The electrochemical behavior of trifluoperazine at decanethiol self-assembledmonolayer (SAM) modified gold electrodes (i. e. C_(10) H_(21) SH/Au) has been studied,Trifluoperazine can effectively accumulate on C_(10) H...The electrochemical behavior of trifluoperazine at decanethiol self-assembledmonolayer (SAM) modified gold electrodes (i. e. C_(10) H_(21) SH/Au) has been studied,Trifluoperazine can effectively accumulate on C_(10) H_(21) SH/Au electrodes and generate asensitive anodic peak at about 0.63 V (vs. SCE) in 0.05 mol/L pH 9.4 Na_2 B_4 O_7 buffer solution.Under the selected conditions, the anodic peak current was linear to trifluoperazine concentrationin the range of 5.0 X 10^(-7)-3.O X 10^(-3) mol/Lwith correlation coefficient of 0.997, thedetection limit was 3.0 X 10^(-5) mol/L. This method was applied to the determination oftrifluoperazine in drug samples and the recovery was 97.3%-104.0% It was found that sodium dodecylsulfate (SDS) could make the anodic peak current increase. In the presence of SDS, the peak at about0.63 V turned into two peaks, resulting from the change of the electrochemical mechanism.展开更多
Blocking is a large-scale, mid-latitude atmospheric anticyclone that splits the westerly into two jets and has a profound effect on local and regional climates. This study examined the seasonal, interannual, and decad...Blocking is a large-scale, mid-latitude atmospheric anticyclone that splits the westerly into two jets and has a profound effect on local and regional climates. This study examined the seasonal, interannual, and decadal variability of the Atlantic and Pacific blocking anticyclones in the Northern Hemisphere based on the National Centers for Environmental Prediction (NCEP)/National Center for Atmospheric Research (NCAR) reanalysis data between 1958 and 1999. The preferred blocking region during these forty-two years was located over the Atlantic. Most blocking anticyclones over the Atlantic occurred in spring, while most of those over the Pacific occurred in winter. Similar two-to four-year and eleven-year oscillations were found for both the Atlantic and Pacific blocks by using wavelet analysis. The dominant mode for the Pacific blocks is decadal variation, while for the Atlantic blocks the predominant one is interannual variation with a period of about three years. The frequencies of the Pacific and Atlantic blocks varied almost in phase on interannual time scales except during the period of 1965-1977, and frequencies were out of phase on decadal time scale throughout the forty-two years.展开更多
On the basis of the analysis of the sea temperature data that are observed from the three automatic temperature line acquisition sysem mooring buoys deployed in the central South China Sea (SCS) during South China Sea...On the basis of the analysis of the sea temperature data that are observed from the three automatic temperature line acquisition sysem mooring buoys deployed in the central South China Sea (SCS) during South China Sea monsoon experiment, vertical features of bi- weekly and synoptic variability are discussed. There are five vertical modes, that is, subsurface temperature variability is in phase with, out of phase with, leads to, lags the surface temperature variability, and at depths within the subsurface layer the upper and lower tem- perature variations are out of phase. The formation of these vertical modes is related to the property of low-level atmospheric forcing and to the background in atmosphere and ocean. Wind stress curl is the main driving factor in forming Modes 1 and 3, and wind stress- es in forming Modes 2 and 4.展开更多
The (2+1)-dimensional nonlinear barotropic and quasi-geostrophic potential vorticity equation without forcing and dissipation on a beta-plane channel is investigated by using the classical Lie symmetry approach. Some ...The (2+1)-dimensional nonlinear barotropic and quasi-geostrophic potential vorticity equation without forcing and dissipation on a beta-plane channel is investigated by using the classical Lie symmetry approach. Some types of group-invariant wave solutions are expressed by means of the lower-dimensional similarity reduction equations. In addition to the known periodic Rossby wave solutions, some new types of exact solutions such as the ring solitary waves and the breaking soliton type of vorticity solutions with nonlinear and nonconstant shears are also obtained.展开更多
Bamboo harvesting residues are wastes by-products of bamboo industries that contain holocellulose for about 63.14%to 70.71%,which often be discarded,incinerated or buried.In this study,carboxymethyl cellulose was prep...Bamboo harvesting residues are wastes by-products of bamboo industries that contain holocellulose for about 63.14%to 70.71%,which often be discarded,incinerated or buried.In this study,carboxymethyl cellulose was prepared from bamboo harvesting residues(bamboo-branch and bamboo-tip)as raw materials.The chemical composition of bamboo harvesting residues,the viscosity and degree of substitution of carboxymethyl cellulose were determined.Carboxymethyl cellulose obtained was further characterized and compared by means of FTIR,SEM,XRD and TG.Results showed that under the optimized identical conditions,the viscosity and degree of substitution of carboxymethyl cellulose from bamboo-branch and bamboo-tip were 6.0 and 78.9 mPa·s,0.75 and 0.89,respectively.Carboxymethyl cellulose obtained from bamboo-tip displayed a lower crystallinity and a better thermal stability as compared to synthetic carboxymethyl cellulose obtained from bamboo-branch and bamboo-culm.展开更多
The isospin I = 0 and I = 1 kaon-nucleon S and P partial waves phase shifts have been studied in the chiral SU(3) quark model by solving a resonating group method equation. When the parameters of the chiral fields are...The isospin I = 0 and I = 1 kaon-nucleon S and P partial waves phase shifts have been studied in the chiral SU(3) quark model by solving a resonating group method equation. When the parameters of the chiral fields are taken in a reasonable region, the numerical results of S-wave are in good agreement with the experimental data, and the P-wave phase shifts can also be explained qualitatively by the calculation of only central force considered.展开更多
基金Supported by the National Natural Science Foundation of China (20173040)
文摘The electrochemical behavior of trifluoperazine at decanethiol self-assembledmonolayer (SAM) modified gold electrodes (i. e. C_(10) H_(21) SH/Au) has been studied,Trifluoperazine can effectively accumulate on C_(10) H_(21) SH/Au electrodes and generate asensitive anodic peak at about 0.63 V (vs. SCE) in 0.05 mol/L pH 9.4 Na_2 B_4 O_7 buffer solution.Under the selected conditions, the anodic peak current was linear to trifluoperazine concentrationin the range of 5.0 X 10^(-7)-3.O X 10^(-3) mol/Lwith correlation coefficient of 0.997, thedetection limit was 3.0 X 10^(-5) mol/L. This method was applied to the determination oftrifluoperazine in drug samples and the recovery was 97.3%-104.0% It was found that sodium dodecylsulfate (SDS) could make the anodic peak current increase. In the presence of SDS, the peak at about0.63 V turned into two peaks, resulting from the change of the electrochemical mechanism.
文摘Blocking is a large-scale, mid-latitude atmospheric anticyclone that splits the westerly into two jets and has a profound effect on local and regional climates. This study examined the seasonal, interannual, and decadal variability of the Atlantic and Pacific blocking anticyclones in the Northern Hemisphere based on the National Centers for Environmental Prediction (NCEP)/National Center for Atmospheric Research (NCAR) reanalysis data between 1958 and 1999. The preferred blocking region during these forty-two years was located over the Atlantic. Most blocking anticyclones over the Atlantic occurred in spring, while most of those over the Pacific occurred in winter. Similar two-to four-year and eleven-year oscillations were found for both the Atlantic and Pacific blocks by using wavelet analysis. The dominant mode for the Pacific blocks is decadal variation, while for the Atlantic blocks the predominant one is interannual variation with a period of about three years. The frequencies of the Pacific and Atlantic blocks varied almost in phase on interannual time scales except during the period of 1965-1977, and frequencies were out of phase on decadal time scale throughout the forty-two years.
基金supported by the National Natural Science Foundation of China under contract No.40305009.
文摘On the basis of the analysis of the sea temperature data that are observed from the three automatic temperature line acquisition sysem mooring buoys deployed in the central South China Sea (SCS) during South China Sea monsoon experiment, vertical features of bi- weekly and synoptic variability are discussed. There are five vertical modes, that is, subsurface temperature variability is in phase with, out of phase with, leads to, lags the surface temperature variability, and at depths within the subsurface layer the upper and lower tem- perature variations are out of phase. The formation of these vertical modes is related to the property of low-level atmospheric forcing and to the background in atmosphere and ocean. Wind stress curl is the main driving factor in forming Modes 1 and 3, and wind stress- es in forming Modes 2 and 4.
文摘The (2+1)-dimensional nonlinear barotropic and quasi-geostrophic potential vorticity equation without forcing and dissipation on a beta-plane channel is investigated by using the classical Lie symmetry approach. Some types of group-invariant wave solutions are expressed by means of the lower-dimensional similarity reduction equations. In addition to the known periodic Rossby wave solutions, some new types of exact solutions such as the ring solitary waves and the breaking soliton type of vorticity solutions with nonlinear and nonconstant shears are also obtained.
基金This work is supported by the National Forestry and Grassland Administration/Beijing Open Fund of Key Laboratory of Bamboo and Rattan Science and Technology(Grant No.ICBR-2020-10)University Scientific Research Project of Anhui Province(Grant No.KJ2020A0130).
文摘Bamboo harvesting residues are wastes by-products of bamboo industries that contain holocellulose for about 63.14%to 70.71%,which often be discarded,incinerated or buried.In this study,carboxymethyl cellulose was prepared from bamboo harvesting residues(bamboo-branch and bamboo-tip)as raw materials.The chemical composition of bamboo harvesting residues,the viscosity and degree of substitution of carboxymethyl cellulose were determined.Carboxymethyl cellulose obtained was further characterized and compared by means of FTIR,SEM,XRD and TG.Results showed that under the optimized identical conditions,the viscosity and degree of substitution of carboxymethyl cellulose from bamboo-branch and bamboo-tip were 6.0 and 78.9 mPa·s,0.75 and 0.89,respectively.Carboxymethyl cellulose obtained from bamboo-tip displayed a lower crystallinity and a better thermal stability as compared to synthetic carboxymethyl cellulose obtained from bamboo-branch and bamboo-culm.
文摘The isospin I = 0 and I = 1 kaon-nucleon S and P partial waves phase shifts have been studied in the chiral SU(3) quark model by solving a resonating group method equation. When the parameters of the chiral fields are taken in a reasonable region, the numerical results of S-wave are in good agreement with the experimental data, and the P-wave phase shifts can also be explained qualitatively by the calculation of only central force considered.
