Ag nanoparitcles were prepared via Ultrasound-assisted Membrane Reaction(UAMR)method.The key issue of the method is to control precisely the injection speed of the reactants by pulseless pump to make the nanoparticles...Ag nanoparitcles were prepared via Ultrasound-assisted Membrane Reaction(UAMR)method.The key issue of the method is to control precisely the injection speed of the reactants by pulseless pump to make the nanoparticles of Ag with small size and narrow size distribution.The size and morphology of silver nanoparticles were characterized with Transmission Electron Microscope(TEM)and UV-Vis spectrum.The experiment results show that the size of Ag nanoparticles prepared via UAMR method was smaller than that via Ultrasound-assisted Dropping Reaction(UADR)method.The size of 80% Ag nanoparticles prepared via UAMR was ranged from 3 nm to 5 nm with the mean particle size 4.7 nm and considerable narrow size distribution.The Ag hydrosol fabricated via UAMR method was very stable at room temperature,even within three months.展开更多
Pd(OH)2/C催化剂是制备六硝基六氮杂异伍兹烷(HNIW,C L-20)的关键材料。选择三种市售的活性炭为载体,采用浸渍沉积法制备了几种六苄基六氮杂异伍兹烷(HBIW)氢解脱苄Pd(OH)2/C催化剂。考察了载体活性炭的表面性质、孔径分布、催化剂制备...Pd(OH)2/C催化剂是制备六硝基六氮杂异伍兹烷(HNIW,C L-20)的关键材料。选择三种市售的活性炭为载体,采用浸渍沉积法制备了几种六苄基六氮杂异伍兹烷(HBIW)氢解脱苄Pd(OH)2/C催化剂。考察了载体活性炭的表面性质、孔径分布、催化剂制备温度、碱的种类及钯负载量对Pd(OH)2/C催化剂的催化活性的影响。催化活性和N2吸附、程序升温脱附(TPD)、粉末X射线衍射(XRD)和透射电镜(TEM)的特性表明,活性炭的表面性质、孔径分布、反应温度和钯负载量显著影响Pd(OH)2/C催化剂的催化活性,而活性炭的比表面积和催化剂制备过程中所用碱的种类不是影响Pd(OH)2/C催化剂性能的关键因素。用30%硝酸预处理AC RO S O rganics公司产的颗粒状活性炭为载体,碳酸钠为碱源,在反应温度5℃下,制得的9%Pd(O H)2/C催化剂有最佳的催化活性。催化剂中钯用量为底物HBIW的0.3%(质量分数)时,氢解脱苄乙酰化产物收率达93%。展开更多
文摘Ag nanoparitcles were prepared via Ultrasound-assisted Membrane Reaction(UAMR)method.The key issue of the method is to control precisely the injection speed of the reactants by pulseless pump to make the nanoparticles of Ag with small size and narrow size distribution.The size and morphology of silver nanoparticles were characterized with Transmission Electron Microscope(TEM)and UV-Vis spectrum.The experiment results show that the size of Ag nanoparticles prepared via UAMR method was smaller than that via Ultrasound-assisted Dropping Reaction(UADR)method.The size of 80% Ag nanoparticles prepared via UAMR was ranged from 3 nm to 5 nm with the mean particle size 4.7 nm and considerable narrow size distribution.The Ag hydrosol fabricated via UAMR method was very stable at room temperature,even within three months.
基金supported by the National Natural Science Foundation of China (21277009)the Funding Project for Academic Human Resources Development in Institutions of Higher Learning under the Jurisdiction of Beijing Municipality(PHR201107104)~~
文摘Pd(OH)2/C催化剂是制备六硝基六氮杂异伍兹烷(HNIW,C L-20)的关键材料。选择三种市售的活性炭为载体,采用浸渍沉积法制备了几种六苄基六氮杂异伍兹烷(HBIW)氢解脱苄Pd(OH)2/C催化剂。考察了载体活性炭的表面性质、孔径分布、催化剂制备温度、碱的种类及钯负载量对Pd(OH)2/C催化剂的催化活性的影响。催化活性和N2吸附、程序升温脱附(TPD)、粉末X射线衍射(XRD)和透射电镜(TEM)的特性表明,活性炭的表面性质、孔径分布、反应温度和钯负载量显著影响Pd(OH)2/C催化剂的催化活性,而活性炭的比表面积和催化剂制备过程中所用碱的种类不是影响Pd(OH)2/C催化剂性能的关键因素。用30%硝酸预处理AC RO S O rganics公司产的颗粒状活性炭为载体,碳酸钠为碱源,在反应温度5℃下,制得的9%Pd(O H)2/C催化剂有最佳的催化活性。催化剂中钯用量为底物HBIW的0.3%(质量分数)时,氢解脱苄乙酰化产物收率达93%。
