The geometric structure parameters and radial density distribution of 1s2s1S excited state of the two-electron atomic system near the critical nuclear charge Z_(c)were calculated in detail under tripled Hylleraas basi...The geometric structure parameters and radial density distribution of 1s2s1S excited state of the two-electron atomic system near the critical nuclear charge Z_(c)were calculated in detail under tripled Hylleraas basis set.Contrary to the localized behavior observed in the ground and the doubly excited 2p^(23)Pe states,for this state our results identify that while the behavior of the inner electron increasingly resembles that of a hydrogen-like atomic system,the outer electron in the excited state exhibits diffused hydrogen-like character and becomes perpendicular to the inner electron as nuclear charge Z approaches Z_(c).This study provides insights into the electronic structure and stability of the two-electron system in the vicinity of the critical nuclear charge.展开更多
Expectation values of single electron and interelectronic geometric quantities such as <γ>,<γ_(12)> ,<γ_(<)> , <γ_(>)>,<cosθ_(12)> and <θ_(12)> are calculated for doubly...Expectation values of single electron and interelectronic geometric quantities such as <γ>,<γ_(12)> ,<γ_(<)> , <γ_(>)>,<cosθ_(12)> and <θ_(12)> are calculated for doubly excited 2pnp ^(1)P^(e)(3 ≤ n ≤ 5), 2pnp ^(3)P^(e)(2 ≤ n ≤ 5)and 2pnd ^(1,3)D°(3 ≤ n ≤ 5) states of helium using Hylleraas-B-spline basis set. The energy levels converge to at least 10 significant digits in our calculations.The extrapolated values of geometric quantities except for <θ_(12)> reach 10 significant digits as well;<θ_(12)> reaches at least 7 significant digits using a multipole expansion approach. Our results provide a precise reference for future research.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.12074295,12304271,and 12104420).
文摘The geometric structure parameters and radial density distribution of 1s2s1S excited state of the two-electron atomic system near the critical nuclear charge Z_(c)were calculated in detail under tripled Hylleraas basis set.Contrary to the localized behavior observed in the ground and the doubly excited 2p^(23)Pe states,for this state our results identify that while the behavior of the inner electron increasingly resembles that of a hydrogen-like atomic system,the outer electron in the excited state exhibits diffused hydrogen-like character and becomes perpendicular to the inner electron as nuclear charge Z approaches Z_(c).This study provides insights into the electronic structure and stability of the two-electron system in the vicinity of the critical nuclear charge.
基金Project supported by the National Natural Science Foundation of China (Grant No. 12074295)。
文摘Expectation values of single electron and interelectronic geometric quantities such as <γ>,<γ_(12)> ,<γ_(<)> , <γ_(>)>,<cosθ_(12)> and <θ_(12)> are calculated for doubly excited 2pnp ^(1)P^(e)(3 ≤ n ≤ 5), 2pnp ^(3)P^(e)(2 ≤ n ≤ 5)and 2pnd ^(1,3)D°(3 ≤ n ≤ 5) states of helium using Hylleraas-B-spline basis set. The energy levels converge to at least 10 significant digits in our calculations.The extrapolated values of geometric quantities except for <θ_(12)> reach 10 significant digits as well;<θ_(12)> reaches at least 7 significant digits using a multipole expansion approach. Our results provide a precise reference for future research.
