It is not uncommon that backfill material used in underground mining being exposed to repetitive dynamic stresses induced by blasting operations or rockburst events. Understanding the strength and fracture evolution o...It is not uncommon that backfill material used in underground mining being exposed to repetitive dynamic stresses induced by blasting operations or rockburst events. Understanding the strength and fracture evolution of backfilled stopes is critical to maintain the long-term stope stability and ensure safe mining activities. This paper aims to study the damage evolution of the backfill material and its host rock behaviour under three-dimensional(3D) dynamic loading. Using a true-triaxial testing machine, multiple samples of backfill material enclosed by country rock were fabricated and tested under various dynamic loadings with different true-triaxial confining stress conditions. In addition, the nuclear magnetic resonance(NMR) measurement was conducted on the samples before and after exerting static and dynamic loading to obtain their porosity distribution changes. The experiment results suggested that with the increase of the dynamic loading, the porosity of the backfill sample goes through a two-stage process,which shows a slightly linear decrease and then followed by an exponential increase. The research findings can help understand the damage mechanism and fracture development of backfilled stopes and its host rock in deep underground mines, which are constantly subject to the combination of 3D static confining stress and dynamic loading.展开更多
Although the development of machine intelligence is far from simulating all the cognitive competence of our brains, still it is absolutely possible to peel the driving activity from people's cognitive activities and ...Although the development of machine intelligence is far from simulating all the cognitive competence of our brains, still it is absolutely possible to peel the driving activity from people's cognitive activities and then make the machine finish some low-level, complicated and lasting driving cognition by simulating our brains. The goal of driving is to replace drivers and free them from boring driving activities. Based on some studies on unmanned driving, this paper summarizes and analyzes the background, significance, research status and key technology of unmanned driving and the research group also introduces some research on brain cognition of driving and sensor placement of intelligent vehicles, which offers more meaningful reference to push the study of unmanned driving.展开更多
Returning rice straw and leguminous green manure alone or in combination to soil is effective in improving soil fertility in South China.Despite the popularity of this practice,our understanding o f the underlying pro...Returning rice straw and leguminous green manure alone or in combination to soil is effective in improving soil fertility in South China.Despite the popularity of this practice,our understanding o f the underlying processes for straw and manure combined application is relatively poor.In this study,rice straw(carbon(C)/nitrogen(N)ratio of 63),green manure(hairy vetch,C/N ratio of 14),and their mixtures(C/N ratio of 25 and 35)were added into a paddy soil,and their effects on soil N availability and C or N loss under waterlogged conditions were evaluated in a 100-d incubation experiment.All plant residue treatments significantly enhanced C〇2 and CH4 emissions,but decreased N2O emission.Dissolved organic C(DOC)and N(DON)and microbial biomass C in soil and water-soluble organic C and N and mineral N in the upper aqueous layer above soil were also enhanced by all the plant residue treatments except the rice straw treatment,and soil microbial biomass N and mineral N were lower in the rice straw treatment than in the other treatments.Changes in plant residue C/N ratio,DOC/DON ratio,and cellulose content significantly affected greenhouse gas emissions and active C and N concentrations in soil.Additionally,the treatment with green manure alone yielded the largest C and N losses,and incorporation of the plant residue mixture with a C/N ratio of 35 caused the largest net global warming potential(nGWP)among the amended treatments.In conclusion,the co-incorporation of rice straw and green manure can alleviate the limitation resulting from only applying rice straw(N immobilization)or the sole application of leguminous green manure(high C and N losses),and the residue mixture with a C/N ratio of 25 is a better option because of lower nGWP.展开更多
As one of the key technologies for the fifth generation(5G) wireless networks,device-to-device(D2D) communications allow user equipment(UE) in close proximity to communicate with each other directly.Forwarded by a rel...As one of the key technologies for the fifth generation(5G) wireless networks,device-to-device(D2D) communications allow user equipment(UE) in close proximity to communicate with each other directly.Forwarded by a relay,the relay-aided D2D(RA-D2D) communications can not only be applied to communications in much longer distance but also achieve a high quality of service(Qo S) .In this paper,we first propose a two-layer system model allowing RA-D2 D links to underlay traditional cellular uplinks.Then we maximize the energy efficiency of the RA-D2 D link while satisfying the minimum data-rate of the cellular link.The optimal transmit power at both D2 D transmitter and D2 D relay sides is obtained by transforming the nonlinear fractional programming into a nonlinear parameter programming.Simulation results show that our proposed power allocation method is more energy efficient than the existing works,and the proposed RA-D2 D scheme outperformed direct D2 D scheme when the distance between two D2 D users is longer.展开更多
The use of green manures contributes to sustainable soil and nutrient management in agriculture;however, the responses of soil microbial communities to different fertilization regimes at the regional scale are uncerta...The use of green manures contributes to sustainable soil and nutrient management in agriculture;however, the responses of soil microbial communities to different fertilization regimes at the regional scale are uncertain. A study was undertaken across multiple sites and years in Hunan, Jiangxi, Anhui, Henan,Hubei, and Fujian provinces of South China to investigate the effects of green manuring on the structure and function of soil bacterial communities in rice-green manure cropping systems. The study included four treatments: winter fallow with no chemical fertilizer as a control(NF), milk vetch as green manure without chemical fertilizer(GM), winter fallow and chemical fertilizer(CF), and a combination of chemical fertilizer and milk vetch(GMCF).Significant differences were found in the responses of soil microbial communities at different sites, with sampling sites explaining 72.33%(F = 36.59,P = 0.001) of the community composition variation. The bacterial communities in the soils from Anhui, Henan, and Hubei were broadly similar, while those from Hunan were distinctly different from other locations. The analysis of Weighted UniFrac distances showed that milk vetch changed soil microbial communities compared with winter fallow. Proteobacteria and Chloroflexi predominated in these paddy soils;however, the application of green manures increased the relative abundance of Actinobacteria. There was evidence showing that the functional microbes which play important roles in the cycling of soil carbon, nitrogen(N), and sulfur(S) changed after several years of milk vetch utilization(linear discriminant analysis score > 2). The abundance of methane-oxidizing bacteria and S-reducing bacteria increased, and microbes involved in N fixation, nitrification, and denitrification also increased in some provinces. We concluded that the application of milk vetch changed the bacterial community structure and affected the functional groups related to nutrient transformation in soils at a regional scale.展开更多
Three new complex borate compounds K7CaBi2B15O30, K7CaLa2B15 O30 and K7BaBi2B15O30 have been synthesized by the high-temperature solution method.K7CaLa2B15O30and K7CaBi2B15O30crystallize in the chiral trigonal space g...Three new complex borate compounds K7CaBi2B15O30, K7CaLa2B15 O30 and K7BaBi2B15O30 have been synthesized by the high-temperature solution method.K7CaLa2B15O30and K7CaBi2B15O30crystallize in the chiral trigonal space group R32, while K7BaBi2B15O30 crystallizes in the noncentrosymmetric orthorhombic polar space group Pca21. All of the title compounds have similar three-dimensional crystal structures, which are composed of isolated B5 O10 groups and LaO6 or BiO6 octahedra, and K^+, Ca^2+, and Ba^2+ cations fill into the cavities to keep charge balance. Based on our research, in the system of K7 MIIRE2 B15O30(MII= Ca, Sr,Ba, Zn, Cd, Pb, K/RE0.5;RE = Sc, Y, La, Gd, Lu, Bi),K7BaBi2B15O30 is unique and crystallizes in a different space group, which enriches the structural chemistry of borate.Detailed structural analyses indicate that the structural variation is due to the difference in size and coordination number of the alkaline-earth metal cations. Besides, UV-Vis-NIR spectroscopy analysis and the second-harmonic generation(SHG) measurement on the powder samples show that K7CaBi2B15O30 exhibits a UV cutoff edge(about 282 nm) and a moderate SHG response(about 0.6 × KDP). In addition,thermal analysis and infrared spectroscopy were also presented. To better understand the structure-property relationships of the title compounds, the first-principles calculations have been performed.展开更多
The isotope exchange method was employed to investigate the catalytic mechanism of ionic liquid in alkylation of benzenes with olefins.It is proposed that alkylation was induced by the Lewis acid AlCl3 which attracted...The isotope exchange method was employed to investigate the catalytic mechanism of ionic liquid in alkylation of benzenes with olefins.It is proposed that alkylation was induced by the Lewis acid AlCl3 which attracted π electrons of 1-dodecene to shift toward 1-carbon,thus forming a carbonium ion.The carbonium ion further reacted with benzenes to form a complex.Due to unstabilit of the complex,a deuterated ring proton was transferred into an electronegative 1-carbon of the side chain to substitute for the AlCl3,accordingly 2-phenyldodecane was generated.展开更多
The Space Advanced Technology demonstration satellite(SATech-01),a mission for low-cost space science and new technology experiments,organized by Chinese Academy of Sciences(CAS),was successfully launched into a Sun-s...The Space Advanced Technology demonstration satellite(SATech-01),a mission for low-cost space science and new technology experiments,organized by Chinese Academy of Sciences(CAS),was successfully launched into a Sun-synchronous orbit at an altitude of~500 km on July 27,2022,from the Jiuquan Satellite Launch Centre.Serving as an experimental platform for space science exploration and the demonstration of advanced common technologies in orbit,SATech-01 is equipped with 16 experimental payloads,including the solar upper transition region imager(SUTRI),the lobster eye imager for astronomy(LEIA),the high energy burst searcher(HEBS),and a High Precision Magnetic Field Measurement System based on a CPT Magnetometer(CPT).It also incorporates an imager with freeform optics,an integrated thermal imaging sensor,and a multi-functional integrated imager,etc.This paper provides an overview of SATech-01,including a technical description of the satellite and its scientific payloads,along with their on-orbit performance.展开更多
New coronavirus disease(COVID-19)has constituted a global pandemic and has spread to most countries and regions in the world.Through understanding the development trend of confirmed cases in a region,the government ca...New coronavirus disease(COVID-19)has constituted a global pandemic and has spread to most countries and regions in the world.Through understanding the development trend of confirmed cases in a region,the government can control the pandemic by using the corresponding policies.However,the common traditional mathematical differential equations and population prediction models have limitations for time series population prediction,and even have large estimation errors.To address this issue,we propose an improved method for predicting confirmed cases based on LSTM(Long-Short Term Memory)neural network.This work compares the deviation between the experimental results of the improved LSTM prediction model and the digital prediction models(such as Logistic and Hill equations)with the real data as reference.Furthermore,this work uses the goodness of fitting to evaluate the fitting effect of the improvement.Experiments show that the proposed approach has a smaller prediction deviation and a better fitting effect.Compared with the previous forecasting methods,the contributions of our proposed improvement methods are mainly in the following aspects:1)we have fully considered the spatiotemporal characteristics of the data,rather than single standardized data.2)the improved parameter settings and evaluation indicators are more accurate for fitting and forecasting.3)we consider the impact of the epidemic stage and conduct reasonable data processing for different stage.展开更多
Fertilizers are widely used to produce more food, inevitably altering the diversity and composition of soil organisms. The role of soil biodiversity in controlling multiple ecosystem services remains unclear, especial...Fertilizers are widely used to produce more food, inevitably altering the diversity and composition of soil organisms. The role of soil biodiversity in controlling multiple ecosystem services remains unclear, especially after decades of fertilization. Here, we assess the contribution of the soil functionalities of carbon(C), nitrogen(N), and phosphorus(P) cycling to crop production and explore how soil organisms control these functionalities in a 33-year field fertilization experiment. The long-term application of green manure or cow manure produced wheat yields equivalent to those obtained with chemical N, with the former providing higher soil functions and allowing the functionality of N cycling(especially soil N mineralization and biological N fixation) to control wheat production. The keystone phylotypes within the global network rather than the overall microbial community dominated the soil multifunctionality and functionality of C,N, and P cycling across the soil profile(0–100 cm). We further confirmed that these keystone phylotypes consisted of many metabolic pathways of nutrient cycling and essential microbes involved in organic C mineralization, N_(2)O release, and biological N fixation. The chemical N, green manure, and cow manure resulted in the highest abundances of amoB, nifH, and GH48 genes and Nitrosomonadaceae,Azospirillaceae, and Sphingomonadaceae within the keystone phylotypes, and these microbes were significantly and positively correlated with N_(2)O release, N fixation, and organic C mineralization, respectively. Moreover, our results demonstrated that organic fertilization increased the effects of the network size and keystone phylotypes on the subsoil functions by facilitating the migration of soil microorganisms across the soil profiles and green manure with the highest migration rates. This study highlights the importance of the functionality of N cycling in controlling crop production and keystone phylotypes in regulating soil functions, and provides selectable fertilization strategies展开更多
A non-cooperative game is proposed to perform the sub-carrier assignment and power allocation for the multi-cell orthogonal frequency division multiple access(OFDMA) system.The objective is to raise the spectral eff...A non-cooperative game is proposed to perform the sub-carrier assignment and power allocation for the multi-cell orthogonal frequency division multiple access(OFDMA) system.The objective is to raise the spectral efficiency of the system and prolong the life time of user nodes.This paper defines a game player as a cell formed by the unique base station and the served users.The utility function considered here measures the user's achieved utility per power.Each individual cell's goal is to maximize the total utility of its users.To search the Nash equilibrium(NE) of the game,an iterative and distributed algorithm is presented.Since the NE is inefficient,the pricing of user's transmission power is introduced to improve the NE in the Pareto sense.Simulation results show the proposed game outperforms the water-filling algorithm in terms of fairness and energy efficiency.Moreover,through employing a liner pricing function,the energy efficiency could be further improved.展开更多
Lactobacillus rhamnosus(Rh)and Lactobacillus reuteri(Re)are well-known probiotic species in inflammatory bowel disease(IBD)research.The variations between these species’efficacy against colitis,and their model of act...Lactobacillus rhamnosus(Rh)and Lactobacillus reuteri(Re)are well-known probiotic species in inflammatory bowel disease(IBD)research.The variations between these species’efficacy against colitis,and their model of action in this regard,are intriguing and enable treatment to be individually tailored to patients.In this study,four strains each of Rh and Re were isolated from fecal samples and their draft genomes were sequenced.The anti-colitis activities of both strains involved various aspects of intestinal immune,physical,chemical,and biological barrier function.Strikingly,the tested strains exhibited considerable interspecies and intraspecies specificity in colitis amelioration.Rh strains significantly outperformed Re strains in terms of short-chain fatty acid synthesis.Nevertheless,Re strains were more effective than Rh strains in inhibiting production of inflammatory factors;promoting production of intestinal mucus,antimicrobial peptides,and tight junction proteins;and supporting the stem cell compartment.This accounts for the anti-colitis outcomes of Re strains being superior to those of Rh strains.In addition,the effective Rh and Re strains were found to express high concentrations of specific carbohydrate metabolism-and prophage-related genes,respectively.Taken together,the results of this study could assist researchers in developing effective therapies for IBD.展开更多
Combustion performance of pulverized coal(PC)in blast furnace(BF)process is regarded as a criteria parameter to assess the prop-er injection dosage of PC.In this paper,effects of two kinds of additives,Fe_(2)O_(3) and...Combustion performance of pulverized coal(PC)in blast furnace(BF)process is regarded as a criteria parameter to assess the prop-er injection dosage of PC.In this paper,effects of two kinds of additives,Fe_(2)O_(3) and CaO,on PC combustion were studied using the thermo-gravimetric method.The results demonstrate that both the Fe_(2)O_(3) and CaO can promote combustion performance index of PC including igni-tion index(C_(i)),burnout index(D_(b)),as well as comprehensive combustibility index(S_(n)).The S_(n) increases from 1.37×10^(−6) to 2.16×10^(−6)%2·min^(−2)·℃^(−3) as the Fe_(2)O_(3) proportion increases from 0 to 5.0wt%.Additionally,the combustion kinetics of PC was clarified using the Coats-Redfern method.The results show that the activation energy(E)of PC combustion decreases after adding the above additives.For instance,the E decreases from 56.54 to 35.75 kJ/mol when the Fe_(2)O_(3) proportion increases from 0 to 5.0wt%,which supports the improved combustion per-formance.Moreover,it is uneconomic to utilize pure Fe_(2)O_(3) and CaO in production.Based on economy analysis,we selected the iron-bearing dust(IBD)which contains much Fe_(2)O_(3) and CaO component to investigate,and got the same effects.Therefore,the IBD is a potential option for catalytic PC combustion in BF process.展开更多
Papaya(Carica papaya L.)is regarded as an excellent model for genomic studies of tropical trees because of its short generation time and its small genome that has been sequenced.However,functional genomic studies in p...Papaya(Carica papaya L.)is regarded as an excellent model for genomic studies of tropical trees because of its short generation time and its small genome that has been sequenced.However,functional genomic studies in papaya depend on laborious genetic transformations because no rapid tools exist for this species.Here,we developed a highly efficient virus-induced gene silencing(VIGS)vector for use in papaya by modifying an artificially attenuated infectious clone of papaya leaf distortion mosaic virus(PLDMV;genus:Potyvirus),PLDMV-E,into a stable Nimble Cloning(NC)-based PLDMV vector,pPLDMV-NC,in Escherichia coli.The target fragments for gene silencing can easily be cloned into pPLDMV-NC without multiple digestion and ligation steps.Using this PLDMV VIGS system,we silenced and characterized five endogenous genes in papaya,including two common VIGS marker genes,namely,phytoene desaturase,Mg-chelatase H subunit,putative GIBBERELLIN(GA)-INSENSITIVE DWARF1A and 1B encoding GA receptors;and the cytochrome P450 gene CYP83B1,which encodes a key enzyme involved in benzylglucosinolate biosynthesis.The results demonstrate that our newly developed PLDMV VIGS vector is a rapid and convenient tool for functional genomic studies in papaya.展开更多
Purpose: The goal of this study is to explore whether deep learning based embed ded models can provide a better visualization solution for large citation networks. De sign/methodology/approach: Our team compared the v...Purpose: The goal of this study is to explore whether deep learning based embed ded models can provide a better visualization solution for large citation networks. De sign/methodology/approach: Our team compared the visualization approach borrowed from the deep learning community with the well-known bibliometric network visualization for large scale data. 47,294 highly cited papers were visualized by using three network embedding models plus the t-SNE dimensionality reduction technique. Besides, three base maps were created with the same dataset for evaluation purposes. All base maps used the classic Open Ord method with different edge cutting strategies and parameters. Findings: The network embedded maps with t-SNE preserve a very similar global structure to the full edges classic force-directed map, while the maps vary in local structure. Among them, the Node2Vec model has the best overall visualization performance, the local structure has been significantly improved and the maps' layout has very high stability.Research limitations: The computational and time costs of training are very high for network em bedded models to obtain high dimensional latent vector. Only one dimensionality reduction technique was tested. Practical implications: This paper demonstrates that the network embedding models are able to accurately reconstruct the large bibliometric network in the vector space. In the future, apart from network visualization, many classical vector-based machine learning algorithms can be applied to network representations for solving bibliomet ric analysis tasks. Originality/value: This paper provides the first systematic comparison of classical science mapping visualization with network embedding based visualization on a large scale dataset. We showed deep learning based network embedding model with t-SNE can provide a richer,more stable science map. We also designed a practical evaluation method to investigate and compare maps.展开更多
This study assessed the influence of exogenous ME in the mitigation of cold damage in pepper seedlings. Melatonin(ME) is a dynamic molecule that helps plants cope with stress in several ways. Cold stress(CS) is one of...This study assessed the influence of exogenous ME in the mitigation of cold damage in pepper seedlings. Melatonin(ME) is a dynamic molecule that helps plants cope with stress in several ways. Cold stress(CS) is one of the most important environmental factors that restrict plant growth and yield. Pepper(Capsicum annuum L.) is a valuable commercial crop, highly sensitive to CS. Thus, identifying an efficient strategy to mitigate cold damage is critical for long-term pepper production. For this purpose, the roots of pepper seedlings were pretreated with ME(5 μmol · L^(-1)) and exposed to CS for 7 d. The results indicated that CS suppressed pepper growth, hampered photosynthetic capacity, and damaged root architecture in pepper plants. In contrast, the production of reactive oxygen species(ROS), malondialdehyde(MDA), electrolyte leakage(EL), proline, and soluble sugars were enhanced in plants under CS. ME(5 μmol · L^(-1)) pretreatment reduced the negative effects of CS by recovering plant growth, root traits, gas exchange elements, and pigment molecules compared to CS control treatment. Furthermore, ME application efficiently reduced oxidative stress markers [hydrogen peroxide(H_(2)O_(2)), superoxide ion(O_(2)^(·-)), EL, and MDA] while increasing proline and soluble sugar content in pepper leaves. ME application combined with CS further increased antioxidant enzymes and related gene expression. Collectively, our results confirmed the mitigating potential of ME supplementation for CS by maintaining pepper seedling growth,improving the photosynthesis apparatus, regulating pigments, and osmolyte content.展开更多
There are two recognized classes of strategic-form symmetric games,both of which can be conveniently defined through the corresponding player symmetry groups.We investigate the basic properties of these groups and sev...There are two recognized classes of strategic-form symmetric games,both of which can be conveniently defined through the corresponding player symmetry groups.We investigate the basic properties of these groups and several related concepts.We generalize the notion of coveringness and adapt their results to characterize these player symmetry groups.We study the relationships between the coveringnesses of various symmetry groups.Our results demonstrate that these symmetry groups have rich mathematical structures that are of game theoretical and economic interests.展开更多
A circulating fluidized bed evaporator(including down-flow, horizontal, and up-flow beds) was constructed to study the effect of flow directions on multiphase flow boiling heat transfer. A range of experimental invest...A circulating fluidized bed evaporator(including down-flow, horizontal, and up-flow beds) was constructed to study the effect of flow directions on multiphase flow boiling heat transfer. A range of experimental investigations were carried out by varying amount of added particles(0-2%), circulation flow rate(2.15-5.16 m^3/h) and heat flux(8-16 kW/m^2). The comparison of heat transfer performance in different vertical heights of the horizontal bed was also discussed. Results reveal that the glass bead particle can enhance heat transfer compared with vapor-liquid two-phase flow for all beds. At a low heat flux(q = 8 kW/m), the heat-transfer-enhancing factor of the horizontal bed is obviously greater than those of the up-flow and down-flow beds. With the increase in the amount of added particles, the heat-transfer-enhancing factors of the up-flow and down-flow beds increase, whereas that of the horizontal bed initially increases and then decreases. However, at a high heat flux(q=16 kW/m), the heat-transfer-enhancing factors of the three beds show an increasing tendency with the increase in the amount of added particles and become closer than those at a low heat flux. For all beds, the heat-transfer-enhancing factor generally increases with the circulation flow rate but decreases with the increase in heat flux.展开更多
Utilizing vacuum-tuned-atmosphere induced dip coating method,we achieve the cross-dimensional macroscopic diverse self-assemblies by using one building block with one chemical functionality.Coordinated modulating the ...Utilizing vacuum-tuned-atmosphere induced dip coating method,we achieve the cross-dimensional macroscopic diverse self-assemblies by using one building block with one chemical functionality.Coordinated modulating the vacuum degree,colloid concentration and evaporation atmosphere,Au@Ag core/shell nanocubes (NCs) can controllably assemble into diverse multi-dimensional superstructures.Under 0.08 MPa,we obtained the two-dimensional (2D) stepped superstructures with continuously tunable step width.In addition,we generated a series of tailorable nanoscale-roughened 2D Au@Ag NCs superstructures at 0.04 MPa,which exhibited the label-free ultrasensitive SERS detection for the different mutants of IAPP8-37 proteins.Under 0.01 MPa,we obtained the cross-dimensional tailorable Au@Ag NCs assemblies from random to macroscale 2D and three-dimensional (3D) densest superstructures by adjusting the capping ligand-environmental molecule interactions.This is a flexible method to generate as-prepared Au@Ag core/shell NCs into well-defined macroscopic diverse superstructures and to promote the exploitation into biological applications.展开更多
To ascertain the effects of long-term conservation tillage and residue retention on soil organic carbon(SOC) content and aggregate distribution in a deep soil(>20-cm depth) in a dryland environment,this paper analy...To ascertain the effects of long-term conservation tillage and residue retention on soil organic carbon(SOC) content and aggregate distribution in a deep soil(>20-cm depth) in a dryland environment,this paper analyzed the SOC and aggregate distribution in soil, and the aggregate-associated organic carbon(OC) and SOC physical fractions. Conservation tillage(reduced tillage with residue incorporated(RT) and no-tillage with residue mulch(NT)) significantly increased SOC sequestration and soil aggregation in deep soil compared with conventional tillage with residue removal(CT). Compared with CT, RT significantly increased the proportion of small macroaggregates by 23%–81% in the 10–80 cm layer, and the OC content in small macroaggregates by 1%–58% in the 0–80 cm layer. RT significantly increased(by 24%–90%) the OC content in mineral-SOC within small macroaggregates in the 0–60 cm layer, while there was a 23%–80% increase in the 0–40 cm layer with NT. These results indicated that:(1) conservation tillage treatments are beneficial for soil aggregation and SOC sequestration in a deep soil in a dryland environment; and(2)the SOC in mineral-associated OC plays important roles in soil aggregation and SOC sequestration. In conclusion, RT with NT is recommended as an agricultural management tool in dryland soils because of its role in improving soil aggregation and SOC sequestration.展开更多
基金National Natural Science Foundation of China (Grant No.51804079)Fujian Natural Science Foundation (Grant No.2019J05039)
文摘It is not uncommon that backfill material used in underground mining being exposed to repetitive dynamic stresses induced by blasting operations or rockburst events. Understanding the strength and fracture evolution of backfilled stopes is critical to maintain the long-term stope stability and ensure safe mining activities. This paper aims to study the damage evolution of the backfill material and its host rock behaviour under three-dimensional(3D) dynamic loading. Using a true-triaxial testing machine, multiple samples of backfill material enclosed by country rock were fabricated and tested under various dynamic loadings with different true-triaxial confining stress conditions. In addition, the nuclear magnetic resonance(NMR) measurement was conducted on the samples before and after exerting static and dynamic loading to obtain their porosity distribution changes. The experiment results suggested that with the increase of the dynamic loading, the porosity of the backfill sample goes through a two-stage process,which shows a slightly linear decrease and then followed by an exponential increase. The research findings can help understand the damage mechanism and fracture development of backfilled stopes and its host rock in deep underground mines, which are constantly subject to the combination of 3D static confining stress and dynamic loading.
基金This work is supported by National Natural Science Foundation of China under Grant No. 61300006, No. 61305055, No. 61035004, No. 61273213, No. 61203366 and No. 90920305, and China National High-Tech Project (863) under grant No. 2015AA015401, and Chinese Academy of engineering consulting Project No. 2015-XY-42.
文摘Although the development of machine intelligence is far from simulating all the cognitive competence of our brains, still it is absolutely possible to peel the driving activity from people's cognitive activities and then make the machine finish some low-level, complicated and lasting driving cognition by simulating our brains. The goal of driving is to replace drivers and free them from boring driving activities. Based on some studies on unmanned driving, this paper summarizes and analyzes the background, significance, research status and key technology of unmanned driving and the research group also introduces some research on brain cognition of driving and sensor placement of intelligent vehicles, which offers more meaningful reference to push the study of unmanned driving.
基金This work was supported by the China Agriculture Research System-Green Manure,the Virtual Joint Nitrogen Centre(N-Circle)(No.B B/N 013484/1)the Science and Technology Innovation Project of Chinese Academy of Agricultural Sciences(2013-2017)the Chinese Outstanding Talents Program in Agricultural Science.
文摘Returning rice straw and leguminous green manure alone or in combination to soil is effective in improving soil fertility in South China.Despite the popularity of this practice,our understanding o f the underlying processes for straw and manure combined application is relatively poor.In this study,rice straw(carbon(C)/nitrogen(N)ratio of 63),green manure(hairy vetch,C/N ratio of 14),and their mixtures(C/N ratio of 25 and 35)were added into a paddy soil,and their effects on soil N availability and C or N loss under waterlogged conditions were evaluated in a 100-d incubation experiment.All plant residue treatments significantly enhanced C〇2 and CH4 emissions,but decreased N2O emission.Dissolved organic C(DOC)and N(DON)and microbial biomass C in soil and water-soluble organic C and N and mineral N in the upper aqueous layer above soil were also enhanced by all the plant residue treatments except the rice straw treatment,and soil microbial biomass N and mineral N were lower in the rice straw treatment than in the other treatments.Changes in plant residue C/N ratio,DOC/DON ratio,and cellulose content significantly affected greenhouse gas emissions and active C and N concentrations in soil.Additionally,the treatment with green manure alone yielded the largest C and N losses,and incorporation of the plant residue mixture with a C/N ratio of 35 caused the largest net global warming potential(nGWP)among the amended treatments.In conclusion,the co-incorporation of rice straw and green manure can alleviate the limitation resulting from only applying rice straw(N immobilization)or the sole application of leguminous green manure(high C and N losses),and the residue mixture with a C/N ratio of 25 is a better option because of lower nGWP.
基金supported by the ZTE Corp under Grant CON1412150018the Natural Science Foundation of China under Grant 61572389 and 61471361
文摘As one of the key technologies for the fifth generation(5G) wireless networks,device-to-device(D2D) communications allow user equipment(UE) in close proximity to communicate with each other directly.Forwarded by a relay,the relay-aided D2D(RA-D2D) communications can not only be applied to communications in much longer distance but also achieve a high quality of service(Qo S) .In this paper,we first propose a two-layer system model allowing RA-D2 D links to underlay traditional cellular uplinks.Then we maximize the energy efficiency of the RA-D2 D link while satisfying the minimum data-rate of the cellular link.The optimal transmit power at both D2 D transmitter and D2 D relay sides is obtained by transforming the nonlinear fractional programming into a nonlinear parameter programming.Simulation results show that our proposed power allocation method is more energy efficient than the existing works,and the proposed RA-D2 D scheme outperformed direct D2 D scheme when the distance between two D2 D users is longer.
基金supported by the earmarked fund for Modern Agro-industry Technology Research System-Green Manure,China (No.CARS-22)the National Natural Science Foundation of China (No.42007071)。
文摘The use of green manures contributes to sustainable soil and nutrient management in agriculture;however, the responses of soil microbial communities to different fertilization regimes at the regional scale are uncertain. A study was undertaken across multiple sites and years in Hunan, Jiangxi, Anhui, Henan,Hubei, and Fujian provinces of South China to investigate the effects of green manuring on the structure and function of soil bacterial communities in rice-green manure cropping systems. The study included four treatments: winter fallow with no chemical fertilizer as a control(NF), milk vetch as green manure without chemical fertilizer(GM), winter fallow and chemical fertilizer(CF), and a combination of chemical fertilizer and milk vetch(GMCF).Significant differences were found in the responses of soil microbial communities at different sites, with sampling sites explaining 72.33%(F = 36.59,P = 0.001) of the community composition variation. The bacterial communities in the soils from Anhui, Henan, and Hubei were broadly similar, while those from Hunan were distinctly different from other locations. The analysis of Weighted UniFrac distances showed that milk vetch changed soil microbial communities compared with winter fallow. Proteobacteria and Chloroflexi predominated in these paddy soils;however, the application of green manures increased the relative abundance of Actinobacteria. There was evidence showing that the functional microbes which play important roles in the cycling of soil carbon, nitrogen(N), and sulfur(S) changed after several years of milk vetch utilization(linear discriminant analysis score > 2). The abundance of methane-oxidizing bacteria and S-reducing bacteria increased, and microbes involved in N fixation, nitrification, and denitrification also increased in some provinces. We concluded that the application of milk vetch changed the bacterial community structure and affected the functional groups related to nutrient transformation in soils at a regional scale.
基金supported by the West Light Foundation of the CAS(2016-YJRC-2 and 2015 XBQN-B-11)the National Natural Science Foundation of China(51602341 and 91622107)+2 种基金the Natural Science Foundation of Xinjiang(2016D01B061)Tianshan Innovation Team Program(2018D14001)Key research project of Frontier Science of CAS(QYZDB-SSW-JSC049)
文摘Three new complex borate compounds K7CaBi2B15O30, K7CaLa2B15 O30 and K7BaBi2B15O30 have been synthesized by the high-temperature solution method.K7CaLa2B15O30and K7CaBi2B15O30crystallize in the chiral trigonal space group R32, while K7BaBi2B15O30 crystallizes in the noncentrosymmetric orthorhombic polar space group Pca21. All of the title compounds have similar three-dimensional crystal structures, which are composed of isolated B5 O10 groups and LaO6 or BiO6 octahedra, and K^+, Ca^2+, and Ba^2+ cations fill into the cavities to keep charge balance. Based on our research, in the system of K7 MIIRE2 B15O30(MII= Ca, Sr,Ba, Zn, Cd, Pb, K/RE0.5;RE = Sc, Y, La, Gd, Lu, Bi),K7BaBi2B15O30 is unique and crystallizes in a different space group, which enriches the structural chemistry of borate.Detailed structural analyses indicate that the structural variation is due to the difference in size and coordination number of the alkaline-earth metal cations. Besides, UV-Vis-NIR spectroscopy analysis and the second-harmonic generation(SHG) measurement on the powder samples show that K7CaBi2B15O30 exhibits a UV cutoff edge(about 282 nm) and a moderate SHG response(about 0.6 × KDP). In addition,thermal analysis and infrared spectroscopy were also presented. To better understand the structure-property relationships of the title compounds, the first-principles calculations have been performed.
基金supported by the National Natural Science Foundation of China(20676150)
文摘The isotope exchange method was employed to investigate the catalytic mechanism of ionic liquid in alkylation of benzenes with olefins.It is proposed that alkylation was induced by the Lewis acid AlCl3 which attracted π electrons of 1-dodecene to shift toward 1-carbon,thus forming a carbonium ion.The carbonium ion further reacted with benzenes to form a complex.Due to unstabilit of the complex,a deuterated ring proton was transferred into an electronegative 1-carbon of the side chain to substitute for the AlCl3,accordingly 2-phenyldodecane was generated.
基金supported by the Strategic Priority Program on Space Science,the Chinese Academy of Sciences。
文摘The Space Advanced Technology demonstration satellite(SATech-01),a mission for low-cost space science and new technology experiments,organized by Chinese Academy of Sciences(CAS),was successfully launched into a Sun-synchronous orbit at an altitude of~500 km on July 27,2022,from the Jiuquan Satellite Launch Centre.Serving as an experimental platform for space science exploration and the demonstration of advanced common technologies in orbit,SATech-01 is equipped with 16 experimental payloads,including the solar upper transition region imager(SUTRI),the lobster eye imager for astronomy(LEIA),the high energy burst searcher(HEBS),and a High Precision Magnetic Field Measurement System based on a CPT Magnetometer(CPT).It also incorporates an imager with freeform optics,an integrated thermal imaging sensor,and a multi-functional integrated imager,etc.This paper provides an overview of SATech-01,including a technical description of the satellite and its scientific payloads,along with their on-orbit performance.
基金This work was supported by the Hainan Provincial Natural Science Foundation of China[2018CXTD333,617048]National Natural Science Foundation of China[61762033,61702539]+3 种基金Hainan University Doctor Start Fund Project[kyqd1328]Hainan University Youth Fund Project[qnjj1444]Ministry of Education Humanities and Social Sciences Research Program Fund Project[19YJA710010]the Opening Project of Shanghai Trusted Industrial Control Platform.
文摘New coronavirus disease(COVID-19)has constituted a global pandemic and has spread to most countries and regions in the world.Through understanding the development trend of confirmed cases in a region,the government can control the pandemic by using the corresponding policies.However,the common traditional mathematical differential equations and population prediction models have limitations for time series population prediction,and even have large estimation errors.To address this issue,we propose an improved method for predicting confirmed cases based on LSTM(Long-Short Term Memory)neural network.This work compares the deviation between the experimental results of the improved LSTM prediction model and the digital prediction models(such as Logistic and Hill equations)with the real data as reference.Furthermore,this work uses the goodness of fitting to evaluate the fitting effect of the improvement.Experiments show that the proposed approach has a smaller prediction deviation and a better fitting effect.Compared with the previous forecasting methods,the contributions of our proposed improvement methods are mainly in the following aspects:1)we have fully considered the spatiotemporal characteristics of the data,rather than single standardized data.2)the improved parameter settings and evaluation indicators are more accurate for fitting and forecasting.3)we consider the impact of the epidemic stage and conduct reasonable data processing for different stage.
基金supported by the National Key Research and Development Program of China(2021YFD1700200)the earmarked fund for CARS-Green manure(CARS-22)the Agricultural Science and Technology Innovation Program of CAAS。
文摘Fertilizers are widely used to produce more food, inevitably altering the diversity and composition of soil organisms. The role of soil biodiversity in controlling multiple ecosystem services remains unclear, especially after decades of fertilization. Here, we assess the contribution of the soil functionalities of carbon(C), nitrogen(N), and phosphorus(P) cycling to crop production and explore how soil organisms control these functionalities in a 33-year field fertilization experiment. The long-term application of green manure or cow manure produced wheat yields equivalent to those obtained with chemical N, with the former providing higher soil functions and allowing the functionality of N cycling(especially soil N mineralization and biological N fixation) to control wheat production. The keystone phylotypes within the global network rather than the overall microbial community dominated the soil multifunctionality and functionality of C,N, and P cycling across the soil profile(0–100 cm). We further confirmed that these keystone phylotypes consisted of many metabolic pathways of nutrient cycling and essential microbes involved in organic C mineralization, N_(2)O release, and biological N fixation. The chemical N, green manure, and cow manure resulted in the highest abundances of amoB, nifH, and GH48 genes and Nitrosomonadaceae,Azospirillaceae, and Sphingomonadaceae within the keystone phylotypes, and these microbes were significantly and positively correlated with N_(2)O release, N fixation, and organic C mineralization, respectively. Moreover, our results demonstrated that organic fertilization increased the effects of the network size and keystone phylotypes on the subsoil functions by facilitating the migration of soil microorganisms across the soil profiles and green manure with the highest migration rates. This study highlights the importance of the functionality of N cycling in controlling crop production and keystone phylotypes in regulating soil functions, and provides selectable fertilization strategies
基金supported by the National Natural Science Foundation of China(60972059)the Fundamental Research Funds for the Central Universities of China(2010QNA27)+2 种基金China Postdoctoral Science Foundation(20100481185)the Ph.D.Programs Foundation of Ministry of Education of China(20090095120013)the Talent Introduction Program and Young Teacher Sailing Program of China University of Mining and Technology
文摘A non-cooperative game is proposed to perform the sub-carrier assignment and power allocation for the multi-cell orthogonal frequency division multiple access(OFDMA) system.The objective is to raise the spectral efficiency of the system and prolong the life time of user nodes.This paper defines a game player as a cell formed by the unique base station and the served users.The utility function considered here measures the user's achieved utility per power.Each individual cell's goal is to maximize the total utility of its users.To search the Nash equilibrium(NE) of the game,an iterative and distributed algorithm is presented.Since the NE is inefficient,the pricing of user's transmission power is introduced to improve the NE in the Pareto sense.Simulation results show the proposed game outperforms the water-filling algorithm in terms of fairness and energy efficiency.Moreover,through employing a liner pricing function,the energy efficiency could be further improved.
基金supported by the National Natural Science Foundation of China(32021005,31820103010)the Fundamental Research Funds for the Central Universities(JUSRP22006,JUSRP51501)the Program of Collaborative Innovation Centre of Food Safety and Quality Control in Jiangsu Province,Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX22_2391).
文摘Lactobacillus rhamnosus(Rh)and Lactobacillus reuteri(Re)are well-known probiotic species in inflammatory bowel disease(IBD)research.The variations between these species’efficacy against colitis,and their model of action in this regard,are intriguing and enable treatment to be individually tailored to patients.In this study,four strains each of Rh and Re were isolated from fecal samples and their draft genomes were sequenced.The anti-colitis activities of both strains involved various aspects of intestinal immune,physical,chemical,and biological barrier function.Strikingly,the tested strains exhibited considerable interspecies and intraspecies specificity in colitis amelioration.Rh strains significantly outperformed Re strains in terms of short-chain fatty acid synthesis.Nevertheless,Re strains were more effective than Rh strains in inhibiting production of inflammatory factors;promoting production of intestinal mucus,antimicrobial peptides,and tight junction proteins;and supporting the stem cell compartment.This accounts for the anti-colitis outcomes of Re strains being superior to those of Rh strains.In addition,the effective Rh and Re strains were found to express high concentrations of specific carbohydrate metabolism-and prophage-related genes,respectively.Taken together,the results of this study could assist researchers in developing effective therapies for IBD.
基金supported by the National Natural Science Foundation of China(Nos.52074086,51974073,52074072,52074074)the Fundamental Research Funds for the Central Universities,China(No.N2225039)the Liaoning Provincial Natural Science Foundation of China(No.2019-MS-132)。
文摘Combustion performance of pulverized coal(PC)in blast furnace(BF)process is regarded as a criteria parameter to assess the prop-er injection dosage of PC.In this paper,effects of two kinds of additives,Fe_(2)O_(3) and CaO,on PC combustion were studied using the thermo-gravimetric method.The results demonstrate that both the Fe_(2)O_(3) and CaO can promote combustion performance index of PC including igni-tion index(C_(i)),burnout index(D_(b)),as well as comprehensive combustibility index(S_(n)).The S_(n) increases from 1.37×10^(−6) to 2.16×10^(−6)%2·min^(−2)·℃^(−3) as the Fe_(2)O_(3) proportion increases from 0 to 5.0wt%.Additionally,the combustion kinetics of PC was clarified using the Coats-Redfern method.The results show that the activation energy(E)of PC combustion decreases after adding the above additives.For instance,the E decreases from 56.54 to 35.75 kJ/mol when the Fe_(2)O_(3) proportion increases from 0 to 5.0wt%,which supports the improved combustion per-formance.Moreover,it is uneconomic to utilize pure Fe_(2)O_(3) and CaO in production.Based on economy analysis,we selected the iron-bearing dust(IBD)which contains much Fe_(2)O_(3) and CaO component to investigate,and got the same effects.Therefore,the IBD is a potential option for catalytic PC combustion in BF process.
基金This work was supported by the Hainan Provincial Natural Science Foundation of China(2019RC298 and 2018CXTD343)the National Natural Science Foundation of China(32072390)the Central Public Interest Scientific Institution Basal Research Fund for Chinese Academy of Tropical Agricultural Sciences(grant no.19CXTD-33)。
文摘Papaya(Carica papaya L.)is regarded as an excellent model for genomic studies of tropical trees because of its short generation time and its small genome that has been sequenced.However,functional genomic studies in papaya depend on laborious genetic transformations because no rapid tools exist for this species.Here,we developed a highly efficient virus-induced gene silencing(VIGS)vector for use in papaya by modifying an artificially attenuated infectious clone of papaya leaf distortion mosaic virus(PLDMV;genus:Potyvirus),PLDMV-E,into a stable Nimble Cloning(NC)-based PLDMV vector,pPLDMV-NC,in Escherichia coli.The target fragments for gene silencing can easily be cloned into pPLDMV-NC without multiple digestion and ligation steps.Using this PLDMV VIGS system,we silenced and characterized five endogenous genes in papaya,including two common VIGS marker genes,namely,phytoene desaturase,Mg-chelatase H subunit,putative GIBBERELLIN(GA)-INSENSITIVE DWARF1A and 1B encoding GA receptors;and the cytochrome P450 gene CYP83B1,which encodes a key enzyme involved in benzylglucosinolate biosynthesis.The results demonstrate that our newly developed PLDMV VIGS vector is a rapid and convenient tool for functional genomic studies in papaya.
基金funded by the strategic research project of the Development Planning Bureau of the Chinese Academy of Sciences under Grant No.GHJ-ZLZX-2019-42the Youth Fund Project of Institutes of Science and Development, Chinese Academy of Sciences under Grant name “Research on Key Methods in Comparison of Scientific Funding Layout”。
文摘Purpose: The goal of this study is to explore whether deep learning based embed ded models can provide a better visualization solution for large citation networks. De sign/methodology/approach: Our team compared the visualization approach borrowed from the deep learning community with the well-known bibliometric network visualization for large scale data. 47,294 highly cited papers were visualized by using three network embedding models plus the t-SNE dimensionality reduction technique. Besides, three base maps were created with the same dataset for evaluation purposes. All base maps used the classic Open Ord method with different edge cutting strategies and parameters. Findings: The network embedded maps with t-SNE preserve a very similar global structure to the full edges classic force-directed map, while the maps vary in local structure. Among them, the Node2Vec model has the best overall visualization performance, the local structure has been significantly improved and the maps' layout has very high stability.Research limitations: The computational and time costs of training are very high for network em bedded models to obtain high dimensional latent vector. Only one dimensionality reduction technique was tested. Practical implications: This paper demonstrates that the network embedding models are able to accurately reconstruct the large bibliometric network in the vector space. In the future, apart from network visualization, many classical vector-based machine learning algorithms can be applied to network representations for solving bibliomet ric analysis tasks. Originality/value: This paper provides the first systematic comparison of classical science mapping visualization with network embedding based visualization on a large scale dataset. We showed deep learning based network embedding model with t-SNE can provide a richer,more stable science map. We also designed a practical evaluation method to investigate and compare maps.
基金supported by the Major Science and Technology Plan of Hainan Province (Grant No.ZDKJ2021010),ChinaNational Key Research and Development Program,(Grant No.2018YFD1000800) Chinathe National Natural Science Foundation (Grant No.31660091),China。
文摘This study assessed the influence of exogenous ME in the mitigation of cold damage in pepper seedlings. Melatonin(ME) is a dynamic molecule that helps plants cope with stress in several ways. Cold stress(CS) is one of the most important environmental factors that restrict plant growth and yield. Pepper(Capsicum annuum L.) is a valuable commercial crop, highly sensitive to CS. Thus, identifying an efficient strategy to mitigate cold damage is critical for long-term pepper production. For this purpose, the roots of pepper seedlings were pretreated with ME(5 μmol · L^(-1)) and exposed to CS for 7 d. The results indicated that CS suppressed pepper growth, hampered photosynthetic capacity, and damaged root architecture in pepper plants. In contrast, the production of reactive oxygen species(ROS), malondialdehyde(MDA), electrolyte leakage(EL), proline, and soluble sugars were enhanced in plants under CS. ME(5 μmol · L^(-1)) pretreatment reduced the negative effects of CS by recovering plant growth, root traits, gas exchange elements, and pigment molecules compared to CS control treatment. Furthermore, ME application efficiently reduced oxidative stress markers [hydrogen peroxide(H_(2)O_(2)), superoxide ion(O_(2)^(·-)), EL, and MDA] while increasing proline and soluble sugar content in pepper leaves. ME application combined with CS further increased antioxidant enzymes and related gene expression. Collectively, our results confirmed the mitigating potential of ME supplementation for CS by maintaining pepper seedling growth,improving the photosynthesis apparatus, regulating pigments, and osmolyte content.
基金supported by National Natural Science Foundation of China(72192804)and National Key Research Program(2018AAA0101000)+1 种基金supported by Natural Natural Science Foundation of China(72271016)Beijing Natural Science Foundation(Z220001)。
文摘There are two recognized classes of strategic-form symmetric games,both of which can be conveniently defined through the corresponding player symmetry groups.We investigate the basic properties of these groups and several related concepts.We generalize the notion of coveringness and adapt their results to characterize these player symmetry groups.We study the relationships between the coveringnesses of various symmetry groups.Our results demonstrate that these symmetry groups have rich mathematical structures that are of game theoretical and economic interests.
基金supported by Tianjin Municipal Science and Technology Commission, China (No. 2009ZCKFGX01900)
文摘A circulating fluidized bed evaporator(including down-flow, horizontal, and up-flow beds) was constructed to study the effect of flow directions on multiphase flow boiling heat transfer. A range of experimental investigations were carried out by varying amount of added particles(0-2%), circulation flow rate(2.15-5.16 m^3/h) and heat flux(8-16 kW/m^2). The comparison of heat transfer performance in different vertical heights of the horizontal bed was also discussed. Results reveal that the glass bead particle can enhance heat transfer compared with vapor-liquid two-phase flow for all beds. At a low heat flux(q = 8 kW/m), the heat-transfer-enhancing factor of the horizontal bed is obviously greater than those of the up-flow and down-flow beds. With the increase in the amount of added particles, the heat-transfer-enhancing factors of the up-flow and down-flow beds increase, whereas that of the horizontal bed initially increases and then decreases. However, at a high heat flux(q=16 kW/m), the heat-transfer-enhancing factors of the three beds show an increasing tendency with the increase in the amount of added particles and become closer than those at a low heat flux. For all beds, the heat-transfer-enhancing factor generally increases with the circulation flow rate but decreases with the increase in heat flux.
基金the National Natural Science Foundation of China (Nos.51872030,51631001,21643003,51702016,and 51501010)Fundamental Research Funds for the Central Universities and Beijing Institute of Technology Research Fund Program for Young Scholars and ZDKT18-01 fund from State Key Laboratory of Explosion Science and Technology (Beijing Institute of Technology).We acknowledge critical and quantity of testing work supported by Beijing Zhongkebaice Technology Service Co., Ltd.
文摘Utilizing vacuum-tuned-atmosphere induced dip coating method,we achieve the cross-dimensional macroscopic diverse self-assemblies by using one building block with one chemical functionality.Coordinated modulating the vacuum degree,colloid concentration and evaporation atmosphere,Au@Ag core/shell nanocubes (NCs) can controllably assemble into diverse multi-dimensional superstructures.Under 0.08 MPa,we obtained the two-dimensional (2D) stepped superstructures with continuously tunable step width.In addition,we generated a series of tailorable nanoscale-roughened 2D Au@Ag NCs superstructures at 0.04 MPa,which exhibited the label-free ultrasensitive SERS detection for the different mutants of IAPP8-37 proteins.Under 0.01 MPa,we obtained the cross-dimensional tailorable Au@Ag NCs assemblies from random to macroscale 2D and three-dimensional (3D) densest superstructures by adjusting the capping ligand-environmental molecule interactions.This is a flexible method to generate as-prepared Au@Ag core/shell NCs into well-defined macroscopic diverse superstructures and to promote the exploitation into biological applications.
基金supported jointly by the National Key Research and Development Program of China (2018YFD0200408, 2016YFD0300804)the Science and Technology Project (2015BAD22B03)the Basic Scientific Research Business Expenses of the Chinese Academy of Agricultural Sciences (1610132018024)
文摘To ascertain the effects of long-term conservation tillage and residue retention on soil organic carbon(SOC) content and aggregate distribution in a deep soil(>20-cm depth) in a dryland environment,this paper analyzed the SOC and aggregate distribution in soil, and the aggregate-associated organic carbon(OC) and SOC physical fractions. Conservation tillage(reduced tillage with residue incorporated(RT) and no-tillage with residue mulch(NT)) significantly increased SOC sequestration and soil aggregation in deep soil compared with conventional tillage with residue removal(CT). Compared with CT, RT significantly increased the proportion of small macroaggregates by 23%–81% in the 10–80 cm layer, and the OC content in small macroaggregates by 1%–58% in the 0–80 cm layer. RT significantly increased(by 24%–90%) the OC content in mineral-SOC within small macroaggregates in the 0–60 cm layer, while there was a 23%–80% increase in the 0–40 cm layer with NT. These results indicated that:(1) conservation tillage treatments are beneficial for soil aggregation and SOC sequestration in a deep soil in a dryland environment; and(2)the SOC in mineral-associated OC plays important roles in soil aggregation and SOC sequestration. In conclusion, RT with NT is recommended as an agricultural management tool in dryland soils because of its role in improving soil aggregation and SOC sequestration.