintering. The effect of(Ti, W)C additions on the microstructure and mechanical properties of ultrafine WC–Co materials was investigated. The results demonstrate that the(Ti, W)C not only retards the sintering densification but also increases the porosity of sintered samples. The increasing sintering temperature is beneficial to the densification but results in the grain coarsening and the dissolution of W in(Ti, W)C. Moreover, there are no(Ti, W)C grains with obvious core/rim structure in the microstructure. With the(Ti, W)C increasing from 10 to 20 wt%, the hardness increases and fracture toughness changes hardly. However, the hardness and fracture toughness decrease slightly as the(Ti, W)C further increases. The transgranular fracture of(Ti, W)C phases is responsible for the slight reduction in fracture toughness. The sample with 20 wt%(Ti, W)C has high hardness and fracture toughness( HV : 21.3 GPa, KIC: 9.8 MPa m1/2).
基金supported by the National Natural Science Foundation of China(Nos.52075266,51875291)Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX22_0402).
文摘Spark plasma sintering(SPS)is a highly efficient method for the preparation ofα/β-SiAlON ceramics.However,the rapid preparation of large-scaleα/β-SiAlON ceramic components with reliable mechanical properties is difficult via SPS due to their near-insulating properties.In this study,high-performanceα/β-SiAlON ceramic end mill rods with large aspect ratios were successfully prepared via SPS.Two different types of sintering processes(namely vertical-round-rod(VRR)and horizontal-square-rod(HSR)processes)were developed,and their effects on the phase composition,microstructure,mechanical properties,and machining performance of theα/β-SiAlON ceramic end mill rods were studied.The electric and temperature field distributions during sintering were studied through an electro–thermal simulation.The simulated and experimental temperature distributions are in good agreement.In contrast to VRR samples,HSR samples with a small axial size show a uniform temperature distribution and satisfactory microstructures within a certain range of dimensions as well as the expected phase composition;furthermore,elongatedβ-SiAlON grains are preferentially oriented in the direction perpendicular to the sintering pressure direction.As a result,the HSR samples exhibit better mechanical properties and machining performance than the VRR samples.
