The dynamics of water within a nanopool of a reverse micelle is heavily affected by the amphiphilic interface.In this work,the terahertz(THz)spectra of cyclohexane/Igepal/water nonionic reverse micelle mixture are mea...The dynamics of water within a nanopool of a reverse micelle is heavily affected by the amphiphilic interface.In this work,the terahertz(THz)spectra of cyclohexane/Igepal/water nonionic reverse micelle mixture are measured by THz timedomain spectroscopy and analyzed with two Debye models and complex permittivity of background with volume ratios.Based on the fitted parameters of bulk and fast water,the molar concentration of all kinds of water molecules and hydration water molecule number per Igepal molecule are calculated.We find that slow hydration water has the highest proportion in water when the radius parameterω_(0)<10,while bulk water becomes the main component whenω_(0)≥10.The feature radius ratio of nonhydrated and hydrated water to total water nanopool is roughly obtained from 0.39 to 0.85 with increasingω_(0).展开更多
基金supported by the National Natural Science Foundation of China(No.62175185)。
文摘The dynamics of water within a nanopool of a reverse micelle is heavily affected by the amphiphilic interface.In this work,the terahertz(THz)spectra of cyclohexane/Igepal/water nonionic reverse micelle mixture are measured by THz timedomain spectroscopy and analyzed with two Debye models and complex permittivity of background with volume ratios.Based on the fitted parameters of bulk and fast water,the molar concentration of all kinds of water molecules and hydration water molecule number per Igepal molecule are calculated.We find that slow hydration water has the highest proportion in water when the radius parameterω_(0)<10,while bulk water becomes the main component whenω_(0)≥10.The feature radius ratio of nonhydrated and hydrated water to total water nanopool is roughly obtained from 0.39 to 0.85 with increasingω_(0).
