This Paper describes an experimental met,that that established a local Pt/Nafion interface on the Platinum Plane, so that the boundary conditions and the initial condition of the (diffusion equation about the diffusio...This Paper describes an experimental met,that that established a local Pt/Nafion interface on the Platinum Plane, so that the boundary conditions and the initial condition of the (diffusion equation about the diffusion of adsorbde hydrogen atom the platinum plane can be controlled.The average diffusion coefficient of underpotential deposition of hydrogen on a surface of platinum was obained for the first time and D=1.50 ×10-4cm2.s-1.The accuracy of the datum was discussed.展开更多
An electrophoresis technique using a strip of perflurosulfonic acid(Nafion 117) membrane as separation column is described. The narrow hydrophilic pores(diameter 1～2 nm) in Nafion act as electrophoresis channels a...An electrophoresis technique using a strip of perflurosulfonic acid(Nafion 117) membrane as separation column is described. The narrow hydrophilic pores(diameter 1～2 nm) in Nafion act as electrophoresis channels and the fixed charge sites on the inner surface of the channels provide a strong background electric field. The technique was used to separate the mixture of dopamine and epinephrine under the separation voltage of 100V with a satisfactory efficiency of separation.展开更多
文摘This Paper describes an experimental met,that that established a local Pt/Nafion interface on the Platinum Plane, so that the boundary conditions and the initial condition of the (diffusion equation about the diffusion of adsorbde hydrogen atom the platinum plane can be controlled.The average diffusion coefficient of underpotential deposition of hydrogen on a surface of platinum was obained for the first time and D=1.50 ×10-4cm2.s-1.The accuracy of the datum was discussed.
文摘An electrophoresis technique using a strip of perflurosulfonic acid(Nafion 117) membrane as separation column is described. The narrow hydrophilic pores(diameter 1～2 nm) in Nafion act as electrophoresis channels and the fixed charge sites on the inner surface of the channels provide a strong background electric field. The technique was used to separate the mixture of dopamine and epinephrine under the separation voltage of 100V with a satisfactory efficiency of separation.
