An orientation distribution model has been suggested for interfacial monomolecular lay-ers by taking account of the orientational uniaxiality of long-chain amphiphilic molecules inmonolayers. The resonance Raman spect...An orientation distribution model has been suggested for interfacial monomolecular lay-ers by taking account of the orientational uniaxiality of long-chain amphiphilic molecules inmonolayers. The resonance Raman spectra of azo-containing monolayers are the oreticallytreated on the basis of the model. Order parameters <P_2> and (P_4> are obtained from polar-ized Raman measurements, giving rise to distribution graphs. These analyses indicate thatthe orientation distribution alters upon the increase of adsorption amount and displays inter-esting variation among different interfacial monolayers. The aggregate aspects of the 2-dimensional condensed states are also discussed from the viewpoint of molecular orientation.展开更多
基金Project supported by the National Natural Science Foundation of China.
文摘An orientation distribution model has been suggested for interfacial monomolecular lay-ers by taking account of the orientational uniaxiality of long-chain amphiphilic molecules inmonolayers. The resonance Raman spectra of azo-containing monolayers are the oreticallytreated on the basis of the model. Order parameters <P_2> and (P_4> are obtained from polar-ized Raman measurements, giving rise to distribution graphs. These analyses indicate thatthe orientation distribution alters upon the increase of adsorption amount and displays inter-esting variation among different interfacial monolayers. The aggregate aspects of the 2-dimensional condensed states are also discussed from the viewpoint of molecular orientation.
