Defects formed at the surface,buried interface and grain boundaries(GB)of CsPbI_(3)perovskite films considerably limit photovoltaic performance.Such defects could be passivated effectively by the most prevalent post m...Defects formed at the surface,buried interface and grain boundaries(GB)of CsPbI_(3)perovskite films considerably limit photovoltaic performance.Such defects could be passivated effectively by the most prevalent post modification strategy without compromising the photoelectric properties of perovskite films,but it is still a great challenge to make this strategy comprehensive to different defects spatially distributed throughout the films.Herein,a spatially selective defect management(SSDM)strategy is developed to roundly passivate various defects at different locations within the perovskite film by a facile one-step treatment procedure using a piperazine-1,4-diium tetrafluoroborate(PZD(BF_(4))_(2))solution.The small-size PZD^(2+)cations could penetrate into the film interior and even make it all the way to the buried interface of CsPbI_(3)perovskite films,while the BF_(4)^(-)anions,with largely different properties from I^(-)anions,mainly anchor on the film surface.Consequently,virtually all the defects at the surface,buried interface and grain boundaries of CsPbI_(3)perovskite films are effectively healed,leading to significantly improved film quality,enhanced phase stability,optimized energy level alignment and promoted carrier transport.With these films,the fabricated CsPbI_(3)PSCs based on carbon electrode(C-PSCs)achieve an efficiency of18.27%,which is among the highest-reported values for inorganic C-PSCs,and stability of 500 h at 85℃with 65%efficiency maintenance.展开更多
In recent years, a growing number of math contents are available on the Web. When conventional search engines deal with mathematical expressions, the two-dimen- sion-al structure of mathematical expressions is lost, w...In recent years, a growing number of math contents are available on the Web. When conventional search engines deal with mathematical expressions, the two-dimen- sion-al structure of mathematical expressions is lost, which results in a low performance of math retrieval. While the retrieval technology specifically designed for mathematical expressions is not mature currently. Aiming at these problems, an improved mathematical expression indexing and matching method was proposed through employing full text index method to deal with the two-dimensional structure of mathematical expressions. Firstly, through the fully consideration of LaTeX formulae’ characteristics, a feature representation method of mathematical expressions and a clustering method of feature keywords were put forward. Then, an improved inter-relevant successive trees index model was applied to the construction of the mathematical expression index, in which the cluster algorithm of mathematical expression features was employed to solve the problem of the quantity growth of the trees in processing large amount of formulae. Finally, the matching algorithms of mathematical expressions were given which provide four query modes called exact matching, compatible matching, sub-expression matching and fuzzy matching. In browser/server mode, 110027 formulae were used as experimental samples. The index file size was 29.02 Mb. The average time of retrieval was 1.092 seconds. The experimental result shows the effectiveness of the method.展开更多
基金supported by the National Natural Science Foundation of China(21875013,U2001217)the Beijing Natural Science Foundation(2182031)Shenzhen Basic Research(JCYJ20220818101018038)。
文摘Defects formed at the surface,buried interface and grain boundaries(GB)of CsPbI_(3)perovskite films considerably limit photovoltaic performance.Such defects could be passivated effectively by the most prevalent post modification strategy without compromising the photoelectric properties of perovskite films,but it is still a great challenge to make this strategy comprehensive to different defects spatially distributed throughout the films.Herein,a spatially selective defect management(SSDM)strategy is developed to roundly passivate various defects at different locations within the perovskite film by a facile one-step treatment procedure using a piperazine-1,4-diium tetrafluoroborate(PZD(BF_(4))_(2))solution.The small-size PZD^(2+)cations could penetrate into the film interior and even make it all the way to the buried interface of CsPbI_(3)perovskite films,while the BF_(4)^(-)anions,with largely different properties from I^(-)anions,mainly anchor on the film surface.Consequently,virtually all the defects at the surface,buried interface and grain boundaries of CsPbI_(3)perovskite films are effectively healed,leading to significantly improved film quality,enhanced phase stability,optimized energy level alignment and promoted carrier transport.With these films,the fabricated CsPbI_(3)PSCs based on carbon electrode(C-PSCs)achieve an efficiency of18.27%,which is among the highest-reported values for inorganic C-PSCs,and stability of 500 h at 85℃with 65%efficiency maintenance.
文摘In recent years, a growing number of math contents are available on the Web. When conventional search engines deal with mathematical expressions, the two-dimen- sion-al structure of mathematical expressions is lost, which results in a low performance of math retrieval. While the retrieval technology specifically designed for mathematical expressions is not mature currently. Aiming at these problems, an improved mathematical expression indexing and matching method was proposed through employing full text index method to deal with the two-dimensional structure of mathematical expressions. Firstly, through the fully consideration of LaTeX formulae’ characteristics, a feature representation method of mathematical expressions and a clustering method of feature keywords were put forward. Then, an improved inter-relevant successive trees index model was applied to the construction of the mathematical expression index, in which the cluster algorithm of mathematical expression features was employed to solve the problem of the quantity growth of the trees in processing large amount of formulae. Finally, the matching algorithms of mathematical expressions were given which provide four query modes called exact matching, compatible matching, sub-expression matching and fuzzy matching. In browser/server mode, 110027 formulae were used as experimental samples. The index file size was 29.02 Mb. The average time of retrieval was 1.092 seconds. The experimental result shows the effectiveness of the method.
