Three polymeric erbium(Ⅲ) complexes [Er(oba)(Hoba)(H 2O) 2]H 2O (A),[Er 2(oba) 3(H 2O) 4] (B), [Er 2(oba) 3(2,2′ bpy) 2] (C) (H 2oba=4,4′ oxybis(benzoic acid), 2,2′ bpy = 2,2′ bipyridine) were hydr...Three polymeric erbium(Ⅲ) complexes [Er(oba)(Hoba)(H 2O) 2]H 2O (A),[Er 2(oba) 3(H 2O) 4] (B), [Er 2(oba) 3(2,2′ bpy) 2] (C) (H 2oba=4,4′ oxybis(benzoic acid), 2,2′ bpy = 2,2′ bipyridine) were hydrothermally synthesized by altering the metal/carboxylate ratios or in the presence of an additional chelate 2,2′ bpy ligand, and characterized by single crystal X ray diffraction. The results show that different metal/carboxylate ratios can influence the polymeric structures and the presence of 2,2′ bpy ligand alters the topology of the framework from two dimensional to three dimensional.展开更多
Molecular qubits are promising as they can benefit from tailoring and versatile design of chemistry.It is essential to reduce the decoherence of molecular qubits caused by their interactions with the environment.Herei...Molecular qubits are promising as they can benefit from tailoring and versatile design of chemistry.It is essential to reduce the decoherence of molecular qubits caused by their interactions with the environment.Herein the dynamical decoupling(DD)technique is utilized to combat such decoherence.The coherence time for a transitionmetal complex(PPh_(4))_(2)[Cu(mnt)_(2)]is prolonged from 6.8μs to 1.4 ms.The ratio of the coherence time and the length ofπ/2 pulse,defined as the single qubit figure of merit(QM),reaches 1.4×10^(5),which is 40 times greater than what previously reported for this molecule.Our results show that molecular qubits,with milliseconds coherence time,are promising candidates for quantum information processing.展开更多
文摘Three polymeric erbium(Ⅲ) complexes [Er(oba)(Hoba)(H 2O) 2]H 2O (A),[Er 2(oba) 3(H 2O) 4] (B), [Er 2(oba) 3(2,2′ bpy) 2] (C) (H 2oba=4,4′ oxybis(benzoic acid), 2,2′ bpy = 2,2′ bipyridine) were hydrothermally synthesized by altering the metal/carboxylate ratios or in the presence of an additional chelate 2,2′ bpy ligand, and characterized by single crystal X ray diffraction. The results show that different metal/carboxylate ratios can influence the polymeric structures and the presence of 2,2′ bpy ligand alters the topology of the framework from two dimensional to three dimensional.
基金Supported by the National Key R&D Program of China(Grant Nos.2018YFA0306600 and 2016YFB0501603)the Chinese Academy of Sciences(Grant Nos.GJJSTD20170001,QYZDY-SSW-SLH004,and QYZDB-SSW-SLH005)+2 种基金Anhui Initiative in Quantum Information Technologies(Grant No.AHY050000)the Youth Innovation Promotion Association of Chinese Academy of Sciences for their supportthe support from Wuhan National High Magnetic Field Center(Grant No.2015KF06)。
文摘Molecular qubits are promising as they can benefit from tailoring and versatile design of chemistry.It is essential to reduce the decoherence of molecular qubits caused by their interactions with the environment.Herein the dynamical decoupling(DD)technique is utilized to combat such decoherence.The coherence time for a transitionmetal complex(PPh_(4))_(2)[Cu(mnt)_(2)]is prolonged from 6.8μs to 1.4 ms.The ratio of the coherence time and the length ofπ/2 pulse,defined as the single qubit figure of merit(QM),reaches 1.4×10^(5),which is 40 times greater than what previously reported for this molecule.Our results show that molecular qubits,with milliseconds coherence time,are promising candidates for quantum information processing.
