The title compound was obtained by the reaction of Rh4 (CO)12 with P(SC6H5)3. The crystal structure of the compound has been determined by X-ray diffraction. The crystal system is monoctric, space group P21/a, a=17.39...The title compound was obtained by the reaction of Rh4 (CO)12 with P(SC6H5)3. The crystal structure of the compound has been determined by X-ray diffraction. The crystal system is monoctric, space group P21/a, a=17.390(8), b=8.983(9),c=24.35(2)A, β =103.84(4); V=3693(5)A3, Z=8, DC=1.93g.cm-3. R=0.057, RW=0.064, The intramolecular Rh-Rh distances are 3.090 and 3.078A respectively.展开更多
文摘The title compound was obtained by the reaction of Rh4 (CO)12 with P(SC6H5)3. The crystal structure of the compound has been determined by X-ray diffraction. The crystal system is monoctric, space group P21/a, a=17.390(8), b=8.983(9),c=24.35(2)A, β =103.84(4); V=3693(5)A3, Z=8, DC=1.93g.cm-3. R=0.057, RW=0.064, The intramolecular Rh-Rh distances are 3.090 and 3.078A respectively.
