Ketocoumarin dye 3-acetyl-7-diethylaminecoumrin was synthesized and charater ized. The spectra and photophysics behavior were studied in different aprotic solvents. Results showed that the fluorescence quantum yield h...Ketocoumarin dye 3-acetyl-7-diethylaminecoumrin was synthesized and charater ized. The spectra and photophysics behavior were studied in different aprotic solvents. Results showed that the fluorescence quantum yield had a maximum and the ratio of non-radiative transition rate to radiative transition rate had a minimum with the increasing of the solvent polarity. Also, the fluorescence of the dye can be quenched by triethylamine and the change is in accordance with the Stern-Volmer formula. These phenomenon was discussed preliminarily.展开更多
The photosensitive initiating system composed of 7 diethylamino 3 (2’ N methylbenzimidazolyl)coumarin dye (DBC) as sensitizer and diphenyliodonium hexafluorophosphate (DIH) as initiator,can be used to initiate the po...The photosensitive initiating system composed of 7 diethylamino 3 (2’ N methylbenzimidazolyl)coumarin dye (DBC) as sensitizer and diphenyliodonium hexafluorophosphate (DIH) as initiator,can be used to initiate the polymerization of methyl methacrylate (MMA) in visible light.When exposed to visible light,coumarin dye/iodonium salt undergoes quick electron transfer from DBC to DIH and free radicals are produced.The visible light photoinduced reaction between DBC and DIH is mainly through the excited singlet state of DBC and thus it is little sensitive to O 2.The fluorescence of DBC can be quenched efficiently by DIH and the change is in accord with Stern Volmer equation and the quench constant K q can reach 10 12 M -1 S -1 .The influence of concentration of DBC on the polymerization rate of MMA shows that coumarin free radical act mainly as chain terminator in polymerization and has a stronger tendency to terminate the chain reaction.展开更多
文摘Ketocoumarin dye 3-acetyl-7-diethylaminecoumrin was synthesized and charater ized. The spectra and photophysics behavior were studied in different aprotic solvents. Results showed that the fluorescence quantum yield had a maximum and the ratio of non-radiative transition rate to radiative transition rate had a minimum with the increasing of the solvent polarity. Also, the fluorescence of the dye can be quenched by triethylamine and the change is in accordance with the Stern-Volmer formula. These phenomenon was discussed preliminarily.
文摘The photosensitive initiating system composed of 7 diethylamino 3 (2’ N methylbenzimidazolyl)coumarin dye (DBC) as sensitizer and diphenyliodonium hexafluorophosphate (DIH) as initiator,can be used to initiate the polymerization of methyl methacrylate (MMA) in visible light.When exposed to visible light,coumarin dye/iodonium salt undergoes quick electron transfer from DBC to DIH and free radicals are produced.The visible light photoinduced reaction between DBC and DIH is mainly through the excited singlet state of DBC and thus it is little sensitive to O 2.The fluorescence of DBC can be quenched efficiently by DIH and the change is in accord with Stern Volmer equation and the quench constant K q can reach 10 12 M -1 S -1 .The influence of concentration of DBC on the polymerization rate of MMA shows that coumarin free radical act mainly as chain terminator in polymerization and has a stronger tendency to terminate the chain reaction.
