Peripherally low symmetric substitution with electron-donating(EDG)and electron-withdrawing(EWG)substituents caused the rational modulation of geometric structure and even the electronic structure of triazasubporphyri...Peripherally low symmetric substitution with electron-donating(EDG)and electron-withdrawing(EWG)substituents caused the rational modulation of geometric structure and even the electronic structure of triazasubporphyrin,the smallest 14πconjugated aza-porphyrinoids.Both structural characterization and spectroscopic investigation were discussed to provide an in-depth understanding of the relationship between peripheral push-pull substituents and SubPz core.展开更多
基金Financially supported by the National Natural Science Foundation of China(No.21701058)the Natural Science Foundation of Jiangsu province(No.BK20160499)+3 种基金the State Key Laboratory of Coordination Chemistry(SKLCC1817)the Key Laboratory of Functional Inorganic Material Chemistry(Heilongjiang University)of Ministry of Education,the China post-doc foundation(No.2018M642183)the Lanzhou Entrepreneurial and Innovative Talents Project(2018-RC-105)the Jiangsu University(No.17JDG035)。
文摘Peripherally low symmetric substitution with electron-donating(EDG)and electron-withdrawing(EWG)substituents caused the rational modulation of geometric structure and even the electronic structure of triazasubporphyrin,the smallest 14πconjugated aza-porphyrinoids.Both structural characterization and spectroscopic investigation were discussed to provide an in-depth understanding of the relationship between peripheral push-pull substituents and SubPz core.
