H10TTPR was prepared starting from terephthalaldehyde and characterized. Crystal structure of H10TTPR and an intermediate compound 11 were determined by X-ray diffraction analysis. A quasi-reversible redox wave at 1.1...H10TTPR was prepared starting from terephthalaldehyde and characterized. Crystal structure of H10TTPR and an intermediate compound 11 were determined by X-ray diffraction analysis. A quasi-reversible redox wave at 1.15 V (vs. SCE) was observed for H10TTPR, indicating that it is a weak electron donor.展开更多
Large two-photon absorption cross section of a novel compound trans-1,3,5-tri-(4-N,N-dimethylaminobenzylstyryl)-acetylacetone is measured to beσ_(2)=8.4×10^(-20)cm^(4)/GW orσ'_(2)=1.594×10^(-47)cm^(4)/...Large two-photon absorption cross section of a novel compound trans-1,3,5-tri-(4-N,N-dimethylaminobenzylstyryl)-acetylacetone is measured to beσ_(2)=8.4×10^(-20)cm^(4)/GW orσ'_(2)=1.594×10^(-47)cm^(4)/(photon.s)by using a 1064 nm Nd:YAG laser with 35 ps pulse width based on the intensity-dependent transmissivity measurement.The frequency upconversion fluorescence is observed by two-photon laser pumping.This material is an ideal candidate for optical limiting and upconversion fluorescence.展开更多
基金Project supported by National Natural Science Foundation of China (No. 90101025) Chinese Academy of Sciences and State Key Basic Research Program (No. G2000077505) and National Science Fund for Distinguished Young Scholars..
文摘H10TTPR was prepared starting from terephthalaldehyde and characterized. Crystal structure of H10TTPR and an intermediate compound 11 were determined by X-ray diffraction analysis. A quasi-reversible redox wave at 1.15 V (vs. SCE) was observed for H10TTPR, indicating that it is a weak electron donor.
基金Supported by the National Natural Science Foundation of China under Grant Nos.29832030 and 20072039the Foundation of Laboratory of Optical Physics at the Institute of Physics,Chinese Academy of Sciences.
文摘Large two-photon absorption cross section of a novel compound trans-1,3,5-tri-(4-N,N-dimethylaminobenzylstyryl)-acetylacetone is measured to beσ_(2)=8.4×10^(-20)cm^(4)/GW orσ'_(2)=1.594×10^(-47)cm^(4)/(photon.s)by using a 1064 nm Nd:YAG laser with 35 ps pulse width based on the intensity-dependent transmissivity measurement.The frequency upconversion fluorescence is observed by two-photon laser pumping.This material is an ideal candidate for optical limiting and upconversion fluorescence.
