渗透性和离子筛分能力是决定纳滤膜分离性能的主要指标.扩大渗透分离层的表面积不仅是提升膜通量的有效途径,还保持了盐的截留效果.受氨基/亚胺与酰氯缩合交联形成致密的聚酰胺网络的启发,我们提出了一种策略:将多孔的卟啉-苯胺共轭微...渗透性和离子筛分能力是决定纳滤膜分离性能的主要指标.扩大渗透分离层的表面积不仅是提升膜通量的有效途径,还保持了盐的截留效果.受氨基/亚胺与酰氯缩合交联形成致密的聚酰胺网络的启发,我们提出了一种策略:将多孔的卟啉-苯胺共轭微孔聚合物(PACMP)接枝到聚酰胺膜上,从而增大纳滤膜的分离表面积.通过一步界面聚合,制备了一种超渗透的共轭微孔聚合物-聚酰胺复合膜(CPCMs),其水通量为61.8 L m^(−2) h^(−1),对盐(Na_(2)SO_(4))的截留率高于91.6%.此外,由于PACMPs中卟啉基团产生的活性氧,原位光激发单线态氧1O2可杀死98.5%的大肠杆菌和99.7%的金黄色葡萄球菌,从而赋予了CMP-聚酰胺复合膜良好的抗菌性.展开更多
Aerogel composed of polyaniline/cellulose nanofiber(PANI/CNF)was synthesized by a two-step method and used as an adsorbent to remove Cr(Ⅵ)from wastewater in this study.Adsorption results showed that PANI/CNF aerogel ...Aerogel composed of polyaniline/cellulose nanofiber(PANI/CNF)was synthesized by a two-step method and used as an adsorbent to remove Cr(Ⅵ)from wastewater in this study.Adsorption results showed that PANI/CNF aerogel adsorbent exhibited a high adsorption capacity of 298.5 mg·g-1 for Cr(Ⅵ)(318 K,pH=2.0).Meanwhile,the adsorption process can be fitted well with the pseudo-second-order model and the Freundlich model.Moreover,the Cr(Ⅵ)removal efficiency of the adsorbent remained above 85%after ten recycling experiments,indicating that PANI/CNF aerogel had excellent stability and reusability.Therefore,PANI/CNF aerogel showed a potential application in the treatment of chromium-containing wastewater.展开更多
Ferroelectric polymer poly(vinylidene fluoride)(PVDF)has received great research interest because of its special electroactive properties which are strongly dependent on the crystalline structures and in turn processi...Ferroelectric polymer poly(vinylidene fluoride)(PVDF)has received great research interest because of its special electroactive properties which are strongly dependent on the crystalline structures and in turn processing conditions.The effect of molecular weight and crystallization temperature on the micro-structure and macro-properties of PVDF films casted from dimethyl sulfoxide(DMSO)solvent is investigated.The results demonstrated that a low molecular weight(180 kg/mol)and a low evaporation temperature(50℃)favored the formation of polarγ-phase,while a high molecular weight(1000 kg/mol)and a high evaporation temperature(125℃)made PVDF crystallize intoα-phase.Compared with films casted at 50℃,films casted at 125℃exhibited higher dielectric loss at a low electric field and less loss conductivity at a high electric field,which was due to their low degrees of crystallinity and fine evaporation of the solvent,respectively.PVDF with a molecular weight of 180 kg/mol casted at 125℃exhibited the highest remnant polarization(0.062 C/m^(2))among all of the solution-processed films,being a result of high chain mobility resulted from the low molecular weight.展开更多
基金supported by the National Key Research and Development Program of China(2022YFB3807100,2022YFB3807102,and 2022YFB3807103)the National Natural Science Foundation of China(22102021 and 52073046)+4 种基金the Fundamental Research Funds for the Central Universities(2232022A-03)Shanghai Shuguang Program(19SG28)the Program of Shanghai Academic Research Leader(21XD1420200)Chang Jiang Scholar Program(Q2019152)the Natural Science Foundation of Shanghai(21ZR1402700 and 23ZR1401100).
文摘渗透性和离子筛分能力是决定纳滤膜分离性能的主要指标.扩大渗透分离层的表面积不仅是提升膜通量的有效途径,还保持了盐的截留效果.受氨基/亚胺与酰氯缩合交联形成致密的聚酰胺网络的启发,我们提出了一种策略:将多孔的卟啉-苯胺共轭微孔聚合物(PACMP)接枝到聚酰胺膜上,从而增大纳滤膜的分离表面积.通过一步界面聚合,制备了一种超渗透的共轭微孔聚合物-聚酰胺复合膜(CPCMs),其水通量为61.8 L m^(−2) h^(−1),对盐(Na_(2)SO_(4))的截留率高于91.6%.此外,由于PACMPs中卟啉基团产生的活性氧,原位光激发单线态氧1O2可杀死98.5%的大肠杆菌和99.7%的金黄色葡萄球菌,从而赋予了CMP-聚酰胺复合膜良好的抗菌性.
基金National Natural Science Foundation of China(Nos.52073046,51873036,and 51673039)Fundamental Research Funds for the Central Universities,China(Nos.2232020D-08 and 2232019A3-01)+3 种基金Natural Science Foundation of Shanghai,China(No.19ZR1470900)Shanghai Shuguang Program,China(No.19SG28)International Joint Laboratory for Advanced Fiber and Low-Dimension Materials,China(No.18520750400)Initial Research Funds for Young Teachers of Donghua University,China(No.106-07-0053089)。
文摘Aerogel composed of polyaniline/cellulose nanofiber(PANI/CNF)was synthesized by a two-step method and used as an adsorbent to remove Cr(Ⅵ)from wastewater in this study.Adsorption results showed that PANI/CNF aerogel adsorbent exhibited a high adsorption capacity of 298.5 mg·g-1 for Cr(Ⅵ)(318 K,pH=2.0).Meanwhile,the adsorption process can be fitted well with the pseudo-second-order model and the Freundlich model.Moreover,the Cr(Ⅵ)removal efficiency of the adsorbent remained above 85%after ten recycling experiments,indicating that PANI/CNF aerogel had excellent stability and reusability.Therefore,PANI/CNF aerogel showed a potential application in the treatment of chromium-containing wastewater.
基金Fundamental Research Funds for the Central Universities,China(No.2232021D-01)Shanghai Pujiang Program,China(No.20PJ1400600)。
文摘Ferroelectric polymer poly(vinylidene fluoride)(PVDF)has received great research interest because of its special electroactive properties which are strongly dependent on the crystalline structures and in turn processing conditions.The effect of molecular weight and crystallization temperature on the micro-structure and macro-properties of PVDF films casted from dimethyl sulfoxide(DMSO)solvent is investigated.The results demonstrated that a low molecular weight(180 kg/mol)and a low evaporation temperature(50℃)favored the formation of polarγ-phase,while a high molecular weight(1000 kg/mol)and a high evaporation temperature(125℃)made PVDF crystallize intoα-phase.Compared with films casted at 50℃,films casted at 125℃exhibited higher dielectric loss at a low electric field and less loss conductivity at a high electric field,which was due to their low degrees of crystallinity and fine evaporation of the solvent,respectively.PVDF with a molecular weight of 180 kg/mol casted at 125℃exhibited the highest remnant polarization(0.062 C/m^(2))among all of the solution-processed films,being a result of high chain mobility resulted from the low molecular weight.
