Mn-based rechargeable aqueous zinc-ion batteries(ZIBs)are highly promising because of their high operating voltages,attractive energy densities,and eco-friendliness.However,the electrochemical performances of Mn-based...Mn-based rechargeable aqueous zinc-ion batteries(ZIBs)are highly promising because of their high operating voltages,attractive energy densities,and eco-friendliness.However,the electrochemical performances of Mn-based cathodes usually suffer from their serious structure transformation upon charge/discharge cycling.Herein,we report a layered sodium-ion/crystal water co-intercalated Birnessite cathode with the formula of Na0.55Mn2O4·0.57H2O(NMOH)for high-performance aqueous ZIBs.A displacement/intercalation electrochemical mechanism was confirmed in the Mn-based cathode for the first time.Na+and crystal water enlarge the interlayer distance to enhance the insertion of Zn^2+,and some sodium ions are replaced with Zn^2+ in the first cycle to further stabilize the layered structure for subsequent reversible Zn^2+/H^+ insertion/extraction,resulting in exceptional specific capacities and satisfactory structural stabilities.Additionally,a pseudo-capacitance derived from the surface-adsorbed Na^+ also contributes to the electrochemical performances.The NMOH cathode not only delivers high reversible capacities of 389.8 and 87.1 mA h g^−1 at current densities of 200 and 1500 mA g^−1,respectively,but also maintains a good long-cycling performance of 201.6 mA h g^−1 at a high current density of 500 mA g^−1 after 400 cycles,which makes the NMOH cathode competitive for practical applications.展开更多
We demonstrate two ultra-stable laser systems at 1064 nm by independently stabilizing two 10-cm-long Fabry–Pérot cavities.The reference cavities are on a cubic spacer,which is rigidly mounted for both low sensit...We demonstrate two ultra-stable laser systems at 1064 nm by independently stabilizing two 10-cm-long Fabry–Pérot cavities.The reference cavities are on a cubic spacer,which is rigidly mounted for both low sensitivity to environmental vibration and ability for transportation.By comparing against an independent ultra-stable laser at 578 nm via an optical frequency comb,the 1064 nm lasers are measured to have frequency instabilities of 6×10^-16 at 1 s averaging time.展开更多
在Columbia超大陆的聚合和裂解过程中,扬子板块西南缘扮演着重要角色,前人认为Columbia超大陆在古元古代末期—中元古代中期裂解,对于其最初裂解在扬子板块西南缘的响应时间存在~1.85 Ga及~1.75 Ga两种认识(Liu Kang et al.,2019;刘军平...在Columbia超大陆的聚合和裂解过程中,扬子板块西南缘扮演着重要角色,前人认为Columbia超大陆在古元古代末期—中元古代中期裂解,对于其最初裂解在扬子板块西南缘的响应时间存在~1.85 Ga及~1.75 Ga两种认识(Liu Kang et al.,2019;刘军平等,2020)。扬子板块西南缘广泛分布的古元古代1.77~1.65 Ga板内镁铁质岩浆活动代表着超大陆裂解的高峰,而古元古代双峰式岩浆作用则相对罕见。展开更多
About 5.2×108 t/a of silts from the upper reach of the Yangtze River are transported through Yichang into the middle Yangtze River. The middle Yangtze itself and its tributaries yield ca. 0.8×108 t silts ann...About 5.2×108 t/a of silts from the upper reach of the Yangtze River are transported through Yichang into the middle Yangtze River. The middle Yangtze itself and its tributaries yield ca. 0.8×108 t silts annually. Of this total 6×108 t/a input of silts, ca. 1.2×108 t/a are deposited within the river artery and lakes, while ca 4.83×108 t/a are at first transported into the lower reach through Datong, and then either deposited along the river and the Yangtze Delta, or output into the sea. Along the middle Yangtze River silting generally exceeds scouring, but the spatial and temporal distributions of scour-and-fill, as well as its distribution in the river valley transections, are uneven. Along the Yichang-Chenglingji and Jiujiang-Datong Segments of the middle Yangtze, scouring exceeds or equals silting. Silting mainly occurs along the Luoshan-Wuhan-Huangshi Segments with Wuhan as the pivotal point, as well as in the Dongting and Poyang Lakes. Even in these silting-dominated areas, there are times and parts of segments that scouring prevails. As to the transections, generally the river channel of main stream is scouring-dominated, forming V-shaped sections to a depth of 2030 m or more, whereas the floodplains and bar islands are silting-dominated, forming wide and relatively high flats, which are often artificially transformed into protected embankments. Because the Jingjiang Levee separates the Jianghan Plain from Yangtze to the south, little has been deposited in that plain except a few sediments from the Han River—a tributary of the middle Yangtze. This factor plus the tectonic sag of that plain has made the altitude of plain surface several meters lower than that of the levee in most of the areas. Sil-tation along the Luoshan-Wuhan-Huangshi Segments has resulted in the elevation of flood level in this and upstream segments. River channel scouring plus floodplain silting have caused the transections of the middle Yangtze valley typically with deep channel and heightening flat bank, separated from the desce展开更多
Nuclear mass is one of the fundamental quantity of atomic nucleus.The total binding energy of a nucleus derived from the related mass values reflects all the interactions among the constituting nucleons.Masses of shor...Nuclear mass is one of the fundamental quantity of atomic nucleus.The total binding energy of a nucleus derived from the related mass values reflects all the interactions among the constituting nucleons.Masses of short-lived A=2Z+3 nuclei of 112Sn projectile fragments have been measured at the experimental cooler storage ring CSRe,employing the Isochronous mass spectrometry(IMS).The experiment was conducted at the Heavy Ion Research Facility in Lanzhou at the beginning of 2016.The primary beam of 112Sn35+was accumulated in the synchrotron CSRm and accelerated to 467.91 MeV/u.Secondary beam were produced by impinging the high intensity 112Sn35+beam onto a 10 mm beryllium target which was located at the entrance of the radioactive beam line RIBLL2.The projectile fragments of 112Sn emerged from the target were then transmitted,separated in flight through RIBLL2 and finally injected into CSRe.展开更多
基金Financial support from the National Natural Science Foundation of China (51972016, 51533001)the National Key Research and Development Program of China (2016YFC0801302)State Key Laboratory of Organic-Inorganic Composites (oic-201801002)
文摘Mn-based rechargeable aqueous zinc-ion batteries(ZIBs)are highly promising because of their high operating voltages,attractive energy densities,and eco-friendliness.However,the electrochemical performances of Mn-based cathodes usually suffer from their serious structure transformation upon charge/discharge cycling.Herein,we report a layered sodium-ion/crystal water co-intercalated Birnessite cathode with the formula of Na0.55Mn2O4·0.57H2O(NMOH)for high-performance aqueous ZIBs.A displacement/intercalation electrochemical mechanism was confirmed in the Mn-based cathode for the first time.Na+and crystal water enlarge the interlayer distance to enhance the insertion of Zn^2+,and some sodium ions are replaced with Zn^2+ in the first cycle to further stabilize the layered structure for subsequent reversible Zn^2+/H^+ insertion/extraction,resulting in exceptional specific capacities and satisfactory structural stabilities.Additionally,a pseudo-capacitance derived from the surface-adsorbed Na^+ also contributes to the electrochemical performances.The NMOH cathode not only delivers high reversible capacities of 389.8 and 87.1 mA h g^−1 at current densities of 200 and 1500 mA g^−1,respectively,but also maintains a good long-cycling performance of 201.6 mA h g^−1 at a high current density of 500 mA g^−1 after 400 cycles,which makes the NMOH cathode competitive for practical applications.
基金supported by the National Natural Science Foundation of China(Nos.11654004,11822402,91636214,and 11804094)the National Key R&D Program of China(No.2017YFA0304403)。
文摘We demonstrate two ultra-stable laser systems at 1064 nm by independently stabilizing two 10-cm-long Fabry–Pérot cavities.The reference cavities are on a cubic spacer,which is rigidly mounted for both low sensitivity to environmental vibration and ability for transportation.By comparing against an independent ultra-stable laser at 578 nm via an optical frequency comb,the 1064 nm lasers are measured to have frequency instabilities of 6×10^-16 at 1 s averaging time.
文摘在Columbia超大陆的聚合和裂解过程中,扬子板块西南缘扮演着重要角色,前人认为Columbia超大陆在古元古代末期—中元古代中期裂解,对于其最初裂解在扬子板块西南缘的响应时间存在~1.85 Ga及~1.75 Ga两种认识(Liu Kang et al.,2019;刘军平等,2020)。扬子板块西南缘广泛分布的古元古代1.77~1.65 Ga板内镁铁质岩浆活动代表着超大陆裂解的高峰,而古元古代双峰式岩浆作用则相对罕见。
文摘About 5.2×108 t/a of silts from the upper reach of the Yangtze River are transported through Yichang into the middle Yangtze River. The middle Yangtze itself and its tributaries yield ca. 0.8×108 t silts annually. Of this total 6×108 t/a input of silts, ca. 1.2×108 t/a are deposited within the river artery and lakes, while ca 4.83×108 t/a are at first transported into the lower reach through Datong, and then either deposited along the river and the Yangtze Delta, or output into the sea. Along the middle Yangtze River silting generally exceeds scouring, but the spatial and temporal distributions of scour-and-fill, as well as its distribution in the river valley transections, are uneven. Along the Yichang-Chenglingji and Jiujiang-Datong Segments of the middle Yangtze, scouring exceeds or equals silting. Silting mainly occurs along the Luoshan-Wuhan-Huangshi Segments with Wuhan as the pivotal point, as well as in the Dongting and Poyang Lakes. Even in these silting-dominated areas, there are times and parts of segments that scouring prevails. As to the transections, generally the river channel of main stream is scouring-dominated, forming V-shaped sections to a depth of 2030 m or more, whereas the floodplains and bar islands are silting-dominated, forming wide and relatively high flats, which are often artificially transformed into protected embankments. Because the Jingjiang Levee separates the Jianghan Plain from Yangtze to the south, little has been deposited in that plain except a few sediments from the Han River—a tributary of the middle Yangtze. This factor plus the tectonic sag of that plain has made the altitude of plain surface several meters lower than that of the levee in most of the areas. Sil-tation along the Luoshan-Wuhan-Huangshi Segments has resulted in the elevation of flood level in this and upstream segments. River channel scouring plus floodplain silting have caused the transections of the middle Yangtze valley typically with deep channel and heightening flat bank, separated from the desce
文摘Nuclear mass is one of the fundamental quantity of atomic nucleus.The total binding energy of a nucleus derived from the related mass values reflects all the interactions among the constituting nucleons.Masses of short-lived A=2Z+3 nuclei of 112Sn projectile fragments have been measured at the experimental cooler storage ring CSRe,employing the Isochronous mass spectrometry(IMS).The experiment was conducted at the Heavy Ion Research Facility in Lanzhou at the beginning of 2016.The primary beam of 112Sn35+was accumulated in the synchrotron CSRm and accelerated to 467.91 MeV/u.Secondary beam were produced by impinging the high intensity 112Sn35+beam onto a 10 mm beryllium target which was located at the entrance of the radioactive beam line RIBLL2.The projectile fragments of 112Sn emerged from the target were then transmitted,separated in flight through RIBLL2 and finally injected into CSRe.
