A simple,efficient and environmentally benign protocol for the synthesis of 4H-chromene derivatives was developed using bio-compatible,neutral,and recoverable mesoporous silica nanoparticles as a catalyst.The 4H-chrom...A simple,efficient and environmentally benign protocol for the synthesis of 4H-chromene derivatives was developed using bio-compatible,neutral,and recoverable mesoporous silica nanoparticles as a catalyst.The 4H-chromene derivatives were obtained in excellent yields by three component reaction of an aldehyde or isatin,malononitrile,and cyclic 1,3-diketones in ethanol at 60℃.展开更多
Copper-catalyzed synthesis of N-aryl anthranilic acid derivatives using effective amination of 2-chloro and 2-bromobenzoic acid under microwave irradiation is reported. Some of the advantages of this method are high c...Copper-catalyzed synthesis of N-aryl anthranilic acid derivatives using effective amination of 2-chloro and 2-bromobenzoic acid under microwave irradiation is reported. Some of the advantages of this method are high chemoselectivity, short reaction times, ease of work up procedure and elimination of the need for acid protection. 2009 Published by Elsevier B.V. on behalf of Chinese Chemical Society.展开更多
Pyridinium bromochromate has been found to be a highly efficient and selective reagent for the α-monobromination of 1,3- diketones and β-keto-esters in the absence of base, Lewis acid, or other catalyst. The product...Pyridinium bromochromate has been found to be a highly efficient and selective reagent for the α-monobromination of 1,3- diketones and β-keto-esters in the absence of base, Lewis acid, or other catalyst. The products were formed in high to excellent yields under mild reaction conditions and in short reaction times.展开更多
A new practical method for the synthesis of unsymmetrical ureas was achieved by reaction of phenylurea with primary and secondary amines under neutral and mild condition in very good yields. The reaction took place in...A new practical method for the synthesis of unsymmetrical ureas was achieved by reaction of phenylurea with primary and secondary amines under neutral and mild condition in very good yields. The reaction took place in refluxing dioxane and does not require any catalyst or additives.展开更多
A one pot three‐component coupling reaction of phenylacetylene, aldehyde, and amine derivatives in the presence of Cu(II) Salen complex as an efficient heterogeneous catalyst under solvent‐free conditions is reporte...A one pot three‐component coupling reaction of phenylacetylene, aldehyde, and amine derivatives in the presence of Cu(II) Salen complex as an efficient heterogeneous catalyst under solvent‐free conditions is reported. The catalyst displayed high activity and afforded the corresponding propargylamines in good to excellent yields. This method provides a wide range of substrate applicability. The catalyst was reused several times without significant loss of its catalytic activity.展开更多
Gas injection is the second largest enhanced oil recovery process, next only to the thermal method used in heavy oil fields. To increase the extent of the reservoir contacted by the injected gas, the gas is generally ...Gas injection is the second largest enhanced oil recovery process, next only to the thermal method used in heavy oil fields. To increase the extent of the reservoir contacted by the injected gas, the gas is generally injected intermittently with water. This mode of injection is called water-alternating-gas (WAG). This study deals with a new immiscible water alternating gas (IWAG) EOR technique, “hot IWAG” which includes combination of thermal, solvent and sweep techniques. In the proposed method CO2 will be superheated above the reservoir temperature and instead of normal temperature water, hot water will be used. Hot CO2 and hot water will be alternatively injected into the sand packs. A laboratory test was conducted on the fractured and conventional sand packs. Slugs of water and CO2 with a low and constant rate were injected into the sand packs alternatively; slug size was 0.05 PV. Recovery from each sand pack was monitored and after that hot water and hot CO2 were injected alternatively under the same conditions and increased oil recovery from each sand pack and breakthrough were measured. Experimental results showed that the injection of hot WAG could significantly recover residual oil after WAG injection in conventional and fractured sand packs.展开更多
基金the Research Council of Mazandaran University,Babolsar,Iran
文摘A simple,efficient and environmentally benign protocol for the synthesis of 4H-chromene derivatives was developed using bio-compatible,neutral,and recoverable mesoporous silica nanoparticles as a catalyst.The 4H-chromene derivatives were obtained in excellent yields by three component reaction of an aldehyde or isatin,malononitrile,and cyclic 1,3-diketones in ethanol at 60℃.
基金the financial support of this work by the Research Council of Mazandaran University.
文摘Copper-catalyzed synthesis of N-aryl anthranilic acid derivatives using effective amination of 2-chloro and 2-bromobenzoic acid under microwave irradiation is reported. Some of the advantages of this method are high chemoselectivity, short reaction times, ease of work up procedure and elimination of the need for acid protection. 2009 Published by Elsevier B.V. on behalf of Chinese Chemical Society.
基金support from the Research Council of Mazandaran University
文摘Pyridinium bromochromate has been found to be a highly efficient and selective reagent for the α-monobromination of 1,3- diketones and β-keto-esters in the absence of base, Lewis acid, or other catalyst. The products were formed in high to excellent yields under mild reaction conditions and in short reaction times.
基金Financial support of this work from the Research Council of the University of Mazandaran is gratefully acknowledged
文摘A new practical method for the synthesis of unsymmetrical ureas was achieved by reaction of phenylurea with primary and secondary amines under neutral and mild condition in very good yields. The reaction took place in refluxing dioxane and does not require any catalyst or additives.
文摘A one pot three‐component coupling reaction of phenylacetylene, aldehyde, and amine derivatives in the presence of Cu(II) Salen complex as an efficient heterogeneous catalyst under solvent‐free conditions is reported. The catalyst displayed high activity and afforded the corresponding propargylamines in good to excellent yields. This method provides a wide range of substrate applicability. The catalyst was reused several times without significant loss of its catalytic activity.
文摘Gas injection is the second largest enhanced oil recovery process, next only to the thermal method used in heavy oil fields. To increase the extent of the reservoir contacted by the injected gas, the gas is generally injected intermittently with water. This mode of injection is called water-alternating-gas (WAG). This study deals with a new immiscible water alternating gas (IWAG) EOR technique, “hot IWAG” which includes combination of thermal, solvent and sweep techniques. In the proposed method CO2 will be superheated above the reservoir temperature and instead of normal temperature water, hot water will be used. Hot CO2 and hot water will be alternatively injected into the sand packs. A laboratory test was conducted on the fractured and conventional sand packs. Slugs of water and CO2 with a low and constant rate were injected into the sand packs alternatively; slug size was 0.05 PV. Recovery from each sand pack was monitored and after that hot water and hot CO2 were injected alternatively under the same conditions and increased oil recovery from each sand pack and breakthrough were measured. Experimental results showed that the injection of hot WAG could significantly recover residual oil after WAG injection in conventional and fractured sand packs.
