Removal of single component and binary mixtures of benzene and m-xylene using a multi-pin-mesh reactor was studied to find the decomposition characteristics, carbon balance and CO2 selectivity. The decomposition rate ...Removal of single component and binary mixtures of benzene and m-xylene using a multi-pin-mesh reactor was studied to find the decomposition characteristics, carbon balance and CO2 selectivity. The decomposition rate of benzene in mixture was approximately 16% lower than that of single component benzene. However, the decomposition rate of m-xylene in mixture was slightly higher than that of single component m-xylene. Carbon balance of the mixture decomposition process achieved a lower level than that of single component benzene/m-xylene. Increase in the specific input energy was helpful to improve CO2 selectivity in the single component decomposition process, while the specific input energy had a negligible effect on CO2 selectivity in the mixture decomposition process. By changing the oxygen content in background gas, we found that different types of radicals showed different reaction activities toward benzene and m-xylene. Benzene was more likely to react with nitrogen-containing radicals, while m-xylene was more likely to react with oxygen-containing radicals.展开更多
In this study, the improvement in the removal of chlorobenzene （C6H5Cl） in the air was investigated by combining dielectric barrier discharge （DBD） driven by bipolar pulse-power with catalysts. Molecular sieve 4A ...In this study, the improvement in the removal of chlorobenzene （C6H5Cl） in the air was investigated by combining dielectric barrier discharge （DBD） driven by bipolar pulse-power with catalysts. Molecular sieve 4A （MS-4A） and MnO2/γ-Al2O3 （MnO2/ALP） as two kinds of catalysts were tested at different positions in a DBD reactor. Catalysts were located either in the discharging area between two electrodes, or just behind the discharging area （in the afterglow area） closed to the outlet. The results indicated that DBD reactor with a bipolar pulse power-supply produced strong instant discharge and energetic particles, which can effectively activate catalysts of MS-4A and MnO2/ALP located in the afterglow area to achieve the synergistic effects on effective fission of chemical bonds of chlorobenzene. It was considered that the gas-chlorobenzene and the chlorobenzene adsorbed on the catalysts were decomposed simultaneously.展开更多
文摘将四氯乙烯,间二甲苯气态混合物同时引入无声放电反应器,加工频正弦交流高压对混合污染物进行放电分解实验.结果发现:与单一组分污染物的降解特性相比,混合气体中四氯乙烯的降解率变化较大,最大降解率由单独处理时的76%下降到27%,而间二甲苯的降解率基本保持不变,最大降解率可达90%左右;相同条件下,不锈钢棒高压电极对污染物的降解效果要略好于螺纹钢棒电极;3种电极间距对混合气体的降解效果依次为5 mm>7.5 mm>10 mm.
基金supported by National Natural Science Foundation of China (No.50678031)
文摘Removal of single component and binary mixtures of benzene and m-xylene using a multi-pin-mesh reactor was studied to find the decomposition characteristics, carbon balance and CO2 selectivity. The decomposition rate of benzene in mixture was approximately 16% lower than that of single component benzene. However, the decomposition rate of m-xylene in mixture was slightly higher than that of single component m-xylene. Carbon balance of the mixture decomposition process achieved a lower level than that of single component benzene/m-xylene. Increase in the specific input energy was helpful to improve CO2 selectivity in the single component decomposition process, while the specific input energy had a negligible effect on CO2 selectivity in the mixture decomposition process. By changing the oxygen content in background gas, we found that different types of radicals showed different reaction activities toward benzene and m-xylene. Benzene was more likely to react with nitrogen-containing radicals, while m-xylene was more likely to react with oxygen-containing radicals.
基金National Natural Science Foundation of China(No.50678031)
文摘In this study, the improvement in the removal of chlorobenzene （C6H5Cl） in the air was investigated by combining dielectric barrier discharge （DBD） driven by bipolar pulse-power with catalysts. Molecular sieve 4A （MS-4A） and MnO2/γ-Al2O3 （MnO2/ALP） as two kinds of catalysts were tested at different positions in a DBD reactor. Catalysts were located either in the discharging area between two electrodes, or just behind the discharging area （in the afterglow area） closed to the outlet. The results indicated that DBD reactor with a bipolar pulse power-supply produced strong instant discharge and energetic particles, which can effectively activate catalysts of MS-4A and MnO2/ALP located in the afterglow area to achieve the synergistic effects on effective fission of chemical bonds of chlorobenzene. It was considered that the gas-chlorobenzene and the chlorobenzene adsorbed on the catalysts were decomposed simultaneously.
