The molar conductance of electrolytes LiPF 6-PC(propylene carbonate), LiPF 6·2DG(diglyme)-PC and LiPF 6·PMDETA(pentamethyldiethylenetriamine)-PC were calculated by using mean spherical approximation(MSA). Th...The molar conductance of electrolytes LiPF 6-PC(propylene carbonate), LiPF 6·2DG(diglyme)-PC and LiPF 6·PMDETA(pentamethyldiethylenetriamine)-PC were calculated by using mean spherical approximation(MSA). The range of concentration was from 0.001 mol·L -1 to 1 mol·L -1. The dissociation equilibrium of salts is taken into account. The mean relative deviations were 5.6%, 4.2% and 4.7%, respectively.展开更多
文摘The molar conductance of electrolytes LiPF 6-PC(propylene carbonate), LiPF 6·2DG(diglyme)-PC and LiPF 6·PMDETA(pentamethyldiethylenetriamine)-PC were calculated by using mean spherical approximation(MSA). The range of concentration was from 0.001 mol·L -1 to 1 mol·L -1. The dissociation equilibrium of salts is taken into account. The mean relative deviations were 5.6%, 4.2% and 4.7%, respectively.
