Hydrophobic membrane can provide fast mass transfer for absorption-desorption of gasesform liquid to absorbent.The removal of ammonia from ammonia water and absorption with dilutesulphuric acid was studied in a pilot ...Hydrophobic membrane can provide fast mass transfer for absorption-desorption of gasesform liquid to absorbent.The removal of ammonia from ammonia water and absorption with dilutesulphuric acid was studied in a pilot plant with polypropylene hollow fiber column,The removalrate and influences of operation temperature,flow rate and concentration on mass transferperformances were discussed mathematically.Experimental results and computer calculation show thatthe ammonia removal rate is not affected by the feed concentration for a given system.Both partialand overall mass transfer coefficients vary along the axis of the fiber,and the mass transfer for themembrane process is controlled by membrane resistance.展开更多
Multiple-effect membrane distillation (MEMD) process for enriching semi-volatile organic acids from their individual aqueous solutions was performed by using a hollow fiber-based air gap membrane distillation (AGMD...Multiple-effect membrane distillation (MEMD) process for enriching semi-volatile organic acids from their individual aqueous solutions was performed by using a hollow fiber-based air gap membrane distillation (AGMD) module with the function of internal heat recovery. Aqueous solutions of glyoxylic acid, glycolic acid, lactic acid, pyrnvic acid, malonic acid and glutaric acid were used as model feed. For a feed of 1% (mass fraction), each acid could be enriched for 8--20 times, which depended on the surface tension of the concentrate. The operation performance of MEMD process was characterized by permeation flux J, performance ratio PR and acid rejection rate R. The effects of cold feed-in temperature, heated feed-in temperature, feed-in volumetric flow rate and feed-in concen- tration on MEMD performance were experimentally evaluated. Maximum values of J, PR and R were 4.8 L/(h-m2), 9.84 and 99.93%, respectively. Moreover, MEMD process demonstrated a fairly good stability in a long-term experiment lasting for 30 d when aqueous solution of 4% (mass fraction) lactic acid was used as a feed.展开更多
文摘Hydrophobic membrane can provide fast mass transfer for absorption-desorption of gasesform liquid to absorbent.The removal of ammonia from ammonia water and absorption with dilutesulphuric acid was studied in a pilot plant with polypropylene hollow fiber column,The removalrate and influences of operation temperature,flow rate and concentration on mass transferperformances were discussed mathematically.Experimental results and computer calculation show thatthe ammonia removal rate is not affected by the feed concentration for a given system.Both partialand overall mass transfer coefficients vary along the axis of the fiber,and the mass transfer for themembrane process is controlled by membrane resistance.
文摘Multiple-effect membrane distillation (MEMD) process for enriching semi-volatile organic acids from their individual aqueous solutions was performed by using a hollow fiber-based air gap membrane distillation (AGMD) module with the function of internal heat recovery. Aqueous solutions of glyoxylic acid, glycolic acid, lactic acid, pyrnvic acid, malonic acid and glutaric acid were used as model feed. For a feed of 1% (mass fraction), each acid could be enriched for 8--20 times, which depended on the surface tension of the concentrate. The operation performance of MEMD process was characterized by permeation flux J, performance ratio PR and acid rejection rate R. The effects of cold feed-in temperature, heated feed-in temperature, feed-in volumetric flow rate and feed-in concen- tration on MEMD performance were experimentally evaluated. Maximum values of J, PR and R were 4.8 L/(h-m2), 9.84 and 99.93%, respectively. Moreover, MEMD process demonstrated a fairly good stability in a long-term experiment lasting for 30 d when aqueous solution of 4% (mass fraction) lactic acid was used as a feed.