The adsorption behavior of eosin yellow (EY) from aqueous solution onto γ-Al<sub>2</sub>O<sub>3</sub> nanoparticles in batch technique was studied. γ-Al<sub>2</sub>O<sub>3&l...The adsorption behavior of eosin yellow (EY) from aqueous solution onto γ-Al<sub>2</sub>O<sub>3</sub> nanoparticles in batch technique was studied. γ-Al<sub>2</sub>O<sub>3</sub> NPs was prepared and characterized by SEM, TEM, XRD and FTIR analysis. The effect of pH, dosage of adsorbent, contact time, temperature, and the initial concentration of dye was investigated. The maximum amount of dye removal found about 99.36% at pH4, the adsorption dose 1g/L, with the initial dye concentration of 100 mg/L, and the temperature of 25°C, with contact time 120 min. The adsorption behavior of the eosin yellow dye is applicable to Langmuir isotherm model, with the maximum sorption capacity of 47.78 mg/g of γ-Al<sub>2</sub>O<sub>3</sub>. The kinetic data also described by the pseudo-second-order model with a correlation coefficient (0.9999), and the mechanism of the process showed a multi-linear steps and the intra-particle diffusion was not only rate controlling step. The adsorption process was endothermic with positive enthalpy of 121.8 kJ/mol, and showed spontaneous process with a mean free energy -5.19 kJ/mol, and increase randomness, 369.77 J/mol. k, at the adsorbent solution interface. The adsorption process was chemisorption in nature The activation energy estimated from Arrhenius and modified Arrhenius is 40.9 kJ/mol, 106.37 kJ/mol respectively. The sticking probability of EY onto Al<sub>2</sub>O<sub>3</sub> NPs very high estimated from the value of S* < 1, (4.82E-19).展开更多
Great efforts had been made to use indirect non-destructive tests in the geotechnical evaluation of rocks, especially sandstones, employing different empirical equations. However, most of these equations have been der...Great efforts had been made to use indirect non-destructive tests in the geotechnical evaluation of rocks, especially sandstones, employing different empirical equations. However, most of these equations have been derived from hard and compacted sandstones data</span><span style="font-family:"">;</span><span style="font-family:"">therefore, the focus of this research is on weak and weakly compacted sandstones, aiming firstly to obtain empirical equations for estimating their characteristics, secondly to demonstrate and visualize the correlations between the studied variables, and finally to cluster <span>the studied samples based on their characteristics. To attain these aims</span></span><span style="font-family:"">,</span><span style="font-family:""> twenty</span><span style="font-family:""> oriented block samples were collected from Nubia sandstone, central Eastern Desert, Golden Triangle area, Egypt. These samples were prepared and tested according to standard test methods, including uniaxial compressive strength (UCS), Brazilian tensile strength (BTS), Schmidt rebound number (SRN), porosity (<i><i>n</i></i>), bulk density (<span>ρ</span>), and ultrasonic P-wave velocity (UPV). The loss on ignition (LOI) was also employed as a physicochemical test for classifying the studied samples and indicating pores filling materials. The results revealed that these sandstones are characterized mainly by high <i><i>n</i></i>, low <span>ρ</span>, and low UPV values and these give an indication of weakly compacted and weakly cemented sandstone with shallow burial diagenetic conditions. Based on UCS and elastic modulus values, these sandstones are mainly classified as very low strength and highly yielding rocks. The results of regression analysis show satisfactory correlations between physical and mechanical characteristics, indicating the suitability of obtained empirical equations to deduce these properties. Principal component analysis revealed that the LOI, BTS, SRN, and USC have a positive correlation to each other an展开更多
文摘The adsorption behavior of eosin yellow (EY) from aqueous solution onto γ-Al<sub>2</sub>O<sub>3</sub> nanoparticles in batch technique was studied. γ-Al<sub>2</sub>O<sub>3</sub> NPs was prepared and characterized by SEM, TEM, XRD and FTIR analysis. The effect of pH, dosage of adsorbent, contact time, temperature, and the initial concentration of dye was investigated. The maximum amount of dye removal found about 99.36% at pH4, the adsorption dose 1g/L, with the initial dye concentration of 100 mg/L, and the temperature of 25°C, with contact time 120 min. The adsorption behavior of the eosin yellow dye is applicable to Langmuir isotherm model, with the maximum sorption capacity of 47.78 mg/g of γ-Al<sub>2</sub>O<sub>3</sub>. The kinetic data also described by the pseudo-second-order model with a correlation coefficient (0.9999), and the mechanism of the process showed a multi-linear steps and the intra-particle diffusion was not only rate controlling step. The adsorption process was endothermic with positive enthalpy of 121.8 kJ/mol, and showed spontaneous process with a mean free energy -5.19 kJ/mol, and increase randomness, 369.77 J/mol. k, at the adsorbent solution interface. The adsorption process was chemisorption in nature The activation energy estimated from Arrhenius and modified Arrhenius is 40.9 kJ/mol, 106.37 kJ/mol respectively. The sticking probability of EY onto Al<sub>2</sub>O<sub>3</sub> NPs very high estimated from the value of S* < 1, (4.82E-19).
文摘Great efforts had been made to use indirect non-destructive tests in the geotechnical evaluation of rocks, especially sandstones, employing different empirical equations. However, most of these equations have been derived from hard and compacted sandstones data</span><span style="font-family:"">;</span><span style="font-family:"">therefore, the focus of this research is on weak and weakly compacted sandstones, aiming firstly to obtain empirical equations for estimating their characteristics, secondly to demonstrate and visualize the correlations between the studied variables, and finally to cluster <span>the studied samples based on their characteristics. To attain these aims</span></span><span style="font-family:"">,</span><span style="font-family:""> twenty</span><span style="font-family:""> oriented block samples were collected from Nubia sandstone, central Eastern Desert, Golden Triangle area, Egypt. These samples were prepared and tested according to standard test methods, including uniaxial compressive strength (UCS), Brazilian tensile strength (BTS), Schmidt rebound number (SRN), porosity (<i><i>n</i></i>), bulk density (<span>ρ</span>), and ultrasonic P-wave velocity (UPV). The loss on ignition (LOI) was also employed as a physicochemical test for classifying the studied samples and indicating pores filling materials. The results revealed that these sandstones are characterized mainly by high <i><i>n</i></i>, low <span>ρ</span>, and low UPV values and these give an indication of weakly compacted and weakly cemented sandstone with shallow burial diagenetic conditions. Based on UCS and elastic modulus values, these sandstones are mainly classified as very low strength and highly yielding rocks. The results of regression analysis show satisfactory correlations between physical and mechanical characteristics, indicating the suitability of obtained empirical equations to deduce these properties. Principal component analysis revealed that the LOI, BTS, SRN, and USC have a positive correlation to each other an
