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脱硫渣吸附剂对Cu^(2+)的吸附动力学和热力学 被引量:18
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作者 郑跃国 +3 位作者 李燕峰 洪明珠 罗鹏 于岩 《硅酸盐学报》 EI CAS CSCD 北大核心 2013年第3期396-401,共6页
以钢铁冶炼厂干法烟气脱硫产生的脱硫渣为吸附主原料制备了除铜吸附材料。探讨了吸附剂样品对含铜废水中Cu2+吸附效果;用3种动力学经验方程和两种热力学模型对吸附过程进行了动力学和热力学表征。结果表明:Cu2+的最佳吸附条件是pH值为8... 以钢铁冶炼厂干法烟气脱硫产生的脱硫渣为吸附主原料制备了除铜吸附材料。探讨了吸附剂样品对含铜废水中Cu2+吸附效果;用3种动力学经验方程和两种热力学模型对吸附过程进行了动力学和热力学表征。结果表明:Cu2+的最佳吸附条件是pH值为8~9,吸附时间为1.5 h以内。热力学和动力学过程拟合结果表明,吸附的动力学过程更符合准二级动力学速率方程,而Freundlich型吸附等温线模型能较好地模拟吸附剂样品对废液中Cu2+吸附的热力学过程。热力学和动力学分析结果表明,脱硫渣吸附剂对Cu2+的吸附并不是单层吸附,同时存在物理和化学吸附过程。 展开更多
关键词 干法脱硫渣 铜吸附 动力学 热力学
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Study on the Structure and Characteristics of Recyclable Copper Removal Adsorbent
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作者 罗鹏 +4 位作者 郑跃国 陈霏云 游瑞荣 巫秋萍 于岩 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2013年第7期975-980,共6页
A recyclable copper removal adsorbent was developed from diatomite and alu- minum sludge composite materials. The. effects of different formulas on the adsorption of Cu2~ under different conditions were discussed. The... A recyclable copper removal adsorbent was developed from diatomite and alu- minum sludge composite materials. The. effects of different formulas on the adsorption of Cu2~ under different conditions were discussed. The properties and rnicrostructures of the samples were characterized. The results showed that the optimum pH value, contacting time and raw materials proportion for copper removal are 6, 90 min and 40:60 (sludge: diatomite), respectively, The copper removal capacity could reach 0.46 mg/g at the initial copper concentration of 5 mg/L. There was no change in the composition of crystal phase before and after copper removal, so physical adsorption was dominant during the adsorption process. 展开更多
关键词 recyelable copper removal adsorbent composite material
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