采用两台波长1064nm的调Q脉冲Nd∶YAG激光器和多通道小型光纤光栅光谱仪,建立了一套共线双脉冲激光诱导击穿光谱分析装置。与单脉冲激光诱导技术相比,在最佳双脉冲时间延时8μs时,Mn I 403.07nm和Cr I 425.43nm的光谱强度分别增加了14....采用两台波长1064nm的调Q脉冲Nd∶YAG激光器和多通道小型光纤光栅光谱仪,建立了一套共线双脉冲激光诱导击穿光谱分析装置。与单脉冲激光诱导技术相比,在最佳双脉冲时间延时8μs时,Mn I 403.07nm和Cr I 425.43nm的光谱强度分别增加了14.3倍和17.2倍,以这两条谱线为分析线,铝合金中Mn和Cr的检测限分别由单脉冲时的73和94.5μg/g降低至双脉冲时的3.76和4.26μg/g,检测灵敏度提高了约20倍。展开更多
Toxic metals such as lead and chromium in aqueous solutions have been analyzed simultaneously by laser-induced breakdown spectroscopy（LIBS）, in which the ordinary printing paper is used as a liquid absorber which wa...Toxic metals such as lead and chromium in aqueous solutions have been analyzed simultaneously by laser-induced breakdown spectroscopy（LIBS）, in which the ordinary printing paper is used as a liquid absorber which was immerged into Pb（NO3）2and Cr（NO3）3aqueous solution to enrich the heavy metals. This method overcomes the drawbacks of splashing and low sensitivity in ordinary LIBS analysis of water, in which a laser beam is directly focused on a liquid surface. A good signal intensity and reproducibility has been demonstrated. The Pb 405.78 nm and Cr 427.48 nm spectral lines are used as the analytical lines. The variation of line intensity with immersion time was investigated. The calibration curve for quantitative measurement of Pb and Cr in water was established, and the detection limits are 0.033 mg/L and 0.026 mg/L respectively,which is about 2-3 orders of magnitude better than that in the ordinary LIBS analysis of heavy metal in solution.展开更多
文摘采用两台波长1064nm的调Q脉冲Nd∶YAG激光器和多通道小型光纤光栅光谱仪,建立了一套共线双脉冲激光诱导击穿光谱分析装置。与单脉冲激光诱导技术相比,在最佳双脉冲时间延时8μs时,Mn I 403.07nm和Cr I 425.43nm的光谱强度分别增加了14.3倍和17.2倍,以这两条谱线为分析线,铝合金中Mn和Cr的检测限分别由单脉冲时的73和94.5μg/g降低至双脉冲时的3.76和4.26μg/g,检测灵敏度提高了约20倍。
基金supported by National Natural Science Foundation of China(No.61178034)Key Research Project of University of Zhejiang Province,China(No.ZD2009006)the Program for Innovative Research Team,Zhejiang Normal University,China
文摘Toxic metals such as lead and chromium in aqueous solutions have been analyzed simultaneously by laser-induced breakdown spectroscopy（LIBS）, in which the ordinary printing paper is used as a liquid absorber which was immerged into Pb（NO3）2and Cr（NO3）3aqueous solution to enrich the heavy metals. This method overcomes the drawbacks of splashing and low sensitivity in ordinary LIBS analysis of water, in which a laser beam is directly focused on a liquid surface. A good signal intensity and reproducibility has been demonstrated. The Pb 405.78 nm and Cr 427.48 nm spectral lines are used as the analytical lines. The variation of line intensity with immersion time was investigated. The calibration curve for quantitative measurement of Pb and Cr in water was established, and the detection limits are 0.033 mg/L and 0.026 mg/L respectively,which is about 2-3 orders of magnitude better than that in the ordinary LIBS analysis of heavy metal in solution.
