The effects of Cd^(2+) ions on the microstructure,magnetic properties,and dielectric properties of Bi_(2)O_(3)-added MgFe_(2)O_(4) ferrites(Cd_(x)Mg_(1-x)Fe_(2)O_(4),x=0.00,0.15,0.30 and 0.45)are obtained by adopting ...The effects of Cd^(2+) ions on the microstructure,magnetic properties,and dielectric properties of Bi_(2)O_(3)-added MgFe_(2)O_(4) ferrites(Cd_(x)Mg_(1-x)Fe_(2)O_(4),x=0.00,0.15,0.30 and 0.45)are obtained by adopting the solid-state reaction method at a low temperature(910℃).The objective is to achieve matching impedances,low magnetic and dielectric losses(tanδμand tanδε,respectively),and a relatively large miniaturization factor to reduce antenna size.Experimental results indicate that the cations occupying the tetrahedral(A)and octahedral(B)ion sites are redistributed,resulting in an enhanced super-exchange interaction between the two sublattices.As a result,improved magnetization,including the increase in saturation magnetization(41.74 emu/g)and decrease in coercivity(63.75 Oe),is realized.The real part of permeability(μ')also increases with increasing concentration of Cd^(2+) ions.When x is 0.15,matching impedances with equivalent μ'and ε'values are obtained over a long frequency range(1–150MHz).Moreover,the formation of a dense microstructure guarantees that losses occur at low orders of magnitude(tanδμ≈10−2 and tanδε≈10−3).Accordingly,these properties afford wide application perspectives for the proposed compounds in the high-frequency region,i.e.,from high-frequency to very-high-frequency bands.展开更多
基金This work was supported by National Key Scientific Instrument and Equipment Development Project No.51827802by Major Science and Technology projects in Sichuan Province Nos.2019ZDZX0026 and 20ZDYF2818+1 种基金by the National Natural Science Foundation of China No.51872041by Foundation for University Teacher of Education of China No.ZYGX2019J011.
文摘The effects of Cd^(2+) ions on the microstructure,magnetic properties,and dielectric properties of Bi_(2)O_(3)-added MgFe_(2)O_(4) ferrites(Cd_(x)Mg_(1-x)Fe_(2)O_(4),x=0.00,0.15,0.30 and 0.45)are obtained by adopting the solid-state reaction method at a low temperature(910℃).The objective is to achieve matching impedances,low magnetic and dielectric losses(tanδμand tanδε,respectively),and a relatively large miniaturization factor to reduce antenna size.Experimental results indicate that the cations occupying the tetrahedral(A)and octahedral(B)ion sites are redistributed,resulting in an enhanced super-exchange interaction between the two sublattices.As a result,improved magnetization,including the increase in saturation magnetization(41.74 emu/g)and decrease in coercivity(63.75 Oe),is realized.The real part of permeability(μ')also increases with increasing concentration of Cd^(2+) ions.When x is 0.15,matching impedances with equivalent μ'and ε'values are obtained over a long frequency range(1–150MHz).Moreover,the formation of a dense microstructure guarantees that losses occur at low orders of magnitude(tanδμ≈10−2 and tanδε≈10−3).Accordingly,these properties afford wide application perspectives for the proposed compounds in the high-frequency region,i.e.,from high-frequency to very-high-frequency bands.
