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具有电子转移路径的金属化氮化碳选择性再生NADH和光酶偶联CO_(2)还原
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作者 张鹏业 董文锦 +7 位作者 张媛媛 赵立楠 苑华磊 王传军 王文硕 王含笑 张洪禹 刘健 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2023年第11期188-198,共11页
将CO_(2)转化为燃料和化学品被认为是缓解能源危机的一种有效策略.受自然光合作用的启发,光酶偶联结合了光催化和酶催化的优点,在绿色生物制造中具有较好的应用前景.铑(Rh)络合物是选择性再生还原型烟酰胺腺嘌呤二核苷酸(M-NADH)的关键... 将CO_(2)转化为燃料和化学品被认为是缓解能源危机的一种有效策略.受自然光合作用的启发,光酶偶联结合了光催化和酶催化的优点,在绿色生物制造中具有较好的应用前景.铑(Rh)络合物是选择性再生还原型烟酰胺腺嘌呤二核苷酸(M-NADH)的关键介体,其固定化可以提高体系的可持续性,并有效缩短电子传递路径,因而受到广泛关注.本文制备了联吡啶功能化的金属化氮化碳(PCNRhbpy_(4)),用于光酶偶联催化CO_(2)还原.首先以双氰胺为前驱体,通过两步退火法制备氮化碳(PCN),再与5,5’-二氨基-2,2’-联吡啶(DABP)进一步热缩合,然后锚定[Cp*RhCl2]2获得PCNRhbpy4,并通过透射电镜、扫描电镜、粉末X射线衍射、紫外可见光吸收光谱、瞬态表面光电压和荧光发射光谱等进行表征.结果表明,合成的PCNRhbpy4材料具有掺杂石墨烯结构,且通过残余的末端联吡啶结构均匀地固定了Rh络合物.以PCNRhbpy4作为光催化剂实现了1,4-NADH的100%选择性再生,并在2.0 min内实现了80%的NADH再生.进一步耦合固定在疏水膜上的甲酸脱氢酶,可以有效地将CO_(2)还原为甲酸盐,48 h内甲酸盐浓度达到7 mmol L^(-1).此外,光催化剂的循环实验结果表明,PCNRhbpy4具有较高的稳定性.反应机理研究结果表明,光生电子经N-掺杂石墨烯传递到Rh活性位点,并结合溶液中的质子,随后氢负离子通过环滑移机制传递到NAD+,高选择性再生1,4-NADH.综上,本文为Rh的固定化开辟了一条新路径,实现了光酶催化CO_(2)还原,为光酶催化在绿色生物制造的实际应用提供参考. 展开更多
关键词 仿生金属化 NADH再生 光酶偶联催化 CO_(2)还原 电荷转移
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A Case of Multi-Stage Fracturing Horizontal Well Used in BZ Oilfield in Bohai Bay Low-Permeability Oilfield Development
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作者 Xiujuan Zhao chuanjun wang +2 位作者 Quanlin wang Jie Tan Wei Yang 《Journal of Geoscience and Environment Protection》 2020年第7期147-154,共8页
BZ oilfield in Bohai Bay of China was a typical offshore low permeability oilfield, which was restricted by many factors such as environment and economy. In this paper, the development characteristics of BZ oilfield w... BZ oilfield in Bohai Bay of China was a typical offshore low permeability oilfield, which was restricted by many factors such as environment and economy. In this paper, the development characteristics of BZ oilfield were summarized in depth, and the new development mode of offshore low-permeability oilfield was explored from reservoir prediction, well spacing and fracturing technology. Taking BZ oilfield as an example, a set of technical system for the effective development of offshore low permeability oilfield had been formed through research, which mainly includes reservoir prediction and evaluation of offshore middle and deep low permeability oilfield, optimization of horizontal well pattern, multi-stage fracturing design of horizontal well and other technologies. The results show that improving the resolution of seismic data, strengthening the analysis of seismic reflection characteristics and carrying out the comprehensive study of seismic geology were the keys to solve the reservoir prediction of offshore low-permeability oil fields. Multi-stage fracturing horizontal well pattern is the main pattern of offshore low-permeability oilfield development. The parameters of multi-stage fracturing horizontal well together affect the development effect. Selecting the optimal fractured horizontal well pattern can greatly improve the development effect. The successful combination and application of new technology system was the foundation and core of conquering offshore low-permeability oil fields. On the basis of understanding the geological characteristics of oil reservoirs, it is an effective means of developing offshore low-permeability oil fields by selecting reasonable production methods, well types and well patterns. Using efficient perforation and fracturing technology to successfully control fracture parameters and form optimal injection and production well pattern was the key to improve low permeability offshore oil fields. 展开更多
关键词 Low Permeability Offshore Oil Field Multi-Stage Fracturing Horizontal Well Pattern
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基于区间优化模型的低碳经济发展碳排放量控制研究 被引量:1
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作者 郑传均 王子豪 《生态经济》 北大核心 2017年第7期19-24,共6页
全球性气候变暖成为世界性的环境问题,作为平衡碳排放与经济发展之间的最佳发展模式,低碳经济发展引起越来越多人的关注,世界各国也由传统经济转向低碳经济发展。在分析低碳经济理论的基础上,从控制碳排放总量的角度,利用区间规划方法... 全球性气候变暖成为世界性的环境问题,作为平衡碳排放与经济发展之间的最佳发展模式,低碳经济发展引起越来越多人的关注,世界各国也由传统经济转向低碳经济发展。在分析低碳经济理论的基础上,从控制碳排放总量的角度,利用区间规划方法构建优化模型,对我国低碳经济发展碳排放量进行实证研究,并基于研究结果对控制碳排放量,促进低碳经济发展提出合理建议。 展开更多
关键词 区间优化模型 低碳经济 碳排放量控制
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