Ethyl（（S）-2＇-hydroxy-1,1＇-binaphthalen-2-yl）-（SP）-vinylphosphonate （SBINOL-SP） was synthesized by diastereoselective reaction and characterized by means of NMR spectroscopy, H RMS and X-ray diffraction. The ...Ethyl（（S）-2＇-hydroxy-1,1＇-binaphthalen-2-yl）-（SP）-vinylphosphonate （SBINOL-SP） was synthesized by diastereoselective reaction and characterized by means of NMR spectroscopy, H RMS and X-ray diffraction. The single crystal belongs to the monoclinic system, space group P21/c with a = 7.4983（13）, b = 12.065（2）, c = 21.805（4） ？, β = 90.094（6）°, Mr = 404.38, V = 1972.6（6） ？3, Z = 4, Dc = 1.362 g/cm3, F（000） = 848, μ = 0.168 mm-1, R = 0.0280 and wR = 0.0743. The title compound shows good activities against E. coli, S. albus, B. subtilis and M. tetragenus.展开更多
文摘Ethyl（（S）-2＇-hydroxy-1,1＇-binaphthalen-2-yl）-（SP）-vinylphosphonate （SBINOL-SP） was synthesized by diastereoselective reaction and characterized by means of NMR spectroscopy, H RMS and X-ray diffraction. The single crystal belongs to the monoclinic system, space group P21/c with a = 7.4983（13）, b = 12.065（2）, c = 21.805（4） ？, β = 90.094（6）°, Mr = 404.38, V = 1972.6（6） ？3, Z = 4, Dc = 1.362 g/cm3, F（000） = 848, μ = 0.168 mm-1, R = 0.0280 and wR = 0.0743. The title compound shows good activities against E. coli, S. albus, B. subtilis and M. tetragenus.
