Nanoporous copper with nano-scale pore size was synthesized by dealloying Mn-Cu precursor alloy using a free corrosion method. The effects of heat treatment of Mn-Cu precursors on alloy phase, morphology and compositi...Nanoporous copper with nano-scale pore size was synthesized by dealloying Mn-Cu precursor alloy using a free corrosion method. The effects of heat treatment of Mn-Cu precursors on alloy phase, morphology and composition of the resultant nanoporous copper were investigated. It is revealed that the compositions distribute homogeneously in the bulk Mn-Cu precursors, which consequently results in a more fully dealloying for forming nanoporous copper. The alloy phase changes from Cuo.a9Mno.51 and Cuo.21Mno.79 of non-thermally treated precursor to Cuo.33Mn0.67 of heat treated alloy. The residual Mn content in nanoporous copper is decreased from 12.97% to 2.04% （molar fraction） made from the precursor without and with 95 h heat treatment. The typical pore shape of nanoporous copper prepared by dealloying the precursor without the heat treatment is divided into two different zones： the uniform bi-continuous structure zone and the blurry or no pore structure zone. Nanoporous copper is of a uniform sponge-like morphology made from the heat-treated precursor, and the average ligament diameter is 40 nm, far smaller than that from the non-thermally treated precursor, in which the average ligament diameter is estimated to be about 70 nm.展开更多
Single-phase Ag2Al intermetallic nanoparticles, and Ag and Al metallic nanoparticles were synthesized by the flow-levitation （FL） method. Measurements of d-spacings from X-ray diffraction and electron diffraction co...Single-phase Ag2Al intermetallic nanoparticles, and Ag and Al metallic nanoparticles were synthesized by the flow-levitation （FL） method. Measurements of d-spacings from X-ray diffraction and electron diffraction confirmed that the intermetallic nanoparticles had the hexagonal Ag2Al structure. The morphology, crystal structure and chemical composition of Ag2Al nanoparticles were investigated by transmission electron microscopy, X-ray diffraction and induction-coupled plasma spectroscopy. A thin amorphous coating was formed around the particles when exposed to air. Based on the XPS measurements, the surface coating of the Ag2Al nanoparticles could most likely be aluminum oxide or silver aluminum oxide. Therefore, the single-phase nanocrystalline Ag2Al intermetallic compound particles can be produced by adjusting some experimental parameters in FL method.展开更多
In order to significantly improve the absorption efficiency of monolayer molybdenum disulfide(M-MoS_(2)), an ultranarrowband M-MoS_(2)metamaterial absorber was obtained through theoretical analysis and numerical calcu...In order to significantly improve the absorption efficiency of monolayer molybdenum disulfide(M-MoS_(2)), an ultranarrowband M-MoS_(2)metamaterial absorber was obtained through theoretical analysis and numerical calculation using the finite difference time domain method. The physical mechanism can be better analyzed through critical coupling and guided mode resonance. Its absorption rate at λ = 806.41 nm is as high as 99.8%, which is more than 12 times that of bare MMoS_(2). From the simulation results, adjusting the geometric parameters of the structure can control the resonant wavelength range of the M-MoS_(2). In addition, we also found that the maximum quality factor is 1256.8. The numerical result shows that the design provides new possibilities for ultra-narrowband M-MoS_(2) perfect absorbers in the near-infrared spectrum.The results of this work indicate that the designed structure has excellent prospects for application in wavelength-selective photoluminescence and photodetection.展开更多
We design a four-band terahertz metamaterial absorber that relied on the block Dirac semi-metal(BDS).It is composed of a Dirac material layer,a gold reflecting layer,and a photonic crystal slab(PCS)medium layer.This s...We design a four-band terahertz metamaterial absorber that relied on the block Dirac semi-metal(BDS).It is composed of a Dirac material layer,a gold reflecting layer,and a photonic crystal slab(PCS)medium layer.This structure achieved perfect absorption of over 97%at 4.06 THz,6.15 THz,and 8.16 THz.The high absorption can be explained by the localized surface plasmon resonance(LSPR).And this conclusion can be proved by the detailed design of the surface structure.Moreover,the resonant frequency of the device can be dynamically tuned by changing the Fermi energy of the BDS.Due to the advantages such as high absorption,adjustable resonance,and anti-interference of incident angle and polarization mode,the Dirac semi-metal perfect absorber(DSPA)has great potential value in fields such as biochemical sensing,information communication,and nondestructive detection.展开更多
We propose a hybrid structure of a nano-cube array coupled with multilayer full-dielectric thin films for refractive index sensing.In this structure,discrete states generated by two-dimensional grating and continuous ...We propose a hybrid structure of a nano-cube array coupled with multilayer full-dielectric thin films for refractive index sensing.In this structure,discrete states generated by two-dimensional grating and continuous states generated by a photonic crystal were coupled at a specific wavelength to form two Fano resonances.The transmission spectra and electric field distributions of the structure were obtained via the finite-difference time-domain method.We obtained the optimal structural parameters after optimizing the geometrical parameters.Under the optimal parameters,the figure of merit(FOM)values of the two Fano resonances reached 1.7×10^(4)and 3.9×10^(3),respectively.These results indicate that the proposed structure can achieve high FOM refractive index sensing,thus offering extensive application prospects in the biological and chemical fields.展开更多
The synthesis of high purity intermetallic FeAI nanoparticles using the flow-levitation （FL） method was reported. Iron and aluminium droplets were levitated stably at about 2 230℃. The morphology, clystal structure...The synthesis of high purity intermetallic FeAI nanoparticles using the flow-levitation （FL） method was reported. Iron and aluminium droplets were levitated stably at about 2 230℃. The morphology, clystal structure and chemical composition of FeAI nanoparticles were investigated by transmission electron microscopy （TEM）, high-resolution TEM, X-ray diffraction and energy dispersive spectrometry. The results show that the average particle size of these nanoparticles is about 34.5 nm. Measurements of the d-spacing from X-ray diffraction and electron diffraction studies confirm that the intermetallic nanoparticles have the same crystal structure （B2） as the bulk FeA1. A thin oxidation coating is formed around the particles when being exposed to air. Based on the XPS measurements, the surface coating of the FeAI nanoparticles is composed of Fe2O3 and FeAl2O4. Besides, hysteresis curve reveals that saturation magnetization （Ms） of FeA1 is 1.66 A/m2, and the coercivity is about 1.214×10^3 A/re.展开更多
基金Project(10804101) supported by the National Natural Science Foundation of ChinaProject(9140C6805021008) supported by the State Key Development Program for Basic Research of ChinaProject(2007B08007) supported by the Science and Technology Development Foundation of Chinese Academy of Engineering Physics
文摘Nanoporous copper with nano-scale pore size was synthesized by dealloying Mn-Cu precursor alloy using a free corrosion method. The effects of heat treatment of Mn-Cu precursors on alloy phase, morphology and composition of the resultant nanoporous copper were investigated. It is revealed that the compositions distribute homogeneously in the bulk Mn-Cu precursors, which consequently results in a more fully dealloying for forming nanoporous copper. The alloy phase changes from Cuo.a9Mno.51 and Cuo.21Mno.79 of non-thermally treated precursor to Cuo.33Mn0.67 of heat treated alloy. The residual Mn content in nanoporous copper is decreased from 12.97% to 2.04% （molar fraction） made from the precursor without and with 95 h heat treatment. The typical pore shape of nanoporous copper prepared by dealloying the precursor without the heat treatment is divided into two different zones： the uniform bi-continuous structure zone and the blurry or no pore structure zone. Nanoporous copper is of a uniform sponge-like morphology made from the heat-treated precursor, and the average ligament diameter is 40 nm, far smaller than that from the non-thermally treated precursor, in which the average ligament diameter is estimated to be about 70 nm.
基金National Natural Science Foundation of China(51306165)Open Foundation of Joint Laboratory for Extreme Conditions Matter Properties,Southwest University of Science and Technology and Research Center of Laser Fusion,CAEP(12zxjk01)Science and Technology Foundation of CAEP(2013B0302052)
基金Project (10804101) supported by the National Natural Science Foundation of China
文摘Single-phase Ag2Al intermetallic nanoparticles, and Ag and Al metallic nanoparticles were synthesized by the flow-levitation （FL） method. Measurements of d-spacings from X-ray diffraction and electron diffraction confirmed that the intermetallic nanoparticles had the hexagonal Ag2Al structure. The morphology, crystal structure and chemical composition of Ag2Al nanoparticles were investigated by transmission electron microscopy, X-ray diffraction and induction-coupled plasma spectroscopy. A thin amorphous coating was formed around the particles when exposed to air. Based on the XPS measurements, the surface coating of the Ag2Al nanoparticles could most likely be aluminum oxide or silver aluminum oxide. Therefore, the single-phase nanocrystalline Ag2Al intermetallic compound particles can be produced by adjusting some experimental parameters in FL method.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11604311, 61705204, and 21506257)the Scientific Research Fund of Si Chuan Provincial Science and Technology Department, China (Grant Nos. 2020YJ0137 and 2020YFG0467)+1 种基金the National Defense Science and Technology Innovation Special Zone Project of China (Grant No. 19-163-21-TS-001-067-01)the College Students’s Innovation and Entrepreneurship Training Program (Grant No. S202110619065)。
文摘In order to significantly improve the absorption efficiency of monolayer molybdenum disulfide(M-MoS_(2)), an ultranarrowband M-MoS_(2)metamaterial absorber was obtained through theoretical analysis and numerical calculation using the finite difference time domain method. The physical mechanism can be better analyzed through critical coupling and guided mode resonance. Its absorption rate at λ = 806.41 nm is as high as 99.8%, which is more than 12 times that of bare MMoS_(2). From the simulation results, adjusting the geometric parameters of the structure can control the resonant wavelength range of the M-MoS_(2). In addition, we also found that the maximum quality factor is 1256.8. The numerical result shows that the design provides new possibilities for ultra-narrowband M-MoS_(2) perfect absorbers in the near-infrared spectrum.The results of this work indicate that the designed structure has excellent prospects for application in wavelength-selective photoluminescence and photodetection.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11604311,61705204,and 21506257)the Scientific Research Fund from Sichuan Provincial Science and Technology Department(Grant Nos.2020YJ0137 and 2020YFG0467)+2 种基金the Undergraduate Innovation Fund by Southwest University of Science and Technology(Grant No.JZ20-027)the Fund by the School of Science of Southwest University of Science and Technology for the Innovation Fund Project(Grant No.LX2020010)the Undergraduate Innovation and Entrepreneurship Training Program of Southwest University of Science and Technology(Grant No.S202010619073).
文摘We design a four-band terahertz metamaterial absorber that relied on the block Dirac semi-metal(BDS).It is composed of a Dirac material layer,a gold reflecting layer,and a photonic crystal slab(PCS)medium layer.This structure achieved perfect absorption of over 97%at 4.06 THz,6.15 THz,and 8.16 THz.The high absorption can be explained by the localized surface plasmon resonance(LSPR).And this conclusion can be proved by the detailed design of the surface structure.Moreover,the resonant frequency of the device can be dynamically tuned by changing the Fermi energy of the BDS.Due to the advantages such as high absorption,adjustable resonance,and anti-interference of incident angle and polarization mode,the Dirac semi-metal perfect absorber(DSPA)has great potential value in fields such as biochemical sensing,information communication,and nondestructive detection.
基金supported by the National Natural Science Foundation of China(Grant No.61865008)the Hong Liu FirstClass Disciplines Development Program of Lanzhou University of Technology。
文摘We propose a hybrid structure of a nano-cube array coupled with multilayer full-dielectric thin films for refractive index sensing.In this structure,discrete states generated by two-dimensional grating and continuous states generated by a photonic crystal were coupled at a specific wavelength to form two Fano resonances.The transmission spectra and electric field distributions of the structure were obtained via the finite-difference time-domain method.We obtained the optimal structural parameters after optimizing the geometrical parameters.Under the optimal parameters,the figure of merit(FOM)values of the two Fano resonances reached 1.7×10^(4)and 3.9×10^(3),respectively.These results indicate that the proposed structure can achieve high FOM refractive index sensing,thus offering extensive application prospects in the biological and chemical fields.
基金Project(10804101) supported by the National Natural Science Foundation of China
文摘The synthesis of high purity intermetallic FeAI nanoparticles using the flow-levitation （FL） method was reported. Iron and aluminium droplets were levitated stably at about 2 230℃. The morphology, clystal structure and chemical composition of FeAI nanoparticles were investigated by transmission electron microscopy （TEM）, high-resolution TEM, X-ray diffraction and energy dispersive spectrometry. The results show that the average particle size of these nanoparticles is about 34.5 nm. Measurements of the d-spacing from X-ray diffraction and electron diffraction studies confirm that the intermetallic nanoparticles have the same crystal structure （B2） as the bulk FeA1. A thin oxidation coating is formed around the particles when being exposed to air. Based on the XPS measurements, the surface coating of the FeAI nanoparticles is composed of Fe2O3 and FeAl2O4. Besides, hysteresis curve reveals that saturation magnetization （Ms） of FeA1 is 1.66 A/m2, and the coercivity is about 1.214×10^3 A/re.
