Improving the emission performance of colloidal quantum dots(QDs)is of paramount importance for their applications on light-emitting diodes(LEDs),displays and lasers.A highly promising approach is to tune the carrier ...Improving the emission performance of colloidal quantum dots(QDs)is of paramount importance for their applications on light-emitting diodes(LEDs),displays and lasers.A highly promising approach is to tune the carrier recombination channels and lifetime by exploiting the energy transfer process.However,to achieve this precise emission optimization,quantitative modulation on energy transfer efficiency is highly desirable but still challenging.Here,we demonstrate a convenient approach to realize tunable energy transfer efficiency by forming QDs mixture with controllable donor/acceptor(D/A)ratio.With the mixing ratio ranging from 16/1 to 1/16,the energy transfer efficiency could be effectively tuned from near zero to~70%.For the high mixing ratio of 16/1,acceptors obtain adequate energy supplied by closely surrounding donors,leading to~2.4-fold PL enhancement.While for the low mixing ratio,the ultrafast and efficient energy extraction process directly suppresses the multi-exciton and Auger recombination in the donor,bringing about a higher threshold.The facile modulation of emission performance by controllably designed mixing ratio and quantitatively tunable energy transfer efficiency will facilitate QD-based optoelectronic and photovoltaic applications.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52025023,51991342,52021006,11888101,and 61922028)the Key R&D Program of Guangdong Province,China(Grant Nos.2020B010189001,2019B010931001,and 2018B030327001)+3 种基金the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB33000000)Beijing Natural Science Foundation,China(Grant No.JQ19004)the Pearl River Talent Recruitment Program of Guangdong Province,China(Grant No.2019ZT08C321)China Postdoctoral Science Foundation(Grant No.2021T140022)。
文摘Improving the emission performance of colloidal quantum dots(QDs)is of paramount importance for their applications on light-emitting diodes(LEDs),displays and lasers.A highly promising approach is to tune the carrier recombination channels and lifetime by exploiting the energy transfer process.However,to achieve this precise emission optimization,quantitative modulation on energy transfer efficiency is highly desirable but still challenging.Here,we demonstrate a convenient approach to realize tunable energy transfer efficiency by forming QDs mixture with controllable donor/acceptor(D/A)ratio.With the mixing ratio ranging from 16/1 to 1/16,the energy transfer efficiency could be effectively tuned from near zero to~70%.For the high mixing ratio of 16/1,acceptors obtain adequate energy supplied by closely surrounding donors,leading to~2.4-fold PL enhancement.While for the low mixing ratio,the ultrafast and efficient energy extraction process directly suppresses the multi-exciton and Auger recombination in the donor,bringing about a higher threshold.The facile modulation of emission performance by controllably designed mixing ratio and quantitatively tunable energy transfer efficiency will facilitate QD-based optoelectronic and photovoltaic applications.
