The ozone consumption effect and organic removal ability of metal coated cordierite ceramic honeycombs catalytic ozonation （catazone） process and ozonation process were comparatively studied by pilot-scale experimen...The ozone consumption effect and organic removal ability of metal coated cordierite ceramic honeycombs catalytic ozonation （catazone） process and ozonation process were comparatively studied by pilot-scale experiments. By Scan Electron Microscope （SEM）, Atomic Force Microscope （AFM）, BET, and X-ray photoelectron spectroscopy （XPS） analysis, metal oxides attached to ceramic surface were found to be in the form of crystal cluster, and the pore structure of ceramics was less developed. The air flow statuses of vacant catazone and ozone contactors were inclined to be plug-flow and mixed flow, respectively. Comparing with ozonation process, the ozone mass transfer efficiency of catazone process is lower, and the ozone decomposition efficiency of catazone is higher. The former effect is more obvious in semi-batch experiment, and the latter effect is more obvious in continuous-flow experiment. Unsaturated organics removal efflciencies of the two oxidation processes are similar, and are less affected by dissolved ozone concentration when it is higher than 1 mg/L. More dissolved organics were detected in catazone process in continuous.flow reaction, and more CH3CI3 formation potential （CH3CI3FP） was removed by catazone in semi-batch mode, especially in the water with lower UV254 .展开更多
A phosphate-accumulating bacteria strain PAO3-1 was isolated from biological phosphorus removal sludge supplied with sodium acetate as carbon source under stable performance. This strain has good enhanced biological p...A phosphate-accumulating bacteria strain PAO3-1 was isolated from biological phosphorus removal sludge supplied with sodium acetate as carbon source under stable performance. This strain has good enhanced biological phosphorus removal effect on normal activated sludge system. Phosphorus removal ratio was raised form 44% with no added strain to more than 82% with strain strengthening biological phosphorus removal. It is identified to be Alcaligenes sp. according to its morphology, biochemical characteristics and 16S rDNA sequence analysis. The cell of strain PAO3-1 is straight bacilli form, 0.4×1.1μm, no flagellum, gram negative and special aerobiotic. The optimal temperature and pH for growth are 32℃-37℃ and 5.5-9.5, respectively. The shape of slant clone is feathery. The phosphate accumulating rate of strain PAO3-1 was 8.1mgP/g cell·h, and 14.3 mgP/g cell·h when in phosphate-starving situation, which was 76.5% higher than that in non-starving situation. Its phosphate release rate of log course in anaerobic phase and in culture without phosphorus was 7.6mgP/g cell·h, while in stable course the rate was 6.1mgP/g cell·h. The rate in stable course was 19.7% lower than that in log course.展开更多
文摘The ozone consumption effect and organic removal ability of metal coated cordierite ceramic honeycombs catalytic ozonation （catazone） process and ozonation process were comparatively studied by pilot-scale experiments. By Scan Electron Microscope （SEM）, Atomic Force Microscope （AFM）, BET, and X-ray photoelectron spectroscopy （XPS） analysis, metal oxides attached to ceramic surface were found to be in the form of crystal cluster, and the pore structure of ceramics was less developed. The air flow statuses of vacant catazone and ozone contactors were inclined to be plug-flow and mixed flow, respectively. Comparing with ozonation process, the ozone mass transfer efficiency of catazone process is lower, and the ozone decomposition efficiency of catazone is higher. The former effect is more obvious in semi-batch experiment, and the latter effect is more obvious in continuous-flow experiment. Unsaturated organics removal efflciencies of the two oxidation processes are similar, and are less affected by dissolved ozone concentration when it is higher than 1 mg/L. More dissolved organics were detected in catazone process in continuous.flow reaction, and more CH3CI3 formation potential （CH3CI3FP） was removed by catazone in semi-batch mode, especially in the water with lower UV254 .
基金Fok Ying Tung Education Foundation ( No.94004)Shanghai Natural ScienceFoundation(No.04ZR14010)Young Teacher Foundation of Donghua University (No.113-10-0044065)
文摘A phosphate-accumulating bacteria strain PAO3-1 was isolated from biological phosphorus removal sludge supplied with sodium acetate as carbon source under stable performance. This strain has good enhanced biological phosphorus removal effect on normal activated sludge system. Phosphorus removal ratio was raised form 44% with no added strain to more than 82% with strain strengthening biological phosphorus removal. It is identified to be Alcaligenes sp. according to its morphology, biochemical characteristics and 16S rDNA sequence analysis. The cell of strain PAO3-1 is straight bacilli form, 0.4×1.1μm, no flagellum, gram negative and special aerobiotic. The optimal temperature and pH for growth are 32℃-37℃ and 5.5-9.5, respectively. The shape of slant clone is feathery. The phosphate accumulating rate of strain PAO3-1 was 8.1mgP/g cell·h, and 14.3 mgP/g cell·h when in phosphate-starving situation, which was 76.5% higher than that in non-starving situation. Its phosphate release rate of log course in anaerobic phase and in culture without phosphorus was 7.6mgP/g cell·h, while in stable course the rate was 6.1mgP/g cell·h. The rate in stable course was 19.7% lower than that in log course.
