南海北部深水区陵水17-2气田储层地层压力系数1.19~1.21、孔隙度平均值为31.5%,渗透率平均值为633×10-3μm2,储层孔渗关系好;黏土含量为16.1%,具有盐敏、水敏等特点。对该气田测试液类型进行了优选:氯化钙海水溶液、甲酸钾海水溶液...南海北部深水区陵水17-2气田储层地层压力系数1.19~1.21、孔隙度平均值为31.5%,渗透率平均值为633×10-3μm2,储层孔渗关系好;黏土含量为16.1%,具有盐敏、水敏等特点。对该气田测试液类型进行了优选:氯化钙海水溶液、甲酸钾海水溶液和100%络合水3种基液均能满足密度在1.28~1.30 g/cm3内可调的要求;均具有较好的抑制性,防膨率均在95%左右;3种基液抑制气体水合物生成的浓度低限为28.06%氯化钙、51.05%甲酸钾和72.00%有机醇,因此甲酸钾基液抑制气体水合物生成的能力不足;氯化钙基液矿化度高,具有盐敏潜在损害;络合水自身具有较好的防水锁性,表面张力约为25 m N/m,而氯化钙和甲酸钾基液的表面张力较大。最终优选100%的络合水作测试液基液。其在陵水17-2-1井进行了应用,测试后产量为160×104 m3/d,表皮系数为0.2,储层保护效果好。展开更多
Sawdust xanthate modified with ethanediamine was used for the removal of Cu（Ⅱ） and Ni（Ⅱ） from aqueous solution. The influence of various operating parameters such temperature and adsorbent dosage on the adsorpti...Sawdust xanthate modified with ethanediamine was used for the removal of Cu（Ⅱ） and Ni（Ⅱ） from aqueous solution. The influence of various operating parameters such temperature and adsorbent dosage on the adsorption isotherms of modified sawdust was investigated. Thermodynamic parameters, namely Gibbs free energy （△GΘ）, enthalpy （△HΘ） and entropy （△SΘ） of Cu（Ⅱ） and Ni（Ⅱ） adsorption process were calculated, showing that the adsorption is a spontaneous and exothermic process. The modified extended Langmuir equation approaches provide excellent prediction of the binary adsorption. In single and binary systems, the overall adsorption data were best described by the pseudo-second order kinetic model, then the calculated values of activation energy of Cu（Ⅱ） and Ni（Ⅱ） adsorption process were 59.12 and 55.92 kJ/mol respectively. The results show that the affinity of each metal ion onto the modified sawdust surface is influenced by the presence of the other one.展开更多
文摘南海北部深水区陵水17-2气田储层地层压力系数1.19~1.21、孔隙度平均值为31.5%,渗透率平均值为633×10-3μm2,储层孔渗关系好;黏土含量为16.1%,具有盐敏、水敏等特点。对该气田测试液类型进行了优选:氯化钙海水溶液、甲酸钾海水溶液和100%络合水3种基液均能满足密度在1.28~1.30 g/cm3内可调的要求;均具有较好的抑制性,防膨率均在95%左右;3种基液抑制气体水合物生成的浓度低限为28.06%氯化钙、51.05%甲酸钾和72.00%有机醇,因此甲酸钾基液抑制气体水合物生成的能力不足;氯化钙基液矿化度高,具有盐敏潜在损害;络合水自身具有较好的防水锁性,表面张力约为25 m N/m,而氯化钙和甲酸钾基液的表面张力较大。最终优选100%的络合水作测试液基液。其在陵水17-2-1井进行了应用,测试后产量为160×104 m3/d,表皮系数为0.2,储层保护效果好。
基金Project(41061044)supported by the National Natural Science Foundation of ChinaProjects(2010GXNSFD013016,2012GXNSFAA053017)supported by the Natural Science Foundation of Guangxi,China
文摘Sawdust xanthate modified with ethanediamine was used for the removal of Cu（Ⅱ） and Ni（Ⅱ） from aqueous solution. The influence of various operating parameters such temperature and adsorbent dosage on the adsorption isotherms of modified sawdust was investigated. Thermodynamic parameters, namely Gibbs free energy （△GΘ）, enthalpy （△HΘ） and entropy （△SΘ） of Cu（Ⅱ） and Ni（Ⅱ） adsorption process were calculated, showing that the adsorption is a spontaneous and exothermic process. The modified extended Langmuir equation approaches provide excellent prediction of the binary adsorption. In single and binary systems, the overall adsorption data were best described by the pseudo-second order kinetic model, then the calculated values of activation energy of Cu（Ⅱ） and Ni（Ⅱ） adsorption process were 59.12 and 55.92 kJ/mol respectively. The results show that the affinity of each metal ion onto the modified sawdust surface is influenced by the presence of the other one.
