Naphthyl acetate was synthesized in yield of 96.8% using sodium bisulfate as catalyst. The optimum conditions were as follows: β naphthol 3 6 g, acetic anhydride 3 mL, sodium bisulfate 0 5 g , temperature 80 ℃, reac...Naphthyl acetate was synthesized in yield of 96.8% using sodium bisulfate as catalyst. The optimum conditions were as follows: β naphthol 3 6 g, acetic anhydride 3 mL, sodium bisulfate 0 5 g , temperature 80 ℃, reaction time 40 min . The method has advantages of cheapness and simplicity , and the catalyst can be easily regenerated.展开更多
A novel polyoxovanadate-based MOFs microsphere,[Ni(phen)V2O7]·H2O(phen=1,10-phenanthroline),constructed from 3-D discrete nano-sheets has been prepared and characterized by XRD,FT-IR,SEM and TEM.Electrochemical p...A novel polyoxovanadate-based MOFs microsphere,[Ni(phen)V2O7]·H2O(phen=1,10-phenanthroline),constructed from 3-D discrete nano-sheets has been prepared and characterized by XRD,FT-IR,SEM and TEM.Electrochemical properties as supercapacitor of the as-prepared sample,such as CV,EIS,GCD and the cycle life test have also been studied.The as-prepared MOF(V,Ni)showed a high specific capacitance of 178.09 F×g^(-1) at 1 A×g^(-1) as well as good cycling stability and coulombic efficiency.This work proved that the novel MOFs based on polyoxovanadate hybrid material may serve as a promising electrode material for high-performance supercapacitor.展开更多
In this study,S-doped g-C_(3)N_(4)nanoparticles were successfully prepared by one-step solid-state microwave synthesis.The detailed characterizations through XRD,FT-IR,SEM and XPS were studied.In addition,the electroc...In this study,S-doped g-C_(3)N_(4)nanoparticles were successfully prepared by one-step solid-state microwave synthesis.The detailed characterizations through XRD,FT-IR,SEM and XPS were studied.In addition,the electrochemical properties as supercapacitor of the sample were tested by cyclic voltammetry(CV),galvanostatic charge-discharge(GCD)and electrochemical impedance spectroscopy(EIS)techniques.The results showed a high specific capacitance of 691 F/g at current density of 4 A/g in 2 M KOH+0.15 M K3[Fe(CN)_(6)]electrolyte.This study shows that the microwave synthesis is a promising way to design carbon-based electrodes for supercapacitor.展开更多
The red long-lasting phosphorescent （LLP） of β-Zn3（POa）2：Mn2＋,pr3＋ material was prepared through combustion and conventional solid-state sintering methods. The influence of Pr3＋ ions on luminescence and LLP o...The red long-lasting phosphorescent （LLP） of β-Zn3（POa）2：Mn2＋,pr3＋ material was prepared through combustion and conventional solid-state sintering methods. The influence of Pr3＋ ions on luminescence and LLP of Mn2＋ in 13-Zn3（POa）2：Mn2＋,pr3＋ phosphor was systematically investigated. The phosphor presented a strong photoluminescence peak at 620 nm attributed to the 4T1g→ 6A1 g transition of Mn2＋ ions in octahedral coordination. Red LLP was observed in β-Zn3（PO4）2：Mn2＋,Pr3＋ phosphors with persistence time for more than 2 h. It was found that the long persistent phosphorescent performance of Mn2＋ such as brightness and duration was improved by the energy transfer from Pr3＋ to Mn2＋ when Pr3＋ ions as sensitizers were doped into matrix. The fact that the TL peak at low temperature was largely enhanced in Mn2＋, Pr3＋ codoped ^-Zn3（PO4）2 phosphor showed the significant increase of defect concentration with suitable depth. There existed two factors working together to be responsible for the enhancement of LLP performance in β-Zn3（PO4）2：Mn2＋,Pr3＋.展开更多
A microsphere discrete structure of CoNi_2S_4 was prepared through one-pot hydrothermal reaction and characterized by FTIR, XRD and SEM. The as-prepared CoNi_2S_4 served as a supercapacitor, showing a specific capacit...A microsphere discrete structure of CoNi_2S_4 was prepared through one-pot hydrothermal reaction and characterized by FTIR, XRD and SEM. The as-prepared CoNi_2S_4 served as a supercapacitor, showing a specific capacitance of 1129.5 F/g with over 99% coulombic efficiency at a current density of 4 A/g in 3 M KOH. And after 3000 cycles of charge and discharge tests, 92.3% of its initial capacitance can be still maintained. The results demonstrate that the material is promising as an electrode material for supercapacitors in energy storage.展开更多
文摘Naphthyl acetate was synthesized in yield of 96.8% using sodium bisulfate as catalyst. The optimum conditions were as follows: β naphthol 3 6 g, acetic anhydride 3 mL, sodium bisulfate 0 5 g , temperature 80 ℃, reaction time 40 min . The method has advantages of cheapness and simplicity , and the catalyst can be easily regenerated.
基金supported by the Natural Science Foundation of Fujian Province(No.2020J01803)Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry(FJKL_FBCM202004)the Fujian Provincial Key Laboratory of Ecotoxicological Effects and Control of New Pollutants(PY19001)。
文摘A novel polyoxovanadate-based MOFs microsphere,[Ni(phen)V2O7]·H2O(phen=1,10-phenanthroline),constructed from 3-D discrete nano-sheets has been prepared and characterized by XRD,FT-IR,SEM and TEM.Electrochemical properties as supercapacitor of the as-prepared sample,such as CV,EIS,GCD and the cycle life test have also been studied.The as-prepared MOF(V,Ni)showed a high specific capacitance of 178.09 F×g^(-1) at 1 A×g^(-1) as well as good cycling stability and coulombic efficiency.This work proved that the novel MOFs based on polyoxovanadate hybrid material may serve as a promising electrode material for high-performance supercapacitor.
基金the Natural Science Foundation of Fujian Province(No.2020J01803)Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry(FJKL_FBCM202004)the Fujian Provincial Key Laboratory of Ecotoxicological Effects and Control of New pollutants(PY19001)。
文摘In this study,S-doped g-C_(3)N_(4)nanoparticles were successfully prepared by one-step solid-state microwave synthesis.The detailed characterizations through XRD,FT-IR,SEM and XPS were studied.In addition,the electrochemical properties as supercapacitor of the sample were tested by cyclic voltammetry(CV),galvanostatic charge-discharge(GCD)and electrochemical impedance spectroscopy(EIS)techniques.The results showed a high specific capacitance of 691 F/g at current density of 4 A/g in 2 M KOH+0.15 M K3[Fe(CN)_(6)]electrolyte.This study shows that the microwave synthesis is a promising way to design carbon-based electrodes for supercapacitor.
基金Project supported by the National Natural Science Foundation of China(91222110)Key Project of Industry-University-Research of Science and Technology Department of Fujian Province(2010H6029,2012H6026)+1 种基金Key Project of Advanced Industry of Science and Technology Department of Fujian Province(2013H0053)the Training Program of Fujian Excellent Talents in University
文摘The red long-lasting phosphorescent （LLP） of β-Zn3（POa）2：Mn2＋,pr3＋ material was prepared through combustion and conventional solid-state sintering methods. The influence of Pr3＋ ions on luminescence and LLP of Mn2＋ in 13-Zn3（POa）2：Mn2＋,pr3＋ phosphor was systematically investigated. The phosphor presented a strong photoluminescence peak at 620 nm attributed to the 4T1g→ 6A1 g transition of Mn2＋ ions in octahedral coordination. Red LLP was observed in β-Zn3（PO4）2：Mn2＋,Pr3＋ phosphors with persistence time for more than 2 h. It was found that the long persistent phosphorescent performance of Mn2＋ such as brightness and duration was improved by the energy transfer from Pr3＋ to Mn2＋ when Pr3＋ ions as sensitizers were doped into matrix. The fact that the TL peak at low temperature was largely enhanced in Mn2＋, Pr3＋ codoped ^-Zn3（PO4）2 phosphor showed the significant increase of defect concentration with suitable depth. There existed two factors working together to be responsible for the enhancement of LLP performance in β-Zn3（PO4）2：Mn2＋,Pr3＋.
基金Supported by the Natural Science Foundation of Fujian Province(No.2017J01420)Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry(FJKL_FBCM201803)
文摘A microsphere discrete structure of CoNi_2S_4 was prepared through one-pot hydrothermal reaction and characterized by FTIR, XRD and SEM. The as-prepared CoNi_2S_4 served as a supercapacitor, showing a specific capacitance of 1129.5 F/g with over 99% coulombic efficiency at a current density of 4 A/g in 3 M KOH. And after 3000 cycles of charge and discharge tests, 92.3% of its initial capacitance can be still maintained. The results demonstrate that the material is promising as an electrode material for supercapacitors in energy storage.
